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International Journal of Photoenergy
Volume 2013 (2013), Article ID 612163, 8 pages
Fabrication of High Transparency Diamond-Like Carbon Film Coating on D263T Glass at Room Temperature as an Antireflection Layer
1Institute of Mechatronic Engineering, National Taipei University of Technology, Taipei 10608, Taiwan
2College of Mechanical and Electrical Engineering, National Taipei University of Technology, Taipei 10608, Taiwan
3Graduate College of Mechanical and Electrical Engineering, National Taipei University of Technology, Taipei 10608, Taiwan
Received 7 December 2012; Revised 28 January 2013; Accepted 1 February 2013
Academic Editor: Ho Chang
Copyright © 2013 Chii-Ruey Lin et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
This study intends to deposit high transmittance diamond-like carbon (DLC) thin films on D263T glass substrate at room temperature via a diamond powder target using the radio frequency (RF) magnetron sputtering technique. Moreover, various process parameters were used to tune the properties of the thin films by using the Taguchi method. Experimental results show that the content of sp3 bonded carbon decreases in accordance with the effect of the substrate temperature. In addition, the hardness of all as-deposited single-layer DLC films ranges from 13.2 to 22.5 GPa, and the RMS surface roughness was improved significantly with the decrease in sputtering pressure. The water repellent of the deposited DLC films improved significantly with the increase of the sp3 content, and its contact angle was larger than that of the noncoated one by 1.45 times. Furthermore, the refraction index (n) of all as-deposited DLC films ranges from 1.95 to 2.1 at λ = 600 nm. These results demonstrate that the thickness increased as the reflectance increased. DLC film under an RF power of 150 W possesses high transmissive ability (>81%) and low average reflectance ability (<9.5%) in the visible wavelengths (at λ = 400–700 nm).
Diamond-like carbon (DLC) containing a large proportion of combined sp3/sp2-hybrid bonds has extreme properties similar to diamonds [1–5]. It is possible to prepare DLC films for several important applications in the fields of mechanical manufacturing, solar energy devices, electricity devices, and so forth, owing to their excellent properties, including high hardness, high thermal conductivity, high electrical resistivity, low infrared (IR) absorption, transparency to visible light, hydrophobic behavior, and chemical inertness [6–11]. Recent researches and technology have focused on keeping high transmission with reduced reflectance capability to maintain enough visibility in a protectively antireflecting coating for solar energy; this type of optical coating can be applied to the surfaces of lenses and other optical devices to reduce reflection [12, 13]. Thus, this study proposes a novel technique which can keep the surface water repellent and improve the surface by lowering reflection.
In this study, hydrogen-free DLC films were deposited at room temperature by using radio frequency (RF) magnetron sputtering with a unique target consisting of artificial nanodiamond powders. The nano-diamond powder used in this work was a commercial product, which was synthesized by the high-pressure high-temperature (HPHT) method. The diamond target fabricated in the RF magnetron cathode for DLC sputtering was composed of high-purity diamond powder with a mean particle size of about 100 nm. The nano-diamond target sputtering process easily formed high sp3 content on the thin film at a low temperature [6, 10, 14]. For optical applications, previous studies have indicated that the optical properties of DLC films vary between those of diamond (sp3 bonding) and graphite (sp2 bonding). The wavelengths of the refractive index (n) and extinction coefficient (k) of DLC depend on the C energies on the substrate . On the other hand, the most important parameter of the film is the thickness. DLC films have been applied as both protective and antireflective coatings for optoelectronic devices and silicon solar cells that are even more demanding in terms of well-defined thickness and the specific optical properties of the films [16, 17]. It is well known that light transparency and hydrophobic behavior depend on D263T glass-based materials. The D263T glass substrate is a borosilicate glass that is produced by melting very pure raw materials. This type of substrate has high luminous transmittance. The properties of D263T glass represent the standard for optical glass. The performances of films deposited onto D263T glass substrate vary under different parameters such as sputtering power, working distance, sputter pressure, and deposition time in the sputtering process. Experiments have carried out to understand the effects of these process parameters. Further discussion of the results of these experiments will be provided in the following. The purpose of this work was to deposit thin films on D263T glass substrate under various process parameters to tune the properties of the thin films by using the Taguchi method, wherein the only estimation standard for steadiness and robustness was to determine a variance index identified as the signal to noise