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ISRN Materials Science
Volume 2012 (2012), Article ID 763048, 6 pages
http://dx.doi.org/10.5402/2012/763048
Research Article

Red Fluorescence in Doped LaF𝟑:Nd𝟑+, Sm𝟑+ Nanocrystals Synthesized by Microwave Technique

1Department of Physics, Bhavan’s College, Andheri (W), Mumbai 400058, India
2Department of Physics, Material Research Lab, Birla College, Kalyan 421304, India
3National Institute of Science and Technology, Palur Hills, Behrampur 761008, Odisha, India
4Department of Physics, K M Agarwal College, Kalyan 421301, India

Received 18 April 2012; Accepted 5 July 2012

Academic Editors: K. S. Bartwal, B. Geng, and P. Pramanik

Copyright © 2012 S. G. Gaurkhede et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Hexagonal shaped LaF3 nanocrystals (NC) doped by Nd3+ and Sm3+ ions are synthesized using microwave technique. The prepared LaF3 sample was characterized by XRD to confirm the average crystalline size of the particle is close to 20 nm (JCPDS standard card (32-0483) of pure hexagonal LaF3 crystals). The Transmission Electron Microscope (TEM) analysis which indicates the size of the primary and secondary particle is in the range between 15 nm–20 nm. Scanning Electron Microscope (SEM) and Energy Dispersive X-ray (EDAX) spectrometry have been carried out. The functional groups of the synthesized nanoparticles were confirmed by Fourier transform infrared spectroscopy (FTIR). The luminescent properties of the nanoparticles have been observed by excitation and emission spectra. Energy transfer from Nd3+ to Sm3+ has been observed. The transparency of the crystals has been confirmed using UV-VIS spectra. UV-Visible absorption spectrum indicates an energy gap of 4.9 eV and shows presence of wide transparency window. Non Linear Optical (NLO) properties of the synthesized nanoparticles have been studied. It has been found that Second Harmonic Generation (SHG) efficiency of LaF3=Nd3+, Sm3+ is less than pure Potassium Dihydroxyl Phosphate (KDP) crystals.

1. Introduction

In recent years, the fields of luminescence and display materials have undergone a revival of sorts with the evolution to nanosized luminescent particles, driven primarily by an ever-increasing awareness of the unique physical and optical properties that differ from those of identical bulk materials as the size of the particle reduced to the nanometer region [1]. Studies on the luminescent properties of lanthanide-doped nanoparticles have attracted a great deal of interest since they are considered as potentially useful phosphors in lamps and display devices [2], components in optical telecommunication [3], active materials in lasers [4], new optoelectronics devices [5], up converters [68], magnetic resonance imaging (MRI) [9], and biological fluorescent labels [1012]. LaF3 nanocrystals are widely used in lubricants, additives in steel and metal alloy, electrode materials [13] chemical sensors, and biosensors [14]. LaF3 possesses low phonon energy and adequate thermal and environmental stability [15], and hence is an excellent host matrix [1618] for investigating luminescence properties. Nanoparticles of LaF3, doped with lanthanide ions, are studied in the past for their luminescence properties [1923]. In past, several investigations have been carried to study the optical properties of LaF3:Nd3+ [24] for their possible applications in optoelectronics devices. In many circumstances, the use of microwave dielectric heating as a nonclassical energy source has been shown to dramatically reduce processing times, increase product yields, and enhance product purity or material properties compared to conventionally processed experiments and hence is favored here for synthesis of LaF3: Nd3+, Sm3+ nanoparticles. Microwaveoven (Sharp Corporation) Sharp Carousel, made in Thailand, Model no R 210D operating voltage 230~240 V, 1.18 kW, current 5.2 A, with output power 800 W, operating at a frequency of 2.45 GHz equipped with an external autodialer temperature monitoring system was used for this purpose.

