Research Article
Novel Nonsymmetrically p-Benzyl-Substituted (Benz)imidazole N-Heterocyclic Carbene-Silver(I) Acetate Complexes: Synthesis and Biological Evaluation
Table 2
Selected bond lengths [Å] and angles [°] for 4b.
| | Bond length [Å] | Bond angle [°] |
| | 4b (95% species) | 4b (5% species) | | 4b (95% species) | 4b (5% species) |
| | Ag(1)–C(9) | 2.060(2) | | C(9)–Ag(1) –O(1) | 170.76(7) | | | Ag(1)–O(1) | 2.1088(14) | | C(9)–Ag(2)–O(1) | | 135.9(4) | | Ag(2)–C(9) | | 2.074(5) | C(9)–Ag(2)–O(2) | | 164.9(3) | | Ag(2)–O(1) | | 2.408(6) | O(1)–Ag(2)–O(2) | | 53.05(11) | | Ag(2)–O(2) | | 2.554(5) | N(3)–C(9)–N(2) | 105.98(17) | | | N(2)–C(9) | 1.350(3) | | N(3)–C(9)–Ag(1) | 127.63(14) | | | N(2)–C(10) | 1.395(2) | | N(2)–C(9)–Ag(1) | 125.82(14) | | | C(9)–N(3) | 1.348(2) | | N(3)–C(9)–Ag(2) | | 118.7(2) | | C(10)–C(15) | 1.388(3) | | N(2)–C(9)–Ag(2) | | 133.79(19) | | C(15)–N(3) | 1.391(3) | | C(15)–C(10)–N(2) | 105.82(17) | | | O(1)–C(24) | 1.276(3) | | C(10)–C(15)–N(3) | 106.11(17) | | | O(2)–C(24) | 1.237(2) | | C(9)–N(3)–C(15) | 111.09(16) | | | C(24)–C(25) | 1.511(3) | | C(9)–N(2)–C(10) | 110.96(16) | | | | | C(24)–O(1)–Ag(1) | 109.21(12) | | | | | C(24)–O(1)–Ag(2) | | 93.9(2) | | | | C(24)–O(2)–Ag(2) | | 88.1(2) | | | | O(2)–C(24)–O(1) | | 124.18(19) | | | | O(2)–C(24)–C(25) | | 119.62(19) | | | | O(1)–C(24)–C(25) | | 116.19(18) |
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