ratio (S/N) [18–22]. Moreover, a lesser number of experiments are desired in the sputtering process when using the Taguchi method. This study utilized the Taguchi method to design experiments involving as-deposited hydrogen-free DLC films on D263T glass substrates at room temperature by the RF magnetron sputtering system. The experiments focused on the significance of the process parameters of DLC films, indicating that using four factors with three levels represents an L9 (34) orthogonal array. According to these analysis results, fewer experiments (only nine experimental runs) were required to study all levels of input parameters. We also filtered out some effects owing to statistical variation . The four factors include sputtering power, working distance, sputtering pressure, and deposition time. The ranks of each factor were considered as major influences in the experiment via the analysis of variance (ANOVA) approach. Thus, the Taguchi method was utilized as an engineering methodology to find a correlation between control factors and product characterization. The corresponding microstructure, optical performance, and mechanical properties of the thin films were identified by a scanning electron microscope (SEM), X-ray photoemission spectroscopy (XPS), atomic force microscopy (AFM), a UV/Vis spectrophotometer, and contact angle goniometry, respectively. XPS can be summed up as the measurement of kinetic energy of the inner or valence electron ejected by used an incident photon with energy hν. The binding energy is sensitive to chemical bonds in a compound and is related to the energy of ionization. The measured kinetic energy of photoelectrons generally ranges between 0 and 1000 eV in DLC films, and the depth of inspection is about 40–50 Å. As mentioned previously, XPS is a highly sensitive analyzer which offers a better method for the surface properties of the sample. The C1s peak of a-C:H films is in the range from 284.5 to 286.4 eV, as the full width at half maximum (FWHM) of the C1s peak of a-C:H is around 1.6–1.7 eV, relatively larger than the corresponding FWHM for diamond and for graphite. XPS was carried out the Mg K-α-line, which analyzed about the top 4 nm of the film, indicating that the spectra were determined with the C1s peak of ~285 eV. Also present was the O1s peak of 531 eV, owing to surface chemisorbed oxygen species. Thus, the sp2: sp3 ratios determined using XPS data will represent the surface values [23–25].
2. Experimental Methods
This study employs the Taguchi methods to design the experiment in which as-deposited hydrogen-free DLC films are deposited onto D263T glass substrate (10 × 10 × 0.55 mm) at room temperature by an RF magnetron sputtering system with an artificial diamond powder target of 3 inches in diameter as the magnetron source in an argon plasma. The diamond powder as the sputter target was easily synthesized with high sp3 content in thin film at low temperature by using the proposed sputtering method owing to the nanocrystalline diamond powders. With a larger fraction of sp3 bonding, the properties of DLC coatings will be skewed toward diamond. The content of sp3 is very much dependent on the ion energy during deposition . The DLC films were deposited by using sputter and the sputtering power; working distance, sputter pressure, and deposition time were used as the deposition parameters. In the sputtering process, the heat flux to the substrate relates to the thermalization coefficient which is the ratio of particle energy at the substrate to that at the target. This ratio depends on the product of gas pressure and substrate-target distance . Therefore, D263T glass substrates were placed at distances between 8 and 10 cm from the target with a rotation speed of 15 rpm. DLC films have been deposited at RF powers ranging from 150 to 200 W and at an rf of 13.56 MHz with capacitive coupling, and the film deposition time was in the range from 0.5 to 2 h under sputter pressure ranging from 1 to 5 mTorr. The corresponding three level experimental designs for depositing DLC films onto D263T glass substrate are listed in Tables 1 and 2. This study carried out the experiments by using the sputtering process conditions for an L9 (34) orthogonal array in all as-deposited DLC films. The structured bonding of the DLC films under different deposition parameters was examined by X-ray photoelectron spectroscopy (XPS). The contact angle of the samples was measured by the sessile drop method using a First Ten Angstroms 1000B (FTA 1000B) contact angle goniometry. The liquid was dropped by using 3 μL droplets of deionized (DI) water. All measurements were carried out at room temperature. A UV/Vis spectrophotometer was used to measure the corresponding optical transmittance of the DLC films deposited onto D263T glass substrate. The corresponding all the specimen’s optical properties of refractive index (n), extinction coefficient (k), transmittance, and reflectance and film thickness were determined by using a UV/Vis spectrometer (Mission peaks optics, MP100-M) equipped with an optical microscope. The instrument with multiple gratings measures to achieve the interference between incident and reflected light with a wide spectrum ranging from UV to visible range (380–950 nm) .
