A Simulation Study of the Fundamental Vibrational Shifts of HCl Diluted in Ar, Kr, and Xe: Anharmonic Corrections Effects

<table>Theoretical solvent shifts <svg height="16.3125" id="M173" style="vertical-align:-3.3907pt" version="1.1" viewbox="0 0 49.849998 16.3125" width="49.849998" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
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</svg> (circle) and the Buckingham approach <svg height="20.237499" id="M174" style="vertical-align:-3.3907pt" version="1.1" viewbox="0 0 49.849998 20.237499" width="49.849998" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
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</svg> (square) for the HCl in Ar at <svg height="11.825" id="M175" style="vertical-align:-0.1638pt" version="1.1" viewbox="0 0 55.349998 11.825" width="55.349998" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
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</svg> K.</table>

International Journal of Spectroscopy

fig3

Figure 3

Figure 3: A Simulation Study of the Fundamental Vibrational Shifts of HCl Diluted in Ar, Kr, and Xe: Anharmonic Corrections Effects 