(a) For the CHMMA polymer, the specific retention volume values of alcohols (cm 3/g) are calculated over the period of retention between 313 and 423 K |
| (K) | Ethyl alcohol | 1-Propyl alcohol | 1-Butyl alcohol | 1-Pentyl alcohol | Probe volume | 0,3 μl | 0,6 μl | 0,9 μl | 0,3 μl | 0,6 μl | 0,9 μl | 0,3 μl | 0,6 μl | 0,9 μl | 0,3 μl | 0,6 μl | 0,9 μl |
| 423 | 8,781 | 9,151 | 9,178 | 10,088 | 10,124 | 10,146 | 10,917 | 11,457 | 11,939 | 14,303 | 14,7 | 14,843 | 413 | 9,623 | 10,207 | 9,997 | 11,727 | 11,921 | 11,777 | 13,48 | 13,597 | 13,595 | 18,467 | 19,012 | 18,632 | 403 | 10,096 | 10,54 | 10,903 | 12,236 | 12,6 | 12,761 | 16,275 | 16,517 | 16,961 | 22,979 | 23,284 | 23,786 | 393 | 11,146 | 11,404 | 12,093 | 14,201 | 14,503 | 14,718 | 19,065 | 19,323 | 17,667 | 27,979 | 29,264 | 29,824 | 383 | 11,914 | 12,372 | 13,059 | 16,084 | 16,267 | 16,496 | 22,591 | 22,682 | 21,186 | 34,184 | 36,979 | 38,079 | 373 | 14,489 | 14,636 | 15,225 | 18,221 | 18,762 | 19,155 | 26,08 | 26,767 | 27,897 | 43,614 | 46,365 | 47,887 | 363 | 16,839 | 17,259 | 17,574 | 20,459 | 20,879 | 21,141 | 31,161 | 33,254 | 34,046 | 61,745 | 67,254 | 69,824 | 353 | 18,694 | 19,595 | 19,877 | 23,762 | 24,269 | 25,226 | 36,826 | 39,079 | 42,968 | 75,23 | 80,917 | 88,238 | 343 | 21,039 | 21,566 | 22,111 | 26,48 | 27,261 | 30,896 | 45,343 | 46,95 | 55,128 | 85,73 | 98,928 | 111,832 | 333 | 21,3 | 21,33 | 22,528 | 27,403 | 27,505 | 32,155 | 44,905 | 49,523 | 61,957 | 91,04 | 104,534 | 122,672 | 323 | 26,109 | 27,927 | 31,128 | 34,473 | 42,037 | 43,419 | 56,655 | 68,728 | 93,893 | 121,312 | 151,785 | 193,532 | 313 | 32,81 | 34,624 | 38,174 | 51,187 | 54,027 | 63,728 | 73,463 | 112,629 | 131,006 | 226,599 | 243,399 | 317,696 |
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(b) For the CHMMA polymer, the specific retention volume values of alkanes (cm 3/g) are calculated over the period of retention between 313 and 423 K |
| (K) | n-Hexane | n-Heptane | n-Octane | n-Nonane | Probe volume | 0,3 μl | 0,6 μl | 0,9 μl | 0,3 μl | 0,6 μl | 0,9 μl | 0,3 μl | 0,6 μl | 0,9 μl | 0,3 μl | 0,6 μl | 0,9 μl |
| 423 | 10,7 | 10,953 | 11,831 | 8,935 | 9,403 | 10,003 | 9,475 | 10,376 | 11,007 | 11,385 | 12,394 | 12,979 | 413 | 12,389 | 12,701 | 12,762 | 10,051 | 10,246 | 10,982 | 11,493 | 12,072 | 12,345 | 14,415 | 14,921 | 15,375 | 403 | 13,044 | 13,205 | 13,569 | 10,742 | 10,903 | 11,792 | 12,196 | 12,519 | 13,449 | 15,305 | 15,709 | 16,598 | 393 | 13,986 | 14,546 | 14,89 | 11,619 | 11,834 | 12,695 | 13,082 | 13,599 | 14,46 | 16,698 | 17,042 | 18,075 | 383 | 14,938 | 15,305 | 15,58 | 12,555 | 12,739 | 13,655 | 14,205 | 14,709 | 15,58 | 19,016 | 19,52 | 20,208 | 373 | 16,208 | 16,553 | 17,092 | 13,604 | 13,752 | 15,127 | 15,324 | 16,453 | 16,748 | 20,923 | 21,856 | 22,838 | 363 | 17,731 | 17,836 | 18,361 | 14,741 | 15,265 | 16,525 | 17,731 | 18,203 | 19,095 | 24,341 | 24,918 | 27,803 | 353 | 19,145 | 19,595 | 19,877 | 16,498 | 17,625 | 18,019 | 19,708 | 20,271 | 20,947 | 27,38 | 30,801 | 33,223 | 343 | 21,039 | 22,293 | 23,868 | 18,077 | 19,99 | 20,536 | 22,611 | 25,171 | 24,383 | 34,4 | 39,287 | 42,467 | 333 | 21,044 | 22,213 | 23,528 | 18,8 | 20,776 | 21,567 | 25,162 | 27,44 | 28,717 | 40,134 | 45,8 | 50,356 | 323 | 25,091 | 27,709 | 30,4 | 24,436 | 26,4 | 28,581 | 36,437 | 40,655 | 43,783 | 67,056 | 67,71 | 78,401 | 313 | 33,284 | 33,757 | 39,12 | 32,81 | 35,886 | 40,382 | 59,39 | 65,7 | 67,277 | 112,55 | 135,096 | 147,618 |
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