3. Results and Discussion
3.1. XPS and Microstructure Analysis of DLC Films
Figure 1 shows the response graph of the four factors versus sp3 content. The ranking of the order of the magnitude of the sp3 content ranges for various levels. The leading factor affecting process parameters is deposition time, followed successively by RF power, sputtering pressure, and working distance. XPS is employed to obtain the quantitative results of film composition (sp2: sp3), which are chemically specific, as each element has its own core level. The deconvolution of the C1s peak of DLC film is obtained by an XPS curve fitted by using the three-curve methods. The sp3 fraction of DLC films was derived from XPS fitting for the C1s core peak, with peaks formed by diamond (285.1 eV), graphite (284.6 eV), and carbon-oxygen (286.5 eV) bonds. The area of each peak depends on the corresponding phase. The sp3 content was estimated by taking the ratio of the diamond peak over the sum of the diamond, graphite, and carbon-oxygen bonds peak areas. In this study, each component was obtained by using a convolution of Gaussian (80%) and Lorentzian (20%) methods, and background subtraction was approximated by the Shirley method. The Gaussian widths of the spectra for DLC films are 1.35 eV, and the component depends on the sp2 and sp3 hybridization results in each specimen shifted by 0.5 eV, as shown in Figure 2 [23–25]. According to the XPS results, the probable sp3 content of the specimens was reduced from 56.17% to 50.92% in correspondence with increased deposition time. The findings demonstrate that the content of the sp3 bonded carbon becomes lower in reference to the effect of the substrate temperature. The implantation of carbon ion during deposition generates heat and warms up the substrate rapidly. The deposition time increases from 0.5 h to 2 h when significantly increasing the temperature on the substrate. The high temperature of the substrate can partially release the compressive stress induced by carbon ion implantation and obstruct the formation of sp3 bonds. The results can affect transform of the sp3 bond into an sp2 bond . On the other hand, this study assumes that the sp3 content varies with RF power. For an RF power of 150 W, the low proportion of sp3 bond in the thin film was formed from the diamond target via the sputtering process owing to the low bombardment energy. The bombardment energy is enhanced on the Ar plasma at the RF power of 175 W, indicating that the bonds of diamond can be broken by powerful bombarding atoms .
Figure 3 shows the typical plan view surface of SEM images, and the insets display the cross view. The results showed that as-deposited DLC films are considerable smooth morphology; the shrink and warped deformations were not observed from the surface of thin films. Figure 3(d) shows cross view of DLC film (specimen GD 3), indicating that the thickness is 30 nm. Through SEM analysis results, it clearly indicated never the existence of highly internal stress in such a thick DLC films leading to films peeling off from the D263T glass substrate. Figure 4 indicates the hardness of the DLC films analyzed by the nanoindentation test with a large loading of 500 μN. A scanning probe microscopy (SPM) apparatus was used to conduct nanofriction, nanowear, and fractal investigations to determine the nanotribological characteristics of the deposited DLC films. Fractal analysis is applied to quantitatively characterize the surface roughness of films measured by AFM. The aforementioned NIP test results showed that the hardness behaviors of all as-deposited DLC films improved significantly with the increase of the sp3 content, and the hardness of the as-deposited films was greater than 13.2 GPa.
3.2. RMS Surface Roughness Analysis of DLC Films
Figure 5 shows the response graph of the four factors versus RMS surface roughness. The ranking of the order of the magnitude of the RMS surface roughness differs at various levels, indicating that the effects of various factors on the RMS surface roughness increase in accordance with sputtering pressure, deposition time, working distance, and RF power. The surface roughness values of DLC films have been obtained by AFM analysis. AFM measurements presented here were obtained in the tapping mode, using a Digital Instruments Nanoscope machine. Typical scan areas were over 30 × 30 μm2, and the scan rate was approximately 1 Hz. Surface RMS roughness was obtained from a complete scan, using the software supplied with the AFM system. From this measurement it is clear that all as-deposited DLC films were lower than 1.9 nm with a scanning area of 30 × 30 μm2, and the RMS surface roughness in the DLC films was improved significantly with the decrease of the sputtering pressure. In this study, the formation of nanoparticles during vapor deposition strongly depends on the sputter pressure. At higher plasma pressure, there is an increase in the number of inelastic collisions which leads to a decrease in the diffusivity of carbon in the D263T glass substrate owing to the significantly reduced energies. Thus, the films deposited at higher plasma pressure demonstrate an increased RMS surface roughness. At low pressures, it is evident that smooth DLC films are formed. This result is consistent with previous results, and this can be understood on the basis of the large differences between the atomic masses of carbon and argon which causes carbon atoms to lose most of their kinetic energies before reaching the substrate at higher plasma pressures. This is expected to lead to the formation of thin film with high surface roughness .
