Line Intensity Measurements of the 𝜈₇+𝜈₈ Band of Ethylene (¹²C₂H₄)

Table 3

Line positions, assignments, and intensities of the 𝜈₇+𝜈₈ band of ¹²C₂H₄.

Peak no.	𝐽^′	𝐾^′𝑎	𝐾^′𝑐	𝐽^′′	𝐾𝑎^′′	𝐾𝑐^′′	Measured wavenumber (cm^−1)	O − C (cm^−1)	Line intensities [cm^−1/(cm atm)]		% Error
									Expt’l	Calc’d
1	19	3	16	20	3	17	1848.10619	0.00069	0.01606	0.01560	−2.971
2	21	1	20	22	1	21	1848.64789	−0.00055	0.01446	0.01426	−1.444
3	16	2	14	17	2	15	1854.62328	−0.00084	0.02340	0.02448	4.416
4	19	0	19	20	0	20	1855.23843	−0.00074	0.05011	0.05116	2.047
5	19	1	19	20	1	20	1855.28243	−0.00065	0.02256	0.02266	0.440
6	16	4	13	17	4	14	1856.28998	−0.00058	0.04276	0.04532	5.650
7	15	2	13	16	2	14	1856.70408	−0.00090	0.06124	0.06292	2.675
8	16	1	15	17	1	16	1856.76313	−0.00044	0.02648	0.02639	−0.325
9	18	0	18	19	0	19	1856.82825	−0.00067	0.02456	0.02458	0.076
10	15	3	12	16	3	13	1857.35152	−0.00017	0.02509	0.02532	0.902
11	15	4	12	16	4	13	1858.33672	−0.00039	0.02055	0.02115	2.876
12	14	2	12	15	2	13	1858.81149	−0.00096	0.02864	0.02930	2.245
13	16	0	16	17	0	17	1860.01569	−0.00065	0.03085	0.02989	−3.240
14	16	1	16	17	1	17	1860.11702	−0.00073	0.02960	0.02988	0.934
15	14	1	13	15	1	14	1860.18831	−0.00043	0.03299	0.03133	−5.310
16	14	4	11	15	4	12	1860.37046	−0.00024	0.05120	0.05299	3.380
17	13	2	11	14	2	12	1860.93859	−0.00086	0.06963	0.07323	4.921
18	15	1	15	16	1	16	1861.74391	−0.00072	0.03209	0.03239	0.927
19	13	6	7	14	6	8	1862.56749	0.00067	0.04786	0.04859	1.513
20	12	2	10	13	2	11	1863.07805	−0.00085	0.03328	0.03311	−0.510
21	13	2	12	14	2	13	1863.15373	−0.00080	0.03355	0.03254	−3.104
22	14	0	14	15	0	15	1863.21161	−0.00058	0.03543	0.03471	−2.079
23	14	1	14	15	1	15	1863.37938	−0.00069	0.03465	0.03469	0.123
24	12	1	11	13	1	12	1863.78464	−0.00054	0.03439	0.03536	2.747
25	12	3	9	13	3	10	1863.94266	−0.00074	0.02858	0.02960	3.440
26	11	3	8	12	3	9	1866.04610	−0.00088	0.03105	0.03049	−1.836
27	12	1	12	13	1	13	1866.67826	−0.00071	0.03791	0.03828	0.963
28	11	2	10	12	2	11	1866.80502	−0.00078	0.03435	0.03516	2.313
29	10	2	8	11	2	9	1867.36336	−0.00095	0.03383	0.03504	3.444
30	10	1	9	11	1	10	1867.54113	−0.00063	0.03787	0.03765	−0.588
31	10	3	7	11	3	8	1868.10596	−0.00077	0.03138	0.03081	−1.853
32	10	3	8	11	3	9	1868.28975	−0.00089	0.03255	0.03089	−5.360
33	9	1	8	10	1	9	1869.46527	−0.00067	0.03780	0.03786	0.176
34	9	2	7	10	2	8	1869.49207	−0.00081	0.07921	0.08174	3.103
35	10	1	10	11	1	11	1870.01782	−0.00067	0.03948	0.03990	1.037
36	9	3	6	10	3	7	1870.12636	−0.00092	0.03106	0.03045	−2.017
37	9	3	7	10	3	8	1870.23830	−0.00100	0.03038	0.03050	0.379