2. Experimental

2.1. Synthesis of Nanocrystals

LaF3: Nd3+ and Sm3+ nanocrystals were synthesized by an aqueous route using microwave oven for heating in low power range. The method is simple and cost effective. Water soluble LaCl3 + NdCl3 + SmCl3 (1 unit) and NH4F (3 units) are mixed to obtain a solution in 1 : 3 molar proportion [25]. We prepared a 10 mL homogenous mixture (in deionized water) in a 100 mL beaker using 0.064 mol of LaCl3 + NdCl3 + SmCl3, allowed a 10 mL solution of 0.576 mol NH4F to drip into this solution uniformly through a funnel attached with a stopper to facilitate control of dripping and placed the whole set up inside a conventional microwave set at low power range (in on-off mode set at 30 sec) for around 30 min. The low power range setting largely helped us avoiding spill off of the solution. A white ultrafine crystalline precipitate identified as doped LaF3 nanocrystals appears almost instantly having settled down to the bottom of the beaker. We stored this white precipitate in sealed tubes after washing it several times with deionized water, absolute methanol and acetone, and then drying it in microwave oven about 15 minutes. We subjected this specimen to detailed characterization and analysis.

LaF3: Nd3+ and Sm3+ nanocrystals were also prepared by using methanol in place of deionized water with the method given above.

3. Characterizations

Powder X-ray diffraction (XRD) measurements have been performed using a PANALYTICAL X’PERT PROMPD diffractometer model using Cu Kα radiation λ = 1.5405 A° with scanning rate of 2° per min in the 2Θ range from 0° to 80°. Transmission electron microscope (TEM) analysis has been carried out for different magnification by PHILIPS (CM 200), 0.24 nm resolution at an operating voltage of 200 kV. SEM images have been obtained using ZEISS ULTRA FESEM, with accelerating voltage from 0.1 kV to 30 kV at beam current up to 100 nA, resolution 0.8 nm at 30 kV, magnification 10x to 1000kx, and image structure down to 10 nm size. Energy dispersive X-ray (EDAX) spectrometry has been done using a Quanta 200 FEG scanning electron microanalysis instrument. The UV-visible spectrum of the samples was recorded in the spectral range of 200–800 nm using a double beam (Perkin Elmer Corp.) spectrophotometer. The fluorescence spectrum was measured on LS 45 luminescence spectrometer (Perkin Elmer Corp.) using a high energy pulsed Xenon source for excitation and FL Win Lab software. NLO studies for the measurements of SHG efficiency, are obtained through the crystalline powder sample by using Kurtz and Perry technique.

4. Result and Discussion

The XRD results are shown in Figure 1(b) which indicates that LaF3:Nd3+, Sm3+ nanoparticles are well crystallized, and the patterns are in good agreement with hexagonal structure (space group: 𝑃3𝑐𝑙 (165), cell = 0.7187×0.7187×0.735nm3, 𝛼=𝛽=90,𝛾=120) known for bulk LaF3 (JCPDS card no. 32-0483) [26]. The standard formula has been used for the determination of 𝑎, 𝑏, and 𝑐 parameters for hexagonal structure 1𝑑2=432+𝑘+𝑘2𝑎2+𝑙2𝑐2,(1) where , 𝑘, and 𝑙 are the Miller indices for the XRD peaks.

fig1
Figure 1: X-ray diffraction pattern of (A) LaF3 nanocrystals in dewater (B) LaF3 nanocrystals in methanol (both undoped), (b) XRD pattern of LaF3:Nd3+, Sm3+ nanocrystals.

The calculated cell parameters 𝑎=𝑏=0.7126nm and 𝑐=0.7255nm for the LaF3:Nd3+ Sm3+ nanoparticles are smaller than those of LaF3 nanoparticles (𝑎=𝑏=0.7187nm and 𝑐=0.735nm). The decrease in the lattice parameters of LaF3:Nd3+, Sm3+ nanoparticles can be attributed to the smaller radius of Nd3+ ion (0.99 nm) and Sm3+ ion (0.96 nm) as compared with that of La3+ ion (0.106 nm) [2729]. This indicates that Nd3+ ions and Sm3+ ions are doped into the LaF3 lattice and occupied the site of La3+ ions, with the formation of a LaF3: Nd3+, Sm3+ solid solution. The broadening of diffraction peaks for LaF3:Nd3+, Sm3+ nanoparticles is also shown by Figure 1, which reveals the nanocrystalline nature of the samples. According to Scherrer equation, 𝐷=0.90𝜆/𝛽cos𝜃, where 𝐷 is the average crystallite size, 𝜆 is the X-ray wavelength (0.15405 nm) 𝜃 and 𝛽 being the diffraction angle and full width at half maximum of an observed peak, respectively. After subtraction of the equipment broadening, the full width at half maximum (FWHM) of the strongest peak (111) at 2θ = 27.9° helps to calculate the average crystalline size of LaF3:Nd3+, Sm3+ nanoparticles as 15–20 nm.