3.3. Hydrophobicity Analysis of DLC Films
Figure 6 shows a response graph of four factors versus contact angle. The ranking order of the magnitude of contact angle at various levels indicates that the effects of various factors on the contact angle are ranked in the following order: RF power, deposition time, working distance, and sputtering pressure. A number of researchers have reported that the contact angle depends on the sp3 content of the film. It may be that hydrophobicity significantly decreases with the increase of sp2 bonded carbon in the films. The findings of this study may demonstrate that the surface energy varies at different carbon hybridized states, which modify the surface properties and associated hydrophobic/hydrophilic behavior. The surface energy of the sp3 terminated surface is very high because of its strong covalent character compared with that of the sp2 terminated surface as sp2 bonded graphite exhibits weak polarity due to its dangling bonds [31–33]. In this study, the DLC films under the RF power of 175 W show higher hydrophobicity than those under the RF power of 150 W and 200 W. It is clear that those films have high sp3 carbon content. Thus, the wetting contact angle of DLC films can be modified and controlled by the variation of sp3 content to obtain a hydrophobic or hydrophilic surface property.
3.4. Optical Properties Analysis of DLC Films
Figure 7 illustrates the response graph of four factors versus transmittance. The ranking order of the magnitude of transmittance at various levels indicates that the effects of various factors on the transmittance are ranked in the following order: RF power, deposition time, working distance, and sputtering pressure. The UV/Vis spectrophotometer shows that the optical properties of the films deposited with a single DLC layer are obtained from the five-point position of the films onto D263T glass. Figure 8 shows the refraction spectra for the D263T glass substrates coated with and without DLC films prepared under the sputtering process parameters, and the thickness of the as-deposited amorphous DLC films ranges from 17 to 66 nm. From the previous results, the values of the RMS roughness surface of the thin films are lower than 1.9 nm. It can be concluded that the effect of light scattering from the thin films was negligible. Thus, the reflectance of the thin films was decreased significantly with increasing transmittance. The reflectance in the visible wavelengths (at λ = 400–700 nm) significantly increases with increasing RF power. This is associated with the larger thickness. The total reflection changes with the refraction indices of the films and substrate, n and ns, respectively. As the refraction index of the substrate, ns, is larger than that of thin films, n, the resultant reflection will be reduced. This is referred to as constructive interference or broken interference . In this study, the reflectance of the as-deposited DLC films is higher than that of the noncoated one. This indicates that the refraction index of thin films is larger than that of the substrate one. The refraction index (n) of D263T glass substrate is 1.52. The UV/Vis spectrophotometer measurements show that the refraction index (n) of all as-deposited DLC films ranges from 1.95 to 2.1 at λ = 600 nm. These results demonstrate that the thickness was increased correspondingly with the increasing reflectance. On the other hand, under an RF power of 150 W and a deposition time of 0.5 h, the specimen GD 1 had high transmissive ability (>81%) and low average reflectance ability (<9.5%) in the visible wavelengths (at λ = 400–700 nm). This result could make an antireflection coating for solar cell devices available, which would improve efficiency .
The present work shows that DLC films have been successfully deposited onto D263T glass substrate at room temperature via a diamond powder target using the radio frequency (RF) magnetron sputtering technique and Taguchi method. Experimental results show that the content of sp3 bonded carbon decreases due to the effect of substrate temperature. The NIP test results showed that the hardness of the prepared DLC films ranges from 13.2 to 22.5 GPa. Moreover, the water repellence of the deposited DLC films improved significantly with increasing sp3 content, and its contact angle is larger than that of the noncoated one by 1.45 times. The reflectance in the visible wavelengths (at λ = 400–700 nm) significantly increases with increasing RF power, which is considered to be associated with the larger thickness. In addition, the refraction index (n) of all as-deposited DLC films ranges from 1.95 to 2.1 at λ = 600 nm. Furthermore, when the RF power was set to 150 W with the deposition time of 0.5 h, the prepared DLC films possessed high transmissive ability (>81%) and low average reflectance ability (<9.5%) in the visible wavelengths (at λ = 400–700 nm).
