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International Journal of Polymer Science
Volume 2012 (2012), Article ID 692604, 10 pages
http://dx.doi.org/10.1155/2012/692604
Research Article

Iron Oxide Arrays Prepared from Ferrocene- and Silsesquioxane-Containing Block Copolymers

Department of Organic and Polymeric Materials, Tokyo Institute of Technology, 2-12-1-S8-36 Ookayama, Meguro-ku, Tokyo 152-8552, Japan

Received 13 August 2012; Accepted 11 October 2012

Academic Editor: Maki Itoh

Copyright © 2012 Raita Goseki et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. M. Lazzari and M. A. López-Quintela, “Block copolymers as a tool for nanomaterial fabrication,” Advanced Materials, vol. 15, no. 19, pp. 1583–1594, 2003. View at Publisher · View at Google Scholar · View at Scopus
  2. C. Park, J. Yoon, and E. L. Thomas, “Enabling nanotechnology with self assembled block copolymer patterns,” Polymer, vol. 44, no. 22, pp. 6725–6760, 2003. View at Publisher · View at Google Scholar · View at Scopus
  3. J. Y. Cheng, C. A. Ross, H. I. Smith, and E. L. Thomas, “Templated self-assembly of block copolymers: top-down helps bottom-up,” Advanced Materials, vol. 18, no. 19, pp. 2505–2521, 2006. View at Publisher · View at Google Scholar · View at Scopus
  4. M. Park, C. Harison, P. M. Chaikin, R. A. Register, and D. H. Adamson, “Block copolymer lithography: periodic arrays of ~1011 holes in 1 square centimeter,” Science, vol. 276, no. 5317, pp. 1401–1404, 1997. View at Publisher · View at Google Scholar
  5. C. J. Hawker and T. P. Russell, “Block copolymer lithography: merging “bottom-up” with “top-down” processes,” MRS Bulletin, vol. 30, no. 12, pp. 952–966, 2005. View at Scopus
  6. J. Bang, U. Jeong, D. Y. Ryu, T. P. Russell, and C. J. Hawker, “Block copolymer lithography: translation of molecular level control to nanoscale patterns,” Advanced Materials, vol. 21, no. 47, pp. 4769–4792, 2009. View at Publisher · View at Google Scholar
  7. A. V. Ruzette and L. Leibler, “Block copolymers in tomorrow's plastics,” Nature Materials, vol. 4, no. 1, pp. 19–31, 2005. View at Publisher · View at Google Scholar · View at Scopus
  8. A. S. Abd-El-Aziz and I. Manners, Frontiers in Transition Metal-Containing Polymers, Wiley-Interscience, Hoboken, NJ, USA, 2007.
  9. I. Manners, Synthetic Metal-Containing Polymers, VCH, Weinheim, Germany, 2004.
  10. D. Wohrle and A. D. Pomogailo, Metal Complexes and Metals in Macromolecules: Synthesis, Structure and Properties, Wiley-VCH, Weinheim, Germany, 2003.
  11. C. E. Carraher, A. S. Abd-El-Aziz, C. Pittman, J. Sheats, and M. Zeldin, A Half Century of Metal and Metalloid Containing Polymers, Wiley, New York, NY, USA, 2003.
  12. M. Rehahn, “Organic-inorganic hybrid polymers,” in Synthesis of Polymers: A Volume of the Materials Science and Technology Series, A. D. Schluter, Ed., Wiley-VCH, Weinheim, Germany, 1999.
  13. P. Nguyen, P. Gómez-Elipe, and L. Manners, “Organometallic polymers with transition metals in the main chain,” Chemical Reviews, vol. 99, no. 6, pp. 1515–1548, 1999. View at Publisher · View at Google Scholar · View at Scopus
  14. I. Manners, “Polymer science with transition metals and main group elements: towards functional, supramolecular inorganic polymeric materials,” Journal of Polymer Science A, vol. 40, no. 2, pp. 179–191, 2002. View at Publisher · View at Google Scholar · View at Scopus
  15. W. A. De Heer, A. Châtelain, and D. Ugarte, “A carbon nanotube field-emission electron source,” Science, vol. 270, no. 5239, pp. 1179–1180, 1995. View at Scopus
