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International Journal of Photoenergy
Volume 2010 (2010), Article ID 528512, 2 pages

Thin-Film Photovoltaics

1CNR- Istituto per i Processi Chimico-Fisici, Viale Ferdinando Stagno d'Alcontres, 37 98158 Messina, Italy
2Dipartimento di Ingegneria Elettrica, Elettronica e delle Telecomunicazioni, Università di Palermo, Viale delle Scienze, 90128 Palermo, Italy

Received 2 November 2010; Accepted 2 November 2010

Copyright © 2010 Gaetano Di Marco and Leonardo Palmisano. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

A solution to obtain energy in a sustainable manner for the environment and to benefit the people of the earth is the use of the sun as a primary source. The development of new technologies is strategic for the scientific community and is a challenge for the 21st century. In fact, the amount of energy that the sun radiates into the earth is about ten thousand times greater than what mankind uses.

Thin-film photovoltaic systems are quickly diffusing in these last years, and they now account for some 12% of solar installation around the world. Thin-film (TF) photovoltaic cells are less expensive to manufacture than the traditional crystalline silicon-based ones and have considerably lowered the barrier to the entry into the photovoltaic energy business. Significantly, the production cost of first solar CdSe modules is now lower than 1$/Wp. The sector is thus rapidly switching from the heavy fragile silicon panels to thin-film technologies which use a number of different inorganic and organic photovoltaic (PV) semiconductors, and the revenue market share of TFPVs is expected to rise very much next years.

This special issue collects some research papers mainly reporting preparation, characterization, and testing of thin-films, some of which could be of importance in the near future by an application point of view to assemble new photovoltaic cells.

The essentials of each papers are described below.

Progress in Polycrystalline thin Film CGIS Solar Cells
A variety of methods are presented to prepare CIGS [Cu(InGa)Se2 or Cu(InGa)(Se,S)2] thin films, and important parameters (optoelectronic properties, substrates, partner layers) are assessed to improve efficiency of solar cells.

Preparation and Characterization of Sb2Te3 thin Films by Coevaporation
New materials such as Sb2Te3 have the peculiarity of forming a stable ohmic back contacts with CdTe; as a matter of fact, the cadmium telluride shows interesting performances for photovoltaic applications. Electrical properties, structure, morphology, and preparation of antimony telluride are described.

Investigation of Low-Cost Surface Processing Techniques for Large-Size Multicrystalline Silicon Solar Cells
A simple method is presented to enhance conversion performance in large-size solar cells using multicrystalline silicon (mc-Si) wafer. In particular, a single layer (SL) and dual layer (DL) of silicon nitride (Si3N4) are deposited in mc-Si by plasma-enhanced chemical vapor deposition. Quantum efficiency measurements show that DL coating can get the best results.

Efficiency Improved by H2 Forming Gas Treatment for Si-Based Solar Cell Application
Forming gas treatments (FG) on single-crystalline (sc) and on multicrystalline (mc) silicon (Si) components useful for solar cells improve their photovoltaic effects. The increment is larger in mc-Si than in sc-Si. The internal quantum efficiency increases with FG, especially in the visible region.

Lateral Infrared Photovoltaic Effects in Ag-Doped ZnO thin Films
Ag-doped ZnO thin films exhibit a lateral-induced photovoltage under 1064 nm pulse laser radiation. High photovoltaic responsivity and position sensitivity values are observed. This circumstance proposes the ZnO thin film as a good candidate for IR position photo-detector.

Organic Solar Cells: Problems and Prespectives
The use of semiconducting conjugated polymers in organic-based photovoltaic (OPV) cells is discussed as a current research topic. In this brief review, some interesting aspects connected to efficiency, diffusion, dissociation, and transport charge of the aforesaid material are described.

ZnO-Nanorod Dye Sensitized Solar Cells: New Structure without a Transparent Conducting Oxide Layer
Dye-sensitized solar cells (DSSCs) based on ZnO nanorod/film structure without transparent conducting oxide (TCO, typically fluoride-doped tin oxide/FTO) and two preparation methods are proposed. The new DSSCs yield interesting photovoltaic features.

Bridged Phthalocyanine Systems for Sensitization of Nanocrystalline TiO2 Films
The paper explains the construction of DSSCs by using metal phtalocyanines and their derivatives. The reason why these dyes are considered “appealing materials” is pointed out. Furthermore, the synthesis strategy for conjugated superchromophore is presented.

Preparation of a counter Electrode with p-Type NiO and its Applications in Dye Sensitized Solar Cell
The effect of counter electrode with a p-type semiconductor (NiO film) on power conversion efficiency of DSSC, is investigated. The study compares different cathodes, and a photoelectrochemical analysis is carried out. It seems that the NiO film increases the electrocatalytic activity of the counterelectrode.

Metal Nanoparticles and Carbon-Based Nanostructures as Advanced Materials for Cathode Application in Dye-Sensitized Solar Cells
Advanced methods for the fabrication of cathodes for DSSCs, employing nanostructured materials, are reviewed. The attention is focused on metal nanoparticles and nanostructured carbon, among which nanotubes and graphene, whose good catalytic properties make them ideal for the development of high performance catalyst materials.

Fabrication of Dye Sensitized Solar Cells with a 3D Nanostructured Elettrode
An original photoanode for DSSCs is fabricated. The electrode is realized by a sputtered 3D nanostructured indium tin oxide (ITO), electrophoretic deposition of TiO2 nanoparticles and dye sensitization. The final device reveals improved performances in respect to the conventional ones.

New Components for Dye-Sensitized Solar Cells
DSSCs are third-generation photovoltaic devices that can be used in various applications, due to their low cost and ease of fabrication. In this contribution, recent advances in molecular sensitizers, electron mediators, conductive polymers, and catalytic materials are reviewed.

Characterizations of Chitosan-Based Polymer Electrode Photovoltaic Cells
Solid polymer electrolytes are employed in the fabrication of solid-state photoelectrochemical cells. Several electrolytic compositions, electrical conduction, and photoelectrical performance are reported. Dyes extracts from local vegetables are also used to reduce the environmental impact.

Debundling and Selective Enrichment of SWNTs for Applications in Dye-Sensitized Solar Cells
The state of the art is reviewed on the use of single-wall carbon nanotubes (SWNTs) in DSSCs, where they can serve multiple purposes. The paper, together with a wide and comprehensive critical analysis of the literature, highlights the possible strategies and indicates a few useful directions for future research to improve the performance of nanotube-based DSSCs.

Gaetano Di Marco
Leonardo Palmisano