The transmission electron microscopy (TEM) image in Figure 2 shows that the particles are well separated from each other. The nanocrystals have a hexagonal shape and a particle size of 6–20 nm. When these nanocrystals are incorporated in the polymer matrix, these particles are so small that the Rayleigh scattering can be nearly neglected. The selected area electron diffraction (SAED) pattern in Figure 2 inset shows three strong diffraction rings corresponding to the (002), (111), and (300) reflections, which is in agreement with the hexagonal LaF3 structure [30], suggesting that the original structure of LaF3 is retained even after the modification. The results are that particle size from TEM measurements is in agreement with those obtained from XRD studies.

763048.fig.002
Figure 2: TEM image of Nd3+, Sm3+ doped LaF3 nanocrystals (Inset: SAED spectra).

Figure 3 shows the particle morphology of the prepared nanocrystals by using SEM image of LaF3: Nd3+ and Sm3+ nanocrystals under low magnification. The hexagonal nanosized LaF3: Nd3+ and Sm3+ particles are seen as aggregates of microdimensions. These aggregates of nanocrystals of large dimensions and of assorted sizes have been observed.

763048.fig.003
Figure 3: SEM image of Nd3+, Sm3+ doped LaF3 nanocrystals.

Figure 4 shows energy dispersive (EDAX) spectra of the synthesized LaF3:Nd3+, Sm3+ nanoparticals. The peaks for the element, namely, lanthanide, neodymium, and samarium are clearly visible along with other trace (impurity) elements.

763048.fig.004
Figure 4: EDAX image of doped Nd3+, Sm3+ LaF3 nanocrystals.

Figure 5 has shown FTIR spectrum of the LaF3:Nd3+, Sm3+ nanocrystals. The characteristic absorption peaks have been observed in the range from 4000 cm−1 to 500 cm−1. The broad absorption band at about 3434 cm−1 can be attributed to 𝜈as (O–H) stretching and bending vibrations. The peaks at 2925 cm−1 and 2853 cm−1 can be attributed to 𝜈as (C–H) group of the long alkyl chain [31]. The characteristic IR peaks located at 1632 cm−1 could be assigned to 𝛿 (H2O) bending vibrations from the residual absorbed water and 1439 cm−1 can be assigned to the asymmetric (𝜈as) and symmetric (𝜈as) bending vibrations of 𝛿 (O–H) group from methanol. Other absorptions are obtained due to use of methanol and acetone while preparing the sample.

763048.fig.005
Figure 5: FTIR spectrum of the from Nd3+, Sm3+ doped LaF3 nanocrystals.

The excitation (monitored at 654 nm) and emission (excited at 357 nm) spectra of LaF3:Nd3+, Sm3+ nanocrystals are shown in Figure 6. The excited peak centered at around 327 nm corresponds to the transition 4𝐼9/24𝐷7/2 for Nd3+ ion and a transition of samarium ions from 6𝐻5/2 to 5𝐼5/2. The emission spectrum shows a typical band between 600 and 700 nm corresponding to the 4𝐼9/24𝐹9/2 transition of Nd3+ ions, with peak at 654 nm, corresponding to red coloured emission from the nanocrystals [32].

763048.fig.006
Figure 6: Excitation (𝜆em=654 nm) and emission (𝜆ex=357 nm) spectra of LaF3 nanocrystals doped Nd3+, Sm3+.