  16. S. J. Tans, A. R. M. Verschueren, and C. Dekker, “Room-temperature transistor based on a single carbon nanotube,” Nature, vol. 393, no. 6680, pp. 49–52, 1998. View at Publisher · View at Google Scholar · View at Scopus
  17. D. H. Lee, D. O. Shin, W. J. Lee, and S. O. Kim, “Hierarchically organized carbon nanotube arrays from self-assembled block copolymer nanotemplates,” Advanced Materials, vol. 20, no. 13, pp. 2480–2485, 2008. View at Publisher · View at Google Scholar · View at Scopus
  18. A. Javey and H. Dai, “Regular arrays of 2 nm metal nanoparticles for deterministic synthesis of nanomaterials,” Journal of the American Chemical Society, vol. 127, no. 34, pp. 11942–11943, 2005. View at Publisher · View at Google Scholar · View at Scopus
  19. Y. Li, W. Kim, Y. Zhang, M. Rolandi, D. Wang, and H. Dai, “Growth of single-walled carbon nanotubes from discrete catalytic nanoparticles of various sizes,” Journal of Physical Chemistry B, vol. 105, no. 46, pp. 11424–11431, 2001. View at Publisher · View at Google Scholar · View at Scopus
  20. C. L. Cheung, A. Kurtz, H. Park, and C. M. Lieber, “Diameter-controlled synthesis of carbon nanotubes,” Journal of Physical Chemistry B, vol. 106, no. 10, pp. 2429–2433, 2002. View at Publisher · View at Google Scholar · View at Scopus
  21. L. An, J. M. Owens, L. E. McNeil, and J. Liu, “Synthesis of nearly uniform single-walled carbon nanotubes using identical metal-containing molecular nanoclusters as catalysts,” Journal of the American Chemical Society, vol. 124, no. 46, pp. 13688–13689, 2002. View at Publisher · View at Google Scholar · View at Scopus
  22. J. Q. Lu, T. E. Kopley, N. Moll et al., “High-quality single-walled carbon nanotubes with small diameter, controlled density, and ordered locations using a polyferrocenylsilane block copolymer catalyst precursor,” Chemistry of Materials, vol. 17, no. 9, pp. 2227–2231, 2005. View at Publisher · View at Google Scholar · View at Scopus
  23. J. Lu, S. S. Yi, T. Kopley, C. Qian, J. Liu, and E. Gulari, “Fabrication of ordered catalytically active nanoparticles derived from block copolymer micelle templates for controllable synthesis of single-walled carbon nanotubes,” Journal of Physical Chemistry B, vol. 110, no. 13, pp. 6655–6660, 2006. View at Publisher · View at Google Scholar · View at Scopus
  24. S. Lastella, Y. J. Jung, H. Yang et al., “Density control of single-walled carbon nanotubes using patterned iron nanoparticle catalysts derived from phase-separated thin films of a polyferrocene block copolymer,” Journal of Materials Chemistry, vol. 14, no. 12, pp. 1791–1794, 2004. View at Publisher · View at Google Scholar · View at Scopus
  25. K. Temple, K. Kulbaba, K. N. Power-Billard et al., “Spontaneous vertical ordering and pyrolytic formation of nanoscopic ceramic patterns from poly(styrene-b-ferrocenylsilane),” Advanced Materials, vol. 15, no. 4, pp. 297–300, 2003. View at Publisher · View at Google Scholar
  26. C. Hinderling, Y. Keles, T. Stöckli et al., “Organometallic block copolymers as catalyst precursors for templated carbon nanotube growth,” Advanced Materials, vol. 16, no. 11, pp. 876–879, 2004. View at Publisher · View at Google Scholar · View at Scopus
  27. J. Q. Lu, D. A. Rider, E. Onyegam et al., “Carbon nanotubes with small and tunable diameters from poly(ferrocenylsilane)-block-Polysiloxane diblock copolymers,” Langmuir, vol. 22, no. 11, pp. 5174–5179, 2006. View at Publisher · View at Google Scholar · View at Scopus
