Research Article
Investigation of the Specific Retention Volume of the Probe Volume and the Effects on the Polymer-Probe System by Inverse Gas Chromatography
Table 4
The sorption-related entropy values of the probe-CHMMA polymer system.
| (K) | (J/mol) | 353 | 363 | 373 | 383 | 0,3 μl | 0,6 μl | 0,9 μl | 0,3 μl | 0,6 μl | 0,9 μl | 0,3 μl | 0,6 μl | 0,9 μl | 0,3 μl | 0,6 μl | 0,9 μl |
| Ethyl alcohol | −26386,08 | −26774 | −25175 | −26973 | −27424 | −25813 | −27719 | −28213 | −26534 | −28635 | −29040 | −27311 | 1-Propyl alcohol | −22544,22 | −22780 | −23359 | −23225 | −23461 | −24117 | −23826 | −24062 | −24662 | −24475 | −24711 | −25385 | 1-Butyl alcohol | −24653,90 | −26790 | −31783 | −25333 | −27447 | −32648 | −26075 | −28304 | −33448 | −26736 | −29033 | −34523 | 1-Pentyl alcohol | −34067,51 | −33911 | −35676 | −34765 | −34565 | −36470 | −35962 | −35829 | −37748 | −36884 | −36691 | −38617 | n-Hexane | −17019,61 | −16762 | −16568 | −17468 | −17261 | −17021 | −17970 | −17781 | −17628 | −18461 | −18271 | −18119 | n-Heptane | −17789,91 | −19607 | −17726 | −18347 | −20253 | −18197 | −18822 | −20800 | −18688 | −19310 | −21276 | −19238 | n-Octane | −19433,73 | −18621 | −18035 | −19944 | −19134 | −18501 | −20597 | −19646 | −19101 | −21050 | −20209 | −19536 | n-Nonane | −19460,79 | −22053 | −23883 | −19970 | −22837 | −24558 | −20604 | −23406 | −25322 | −21085 | −23939 | −25881 |
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