This work was financially supported by the main research projects of the National Science Council of the China under Grant nos. NSC 101-2221-E-027-009.
- R.-H. Horng, W.-C. Kao, S.-L. Ou, and D.-S. Wuu, “Effect of diamond like carbon layer on heat dissipation and optoelectronic performance of vertical-type InGaN light emitting diodes,” Applied Physics Letters, vol. 101, no. 17, Article ID 171102, 2012.
- J. Wang, F. Liu, H. Chen, and D. Chen, “Superhydrophobic behavior achieved from hydrophilic surfaces,” Applied Physics Letters, vol. 95, no. 8, Article ID 084104, 2009.
- C. R. Lin, C. H. Su, P. S. Fan, and K. L. Wang, “Application of nitrified steel deposit diamond-like carbon film in explosive environment,” Japanese Journal of Applied Physics, vol. 47, no. 4, pp. 2221–2224, 2008.
- J. A. Johnson, J. B. Woodford, D. Rajput et al., “Carbon-hydrogen bonding in near-frictionless carbon,” Applied Physics Letters, vol. 93, no. 13, Article ID 131911, 2008.
- T. Patrusheva, V. Letunovsky, L. Gorjacheva, A. Gorschkov, V. Sergienko, and E. Jakovleva, “Protective coatings from ultra fine diamond,” Carbon, vol. 40, no. 1, pp. 125–129, 2002.
- C. R. Lin, D. H. Wei, C. K. Chang, W. H. Liao, and K. Ran Peng, “Diamond-like carbon films deposited at room temperature on flexible plastics substrates for antireflection coating,” Japanese Journal of Applied Physics, vol. 50, no. 3, Article ID 035802, 2011.
- S. Sahoo, S. S. Pradhan, V. Bhavanasi, and S. K. Pradhan, “Structural and mechanical characterization of diamond like carbon films grown by microwave plasma CVD,” Surface and Coatings Technology, vol. 204, no. 16-17, pp. 2817–2821, 2010.
- S. B. Singh, M. Pandey, N. Chand et al., “Optical and mechanical properties of diamond like carbon films deposited by microwave ECR plasma CVD,” Bulletin of Materials Science, vol. 31, no. 5, pp. 813–818, 2008.
- W. S. Choi, K. Kim, J. Yi, and B. Hong, “Diamond-like carbon protective anti-reflection coating for Si solar cell,” Materials Letters, vol. 62, no. 4-5, pp. 577–580, 2008.
- C. H. Su, C. R. Lin, C. Y. Chang, H. C. Hung, and T. Y. Lin, “Mechanical and optical properties of diamond-like carbon thin films deposited by low temperature process,” Thin Solid Films, vol. 498, no. 1-2, pp. 220–223, 2006.
- J. Robertson, “Properties of diamond-like carbon,” Surface and Coatings Technology, vol. 50, no. 3, pp. 185–203, 1992.
- V. M. Aroutiounian, K. Martirosyan, and P. Soukiassian, “Low reflectance of diamond-like carbon/porous silicon double layer antireflection coating for silicon solar cells,” Journal of Physics D, vol. 37, no. 19, pp. L25–L28, 2004.
- Y. Hayashi, S. Ishikawa, T. Soga, M. Umeno, and T. Jimbo, “Photovoltaic characteristics of boron-doped hydrogenated amorphous carbon on n-Si substrate prepared by r.f. plasma-enhanced CVD using trimethylboron,” Diamond and Related Materials, vol. 12, no. 3–7, pp. 687–690, 2003.
- W.-H. Liao, C. -R. Lin, D.-H. Wei et al., “Concurrent improvement in biocompatibility and bioinertness of diamond-like carbon films with nitrogen doping,” Journal of Biomedical Materials Research Part A, vol. 100, no. 11, pp. 3151–3156, 2012.
- Y. Lifshitz, G. D. Lempert, E. Grossman et al., “Optical and photoemission studies of DLC films prepared with a systematic variation of the sp3:sp2 composition,” Diamond and Related Materials, vol. 6, no. 5–7, pp. 687–693, 1997.
- M. Smietana, W. J. Bock, J. Szmidt, and J. Grabarczyk, “Substrate effect on the optical properties and thickness of diamond-like carbon films deposited by the RF PACVD method,” Diamond and Related Materials, vol. 19, no. 12, pp. 1461–1465, 2010.
