Review Article

Tin-Catalyzed Esterification and Transesterification Reactions: A Review

Table 8

Alcoholysis of soybean oil and methanolysis of different Brazilian vegetable oils catalyzed by sulfuric acid or Sn(II)-pyrone complexa.

EntryAlcoholH2SO4 catalystSn(II)-pyrone catalyst
Ester yield after 1 hour reaction (%)b

