Syntheses and Crystal Structures of Two Transition Metal Complexes (M = Mn and Co) Containing Malonate and Reduced Imino Nitroxide Radicals

Table 2

Selected bond distances (Å) and bond angles (°) for the complex 1.

Co(1)–O(2)	1.879(4)	C(1)–C(2)	1.360(9)
Co(1)–N(1)	1.945(4)	O(2)–Co(1)–O(2)#1	95.0(3)
Co(1)–N(2)	1.947(5)	O(2)–Co(1)–N(1)#1	93.8(2)
O(1)–N(3)	1.400(6)	O(2)–Co(1)–N(1)	86.8(2)
N(1)–C(5)	1.336(7)	N(1)#–Co(1)–N(1)	179.1(4)
N(1)–C(1)	1.354(8)	O(2)–Co(1)–N(2)#1	175.0(2)
N(2)–C(6)	1.296(7)	N(1)–Co(1)–N(2)#1	97.2(2)
N(2)–C(10)	1.490(8)	O(2)–Co(1)–N(2)	87.67(16)
N(3)–C(6)	1.336(7)	N(1)–Co(1)–N(2)	82.1(2)
N(3)–C(7)	1.469(8)	N(2)#1–Co(1)–N(2)	90.0(3)

Symmetry transformations used to generate equivalent atoms: no. 1 −𝑥,𝑦,−𝑧.