The energy level scheme of synthesized nanocrystals is shown in Figure 7. Here, Nd3+ energy levels arise from the 4𝑓3 electronic configurations. The emission from the 4𝑓25𝑑 higher lying states is in the UV range. Some transitions among 4𝑓3 levels of Nd3+ ion are spin-allowed, such as 4𝐼9/2, 4𝐹3/2,4𝐹5/2, 4𝐹7/2,4𝐹9/2,4𝐺7/2 or 4𝐹3/2,4𝐺7/2, 4𝐷3/2 but this is not valid for the remaining ones. Neodymium has been recognized as one of the most efficient rare-earth luminescence centers in minerals, while its emission has been found only in the IR part of the spectrum. Nevertheless, it is well known that Nd3+ may also generate UV-visible luminescence in certain matrixes, for example, in laser (YAG-Nd). The Nd3+ UV and visible luminescence spectra consists of many narrow lines whose half-widths reach only several cm−1. It has been found that the Nd3+ UV and visible luminescence depend on the excitation wavelength [33].

763048.fig.007
Figure 7: Energy level scheme of LaF3:Nd3+, Sm3+ nanocrystals.

The observed Nd3+ UV and visible luminescence spectra are interpreted in the following way: the most intense lines originates from level 2𝐹5/2 to 4𝐹5/2 of Nd3+ resulting in UV emission, 2𝐻9/2 (lines around 400 nm) to 4𝐹9/2 (lines around 435 nm) and 2𝐻11/2 (lines in the range 450–464 nm), to 4𝐺5/2 (lines around 480 nm) and to 2𝐺7/2 (lines around 488 nm). In minerals, such luminescence is mixed with other rare earth elements (REE) lines and hence is not detected by steady-state spectroscopy. Trivalent samarium (Sm3+) activated minerals usually display an intense luminescence spectrum with a distinct line structure in the red-orange part of the spectrum. The radiating term 4𝐺5/2 is separated from the nearest lower level 6𝐹11/2 by an energy interval of 7,500 cm−1. This distance is too large compared to the energy of phonons capable to accomplish an effective nonradiative relaxation of excited levels and these processes do not significantly affect the nature of the spectra in minerals. Thus, all detected lines of the Sm3+ luminescence take place from one excited level and are usually characterized by a long decay time [34]. UV-visible range investigated from the absorption spectra shows that the cut-off wavelength 𝜆max lies at 250 nm with a corresponding energy gap of 4.9 eV suggesting its use in optoelectronics devicesas shown in Figure 8.

763048.fig.008
Figure 8: UV-Vis absorption spectrum of LaF3:Nd3+, Sm3+ nanocrystals.

It is observed that the measured relative SHG efficiency of LaF3 doped Nd3+, Sm3+ in deionized water with KDP crystal is 0.281 and that of LaF3 doped Nd3+, Sm3+ in methanol with KDP crystal is 0.513 by using Kurtz and Perry technique [35].

5. Conclusions

Nanocrystals of LaF3:Nd3+, Sm3+ have been rapidly synthesized by chemical route using domestic microwave oven at low power range. Nanocrystals of hexagonal geometry with particle size varying from 15 nm to 20 nm have been located by TEM analysis which is in agreement with the average crystalline size obtained from XRD studies. SEM pattern shows dispersed particles with traces of aggregates; EDAX spectra confirm the elemental components in the nanocrystals. The FTIR spectrum has been used for identification of fundamental groups present in the material. The absorption edge in UV spectra is found at 250 nm (corresponding to 4.9 eV) and a wide window between 250 nm to 800 nm has been observed. Emission of red color (654 nm) has been observed for LaF3:Nd3+, Sm3+ nanocrystals at an excitation wavelength of 357 nm. It has been found that relative SHG efficiency of LaF3 = Ln3+ (Ln3+ = Nd3+, Sm3+) containing rare earth elements are less than pure KDP crystals.

Acknowledgments

Thanks are due the staff of TIFR, SAIF IIT Mumbai, IIT Madras, and ISFAL Punjab for providing experimental facilities. This work was partially supported by the University of Mumbai (Letter no. APD/237/70 OF 2010 dated 13/01/2010). S. G. Gaurkhede thanks Material research Lab, Birla College, for providing experimental facility and Bhavan’s College, Andheri (W), Mumbai for institutional support.

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