A Theoretical Study of the Insertion of Atoms and Ions into Titanosilsequioxane (Ti-POSS) in Comparison with POSS : Figure 5

(a) Axial C_s

(b) Endo D_4h

Figure 5: The B3LYP/6-311+G(d) optimized geometries of the exohedral (Axial) and endohedral (Endo) complexes of Cl⁻ and Ti-T₈ in angstroms.