  28. T. Hirai, M. Leolukman, C. C. Liu et al., “One-step direct-patterning template utilizing self-assembly of POSS-containing block copolymers,” Advanced Materials, vol. 21, no. 43, pp. 4334–4338, 2009. View at Publisher · View at Google Scholar
  29. T. Hirai, M. Leolukman, S. Jin et al., “Hierarchical self-assembled structures from POSS-containing block copolymers synthesized by living anionic polymerization,” Macromolecules, vol. 42, no. 22, pp. 8835–8843, 2009. View at Publisher · View at Google Scholar · View at Scopus
  30. Y. Ishida, Y. Tada, T. Hirai et al., “Directed self-assembly of cage silsesquioxane containing block copolymers via graphoepitaxy techniques,” Journal of Photopolymer Science and Technology, vol. 23, no. 2, pp. 155–159, 2010. View at Publisher · View at Google Scholar
  31. Y. Ishida, T. Hirai, R. Goseki, M. Tokita, M. Kakimoto, and T. Hayakawa, “Synthesis and self-assembly of thermotropic block copolymer with long alkyl tethered cage silsesquioxane in the side chain,” Journal of Polymer Science A, vol. 49, no. 12, pp. 2653–2664, 2011.
  32. R. Goseki, T. Hirai, Y. Ishida, M. Kakimoto, and T. Hayakawa, “Rapid and reversible morphology control in thin films of poly(ethylene oxide)-block-POSS containing poly(methacrylate),” Polymer Journal, vol. 44, pp. 658–664, 2012.
  33. Y. Tada, H. Yoshida, Y. Ishida et al., “Directed self-assembly of POSS containing block copolymer on lithographically defined chemical template with morphology control by solvent vapor,” Macromolecules, vol. 45, no. 1, pp. 292–304, 2012.
  34. C. U. Pittman, “Anionic homopolymerization of ferrocenylmethyl methacrylate,” Journal of Polymer Science Part A, vol. 15, no. 7, pp. 1677–1686, 1977. View at Scopus
  35. T. Higashihara and R. Faust, “Synthesis of novel block copolymers comprised of polyisobutylene and poly(vinylferrocene) segments,” Macromolecules, vol. 40, no. 21, pp. 7453–7463, 2007. View at Publisher · View at Google Scholar · View at Scopus
  36. F. Yan, T. Higashihara, R. Mosurkal et al., “Self organization and redox behavior of poly(vinylferrocene)-block- poly(isobutylene)-block-poly(vinylferrocene) triblock copolymer,” Journal of Macromolecular Science A, vol. 45, no. 11, pp. 911–914, 2008. View at Publisher · View at Google Scholar · View at Scopus
  37. Y. Yang, Z. Xie, and C. Wu, “Novel synthesis and characterization of side-chain ferrocene-containing polymers,” Macromolecules, vol. 35, no. 9, pp. 3426–3432, 2002. View at Publisher · View at Google Scholar · View at Scopus
  38. M. Gallei, B. V. K. J. Schmidt, R. Klein, and M. Rehahn, “Defined poly[styrene-block-(ferrocenylmethyl methacrylate)] diblock copolymers via living anionic polymerization,” Macromolecular Rapid Communications, vol. 30, no. 17, pp. 1463–1469, 2009. View at Publisher · View at Google Scholar · View at Scopus
  39. M. Gallei, S. Tockner, R. Klein, and M. Rehahn, “Silacydobutane-based diblock copolymers with vinylferrocene, ferrocenylmethyl methacrylate, and [1]dimethylsilaferrocenophane,” Macromolecular Rapid Communications, vol. 31, no. 9-10, pp. 889–896, 2010. View at Publisher · View at Google Scholar · View at Scopus
  40. J. K. Lindsay and C. R. Hauser, “Aminomethylation of ferrocene to form N,N-dimethylaminomethylferrocene and its conversion to the corresponding alcohol and aldehyde,” Journal of Organic Chemistry, vol. 22, no. 4, pp. 355–358, 1957. View at Scopus