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International Journal of Polymer Science
Volume 2012 (2012), Article ID 460835, 6 pages
Research Article

Evolution of Mesopores in Monolithic Macroporous Ethylene-Bridged Polysilsesquioxane Gels Incorporated with Nonionic Surfactant

Department of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa, Sakyo-ku, Kyoto 606-8502, Japan

Received 11 July 2012; Accepted 4 September 2012

Academic Editor: Takahiro Gunji

Copyright © 2012 Atsushi Mushiake et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


By combining the micellar templating in nanometer scale with the polymerization-induced phase separation in micrometer scale, ethylene-bridged polysilsesquioxane gels with hierarchical macropores and mesopores are prepared. The difference of mesopore structures depending on the method of the solvent removal has been observed by the X-ray diffraction and the nitrogen adsorption-desorption measurements. During the hydrothermal treatment under the basic condition, the reorganization of the polysilsesquioxane gel network occurred differently depending on the alkoxy group contained in the precursors. From 29Si CP/MAS NMR measurements, it was revealed that the crosslinking density of the hydrothermally treated gels was increased so that the highly ordered mesostructure of the wet gel could be preserved even after the evaporative drying of solvent.