38	9	4	6	10	4	7	1870.31021	−0.00038	0.08089	0.08210	1.470
39	9	5	5	10	5	6	1870.40586	0.00016	0.03628	0.03704	2.035
40	9	0	9	10	0	10	1871.28500	−0.00062	0.08776	0.09346	6.102
41	8	1	7	9	1	8	1871.41065	−0.00066	0.03654	0.03734	2.132
42	8	2	6	9	2	7	1871.59872	−0.00082	0.03386	0.03427	1.192
43	9	1	9	10	1	10	1871.70380	−0.00041	0.04055	0.03974	−2.031
44	8	0	8	9	0	9	1872.94192	−0.00074	0.03965	0.03931	−0.865
45	8	1	8	9	1	9	1873.39988	−0.00066	0.03836	0.03885	1.264
46	7	2	5	8	2	6	1873.67558	0.00003	0.07336	0.07621	3.739
47	7	3	4	8	3	5	1874.07039	−0.00074	0.02819	0.02735	−3.083
48	7	4	4	8	4	5	1874.18383	−0.00073	0.06605	0.06964	5.155
49	7	2	6	8	2	7	1874.2107	−0.00061	0.03404	0.03289	−3.484
50	7	5	3	8	5	4	1874.27146	−0.00066	0.02911	0.02857	−1.869
51	7	0	7	8	0	8	1874.62617	−0.00062	0.08373	0.08825	5.122
52	6	5	2	7	5	3	1876.18440	−0.00072	0.02076	0.02160	3.899
53	6	0	6	7	0	7	1876.34147	−0.00057	0.03586	0.03554	−0.909
54	6	1	6	7	1	7	1876.82250	−0.00061	0.03563	0.03465	−2.824
55	5	1	4	6	1	5	1877.30902	−0.00069	0.03059	0.03073	0.458
56	5	2	3	6	2	4	1877.71216	−0.00056	0.06023	0.06230	3.326
57	5	1	5	6	1	6	1878.54707	−0.00056	0.03122	0.03130	0.256
58	4	2	2	5	2	3	1879.67047	−0.00048	0.02164	0.02223	2.661
59	4	1	4	5	1	5	1880.27874	−0.00061	0.02718	0.02713	−0.200
60	3	1	2	4	1	3	1881.2420	−0.00060	0.02281	0.02194	−3.970
61	3	2	1	4	2	2	1881.59210	−0.00029	0.03805	0.03881	1.951
62	3	1	3	4	1	4	1882.01624	−0.00051	0.02253	0.02213	−1.780
63	2	1	2	3	1	3	1883.75761	−0.00057	0.01734	0.01630	−6.386
64	4	1	4	3	1	3	1895.92667	−0.00056	0.02389	0.02306	−3.592
65	4	0	4	3	0	3	1896.15857	−0.00065	0.02545	0.02499	−1.835
66	4	2	3	3	2	2	1896.23848	−0.00044	0.04011	0.04055	1.083
67	4	2	2	3	2	1	1896.28176	−0.00034	0.01777	0.01738	−2.226
68	4	1	3	3	1	2	1896.47926	−0.00063	0.02295	0.02295	0.008
69	5	1	5	4	1	4	1897.64824	−0.00057	0.02920	0.02856	−2.219
70	5	0	5	4	0	4	1897.90300	−0.00069	0.06879	0.07038	2.260
71	6	1	6	5	1	5	1899.36413	−0.00061	0.03363	0.03330	−0.981
72	6	0	6	5	0	5	1899.62494	−0.00064	0.03432	0.03465	0.955
73	6	2	5	5	2	4	1899.77723	−0.00054	0.06549	0.06667	1.769
74	6	1	5	5	1	4	1900.10630	−0.00061	0.03410	0.03289	−3.656
75	7	1	7	6	1	6	1901.07464	−0.00064	0.03734	0.03724	−0.261
76	7	0	7	6	0	6	1901.32589	−0.00069	0.08671	0.08953	3.142
77	7	4	3	6	4	2	1901.67885	−0.00084	0.06004	0.06347	5.407
78	7	2	5	6	2	4	1901.72320	−0.00076	0.07384	0.07622	3.127
79	7	5	2	6	5	1	1901.74327	−0.00048	0.02443	0.02331	−4.805
80	8	1	8	7	1	7	1902.78030	−0.00068	0.04118	0.04035	−2.046
81	8	0	8	7	0	7	1903.00952	−0.00067	0.04122	0.04128	0.131
