Monte Carlo Simulation of Linear Polymer Thermal Depolymerization under Isothermal and Dynamic Modes

Table 3

Estimations of the Avrami equation parameters for arrays with different initial PDI under dynamic TGA mode of depolymerization.

𝑃𝑤/𝑃𝑛	Log(𝑘0),	𝐴0∗10^−7,	𝐸, kJ/mol	𝑞
	min^−1	min^−1
1	4.89±0.02	0.78	99.4±0.3	1.525±0.013
1.14	4.91±0.02	0.81	99.0±0.2	1.354±0.005
1.25	4.97±0.01	0.93	99.5±0.1	1.248±0.002
1.5	5.00±0.01	1.00	99.6±0.1	1.105±0.001
1.75	5.04±0.01	1.08	99.9±0.1	1.016±0.002
2	5.06±0.02	1.15	100.1±0.1	0.950±0.002
2.5	5.09±0.02	1.23	100.7±0.1	0.874±0.002
3	5.02±0.02	1.05	100.2±0.1	0.837±0.001