Research Article
Novel Low Spin Mixed Ligand Thiohydrazide Complexes of Iron(III): Synthesis, Spectral Characterization, Molecular Modeling, and Antibacterial Activity
Table 4
Selected bond lengths (Å) and bond angles (°) for the optimized structure of
Fe(acac)(htbh)
2.
(a) Bond lengths (Å) |
| Fe–O1 | 1.940 | Fe–N2 | 2.029 | Fe–O2 | 1.973 | Fe–S1 | 2.223 | Fe–N1 | 2.105 | Fe–S2 | 2.295 |
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(b) Bond angles (°) |
| O1–Fe–O2 | 93.61 | O1–Fe–N2 | 172.36 | O1–Fe–S1 | 93.51 | N1–Fe–S1 | 85.47 | N1–Fe–N2 | 94.69 | O2–Fe–S1 | 168.90 | O1–Fe–N1 | 89.72 | N2–Fe–S2 | 83.25 | S1–Fe–S2 | 93.33 | N1–Fe–S2 | 177.59 | O2–Fe–S2 | 94.87 | | |
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