82	8	2	7	7	2	6	1903.26718	−0.00069	0.07925	0.08368	5.293
83	8	3	6	7	3	5	1903.38554	−0.00083	0.03151	0.02986	−5.501
84	8	3	5	7	3	4	1903.40236	−0.00088	0.02999	0.02986	−0.408
85	8	5	4	7	5	3	1903.48914	−0.00039	0.02967	0.03117	4.811
86	8	2	6	7	2	5	1903.53266	−0.00072	0.03610	0.03582	−0.796
87	8	1	7	7	1	6	1903.64766	−0.00060	0.03873	0.03942	1.754
88	9	1	9	8	1	8	1904.48187	−0.00069	0.04269	0.04261	−0.181
89	9	0	9	8	0	8	1904.68064	−0.00068	0.09736	0.10117	3.759
90	9	2	8	8	2	7	1904.99430	−0.00073	0.03804	0.03814	0.258
91	9	3	7	8	3	6	1905.13308	−0.00097	0.03196	0.03239	1.312
92	9	5	5	8	5	4	1905.22533	0.00033	0.03566	0.03708	3.823
93	9	2	7	8	2	6	1905.33298	−0.00080	0.08518	0.08876	4.041
94	9	1	8	8	1	7	1905.38538	−0.00066	0.04257	0.04135	−2.948
95	10	1	10	9	1	9	1906.18023	−0.00068	0.04431	0.04404	−0.606
96	10	0	10	9	0	9	1906.34476	−0.00062	0.04372	0.04462	2.022
97	10	2	9	9	2	8	1906.71002	−0.00079	0.08937	0.09230	3.178
98	10	1	9	9	1	8	1907.10144	−0.00056	0.04345	0.04241	−2.436
99	10	2	8	9	2	7	1907.11905	−0.00094	0.03971	0.03936	−0.868
100	12	1	12	11	1	11	1909.57111	−0.00073	0.04447	0.04453	0.149
101	12	0	12	11	0	11	1909.67100	−0.00035	0.04414	0.04486	1.608
102	12	3	9	11	3	8	1910.40373	−0.00068	0.03404	0.03492	2.519
103	12	1	11	11	1	10	1910.47072	−0.00054	0.04105	0.04215	2.613
104	13	1	13	12	1	12	1911.26574	−0.00064	0.04612	0.04373	−5.480
105	13	2	12	12	2	11	1911.79607	−0.00068	0.03899	0.03920	0.539
106	14	0	14	13	0	13	1913.01332	−0.00060	0.04431	0.04249	−4.279
107	14	2	13	13	2	12	1913.47402	−0.00060	0.08445	0.08824	4.298
108	14	3	11	13	3	10	1913.85956	−0.00042	0.03315	0.03317	0.039
109	14	2	12	13	2	11	1914.04936	−0.00093	0.03640	0.03694	1.465
110	15	2	14	14	2	13	1915.14502	−0.00055	0.03635	0.03597	−1.073
111	15	3	12	14	3	11	1915.57036	0.00013	0.03122	0.03153	0.977
112	15	2	13	14	2	12	1915.72204	−0.00072	0.07749	0.08138	4.779
113	16	2	15	15	2	14	1916.81050	−0.00032	0.07632	0.07876	3.102
114	16	3	13	15	3	12	1917.26494	0.00018	0.02985	0.02953	−1.094
115	16	2	14	15	2	13	1917.37156	−0.00090	0.03252	0.03247	−0.157
116	17	1	16	16	1	15	1918.63389	−0.00040	0.03193	0.03197	0.117
117	17	3	14	16	3	13	1918.94100	0.00062	0.02739	0.02725	−0.515
118	18	1	18	17	1	17	1919.76121	−0.00056	0.03258	0.03271	0.389
119	18	0	18	17	0	17	1919.77121	−0.00077	0.03172	0.03274	3.106
120	18	1	17	17	1	16	1920.25070	−0.00056	0.03080	0.02914	−5.706
121	20	3	17	19	3	16	1923.83142	0.00046	0.02002	0.01974	−1.386
122	21	3	18	20	3	17	1925.41296	−0.00049	0.01821	0.01728	−5.359
123	22	1	21	21	1	20	1926.76828	−0.00060	0.01859	0.01809	−2.752