Research Article

A Study of the Deformation, Network, and Aging of Polyethylene Oxide Films by Infrared Spectroscopy and Calorimetric Measurements

Table 1

Characteristics of the melting traces of the PEO sample in different conditions.

Ramp
(K/min)
ΔHa
(J/g)
Tm
(°C)
Tc
(°C)
Events in the meltb,c
ΔHrelax
(J/g)
Trelax
(°C)

Standard51476146
Nonstandard0.05130684450–10080–110

a The value of c is found to be 0.72 from ΔH0 = 204 J/g.
b The value of ΔHrelax and the range of Trelax are sensitive to the conditions [2230, 36, 37].
c The signal in the melt is endothermic for a deformation and exothermic for a relaxation.