- M. H. Oliveira, D. S. Silva, A. D. S. Côrtes, M. A. B. Namani, and F. C. Marques, “Diamond like carbon used as antireflective coating on crystalline silicon solar cells,” Diamond and Related Materials, vol. 18, no. 5–8, pp. 1028–1030, 2009.
- Y.-S. Yang and W. Huang, “A grey-fuzzy Taguchi approach for optimizing multi-objective properties of zirconium-containing diamond-like carbon coatings,” Expert Systems with Applications, vol. 39, no. 1, pp. 743–750, 2012.
- M. Hamidi, A. Azadi, H. Ashrafi, P. Rafiei, and S. Mohamadi-Samani, “Taguchi orthogonal array design for the optimization of hydrogel nanoparticles for the intravenous delivery of small-molecule drugs,” Journal of Applied Polymer Science, vol. 126, no. 5, pp. 1714–1724, 2012.
- A. Czyzniewski, “Optimising deposition parameters of W-DLC coatings for tool materials of high speed steel and cemented carbide,” Vacuum, vol. 86, no. 12, pp. 2140–2147, 2012.
- A. H. Tan and Y. C. Cheng, “Optimization of wear-corrosion properties of a-C:N films using filtered cathodic arc deposition,” Diamond and Related Materials, vol. 17, no. 1, pp. 36–42, 2008.
- N. Ali, V. F. Neto, S. Mei et al., “Optimisation of the new time-modulated CVD process using the Taguchi method,” Thin Solid Films, vol. 469-470, pp. 154–160, 2004.
- T. Y. Leung, W. F. Man, P. K. Lim, W. C. Chan, F. Gaspari, and S. Zukotynski, “Determination of the sp3/sp2 ratio of a-C:H by XPS and XAES,” Journal of Non-Crystalline Solids, vol. 254, no. 1–3, pp. 156–160, 1999.
- J. Filik, P. W. May, S. R. J. Pearce, R. K. Wild, and K. R. Hallam, “XPS and laser Raman analysis of hydrogenated amorphous carbon films,” Diamond and Related Materials, vol. 12, no. 3–7, pp. 974–978, 2003.
- Z. G. Lu and C. Y. Chung, “Electrochemical characterization of diamond like carbon thin films,” Diamond and Related Materials, vol. 17, no. 11, pp. 1871–1876, 2008.
- J. B. Wu, J. J. Chang, M. Y. Li, M. S. Leu, and A. K. Li, “Characterization of diamond-like carbon coatings prepared by pulsed bias cathodic vacuum arc deposition,” Thin Solid Films, vol. 516, no. 2–4, pp. 243–247, 2007.
- K. Bewilogua, C. V. Cooper, C. Specht, J. Schröder, R. Wittorf, and M. Grischke, “Effect of target material on deposition and properties of metal-containing DLC (Me-DLC) coatings,” Surface and Coatings Technology, vol. 127, no. 2-3, pp. 224–232, 2000.
- C. M. Chuang, M. C. Wu, W. F. Su, K. C. Cheng, and Y. F. Chen, “High intensity fluorescence of photoactivated silver oxide from composite thin film with periodic array structure,” Applied Physics Letters, vol. 89, no. 6, Article ID 061912, 2006.
- X. Z. Che, L. H. Chen, H. T. Ma, and H. X. Fang, “Effect of thickness on structures of ultrathin diamond-like carbon films,” Chinese Science Bulletin, vol. 55, no. 18, pp. 1949–1951, 2010.
- R. Maheswaran, R. Sivaraman, O. Mahapatra, P. C. Rao, C. Gopalakrishnan, and D. J. Thiruvadigal, “Surface studies of diamond-like carbon films grown by plasma-enhanced chemical vapor deposition,” Surface and Interface Analysis, vol. 42, no. 12-13, pp. 1702–1705, 2010.
- J. Robertson, “Diamond-like amorphous carbon,” Materials Science and Engineering R, vol. 37, pp. 129–281, 2002.
- Y. Zhou, B. Wang, X. Song et al., “Control over the wettability of amorphous carbon films in a large range from hydrophilicity to super-hydrophobicity,” Applied Surface Science, vol. 253, no. 5, pp. 2690–2694, 2006.
- R. Paul, S. N. Das, S. Dalui et al., “Synthesis of DLC films with different sp2/sp3 ratios and their hydrophobic behaviour,” Journal of Physics D, vol. 41, no. 5, Article ID 055309, 2008.