]>Two-Dimensional Free Energy Surfaces for Electron Transfer Reactions in Solution : Table 1
Table 1: Parameters 𝐸 𝑓 ∞ and − Δ 𝐺 A N determined by analyzing the fluorescence decay curves.
𝑅 0 /eV 𝑘 0 /eV − 1 /Å 2 . 9 × 1 0 1 0 /s 3 . 7 × 1 0 1 0
C153-TMPD(0.2 M)0.920.7811.1 4 . 2 × 1 0 8
C522-TMPD(0.2 M)0.810.8912.2 𝐸 𝑓 ∞
C152-TMPD(0.2 M)0.631.0715.2 Δ 𝐺 A N
𝜀 𝑆 = 𝜀 o p = 2 . 1 6 was calculated from 𝑎 = 3 . 5 using (4). 𝑏 = 3 . 9 for liquid paraffin and 𝑌 ( 𝑟 )  Å  for TMPD and 𝑌 𝑟 = 4 𝜋 𝑟 2 𝑐 0 𝑘 𝑟 ∞ 0 𝑞 𝑃 𝑡 𝑟 , 𝑡 𝑑 𝑡 , ( 2 0 )  Å  for coumarins.