|
Sample (s) | Analyte | Remarks | Pre concentration factor | LOD(μg/L) | Complexing agent | Ref. |
|
Water and certified reference material | Ag | Novel flow injection (FI) online displacement SPE | 110 | 0.2 | Sodium diethyl dithiocarbamate | [262] |
Water | Cd | New simple flow injection wetting film extraction was desenvolved and used diisobutyl ketone (DIBK) as extraction solvent | 35 | 0.7 | Diethyl dithiocarbamate | [263] |
Water | Cu | The microextraction was realized using of ethanol as dispersive solvent and 1,2-DCB as extraction solvent. |
*
| 0.5 |
**
| [264] |
Water | Cu (II) | Dispersive liquid-liquid microextraction (DLLME) method using dispersive solvent as methanol | 42 | 3 | 8-Hydroxy quinoline | [265] |
Water | Cu and Pb | Online sequential injection (SI) dispersive liquid-liquid microextraction (DLLME) | 560 and 265 | 0.04 and 0.54 | ammonium diethyldithiophosphate | [266] |
Water, vegetable, Rice and spices | Cu(II) and Fe(III) | SPE method was developed for the determination of the elements | 50.0 | 0.82 and 1.05 | N-benzoyl-N-phenylhydroxylamine | [267] |
Water | Mn | On-line preconcentration procedure using flow injection with determination by FAAS | 30 | 12.0 and 16.0 | 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrin | [268] |
Seawater, stream water, well water and vegetable | Cd and Pb | Cu(II)-mercaptobenzothiazole was used as a new coprecipitant | 150 | 0.04 and 1.08 |
**
| [269] |
Water | Ag | Dispersive liquid-liquid microextraction method with microsample introduction | 575 | 0.018 | Dithizone | [270] |
Seawater, urine, mineral water, soil and physiological solution | Pb(II) and Fe(III) | Coprecipitation using the violuric acid-copper(II) system and optimization step using two-level full factorial desig |
*
| 0.16 and 0.18 |
**
| [271] |
Synthetic metal mixture solution and river water | Pb(II), Cu(II), Cd(II), and Ni(II) | New chelating was used to preconcentrate the metals | ~ 200 and ~100 for Cd(II) | 0.58, 0.86, 0.65 and 0.92 | silica gel modified with gallic acid (GASG) | [272] |
River water and Sewage water | Cu | SPE method and copper complex was adsorbed on the naphthalene column | 40 | 2.0 | Methylthymol blue | [273] |
Environmental | Fe (III), Cu (II), Cr (III), Zn (II), and Pb (II) | New co-precipitation method was developed using an organic coprecipitant, 3-benzyl-4-p-nitrobenzylidenamino-4,5-dihydro-1,2,4-triazole-5-on (BPNBAT) without any carrier element | 150, 150, 100, 100, and 50 | 0.7, 0.3, 0.4, 0.3, and 2.0 |
*
| [274] |
Natural water | Be, Pb, Ni, and Bi | Use of syringe loaded with sorbent for the separation and enrichment of the elements | 100 | 0.30, 0.25, 0.20, and 0.34 | 2 propylpiperidine -1-carbodithioate | [275] |
|