Effect of Initial Orientation on the Laser-Induced Cycloaddition Reaction of Benzene and Ethylene

Figure 5

The variations with time of (a) the HOMO and LUMO energies; (b) the time-dependent population of stacked benzene and ethylene system in synchronous mode, which is subjected to a laser with frequency of 4.7 eV and fluency of 96.93 Jm⁻²; (c) and (d) are the HOMO and LUMO energies and the time-dependent population in asynchronous mode, which is subjected to a laser with frequency of 4.7 eV and fluence of 94.11 Jm⁻².

(a)

(b)

(c)

(d)