Research Article
Synthesis and Characterization of the Adducts of Bis(O-ethyldithiocarbonato)copper(II) with Substituted Pyridines
Table 1
Molar conductance, magnetic moments, and analytical data of 1 : 1 adducts of bis(
-ethyldithiocarbonato)copper(II) with substituted pyridines.
| S. No. | Name of the compound | Molar conductance (ohm−1 mol−1 cm2) | eff (B.M.) at 293 K | % found | % calculated | C | H | N | S | C | H | N | S |
| 1 | Bis(ethylxanthato) (2-methylpyridine)copper(II) | 3.49 | 1.88 | 33.0 | 3.02 | 3.0 | 32.7 | 34.4 | 3.91 | 3.64 | 33.3 | 2 | Bis(ethylxanthato) (3-methylpyridine)copper(II) | 3.85 | 1.92 | 34.8 | 3.98 | 2.78 | 31.9 | 36.2 | 4.27 | 3.51 | 32.2 | 3 | Bis(ethylxanthato) (4-methylpyridine)copper(II) | 4.35 | 1.93 | 35.5 | 3.55 | 2.98 | 30.8 | 36.2 | 4.27 | 3.51 | 32.2 | 4 | Bis(ethylxanthato) (2-ethylpyridine)copper(II) | 3.89 | 1.76 | 36.6 | 4.01 | 3.15 | 30.7 | 37.9 | 4.61 | 3.40 | 31.1 | 5 | Bis(ethylxanthato) (3-ethylpyridine)copper(II) | 3.97 | 1.82 | 36.2 | 4.00 | 3.32 | 30.6 | 37.9 | 4.61 | 3.40 | 31.1 | 6 | Bis(ethylxanthato) (4-ethylpyridine)copper(II) | 4.74 | 1.85 | 36.6 | 3.98 | 3.20 | 30.2 | 37.9 | 4.61 | 3.40 | 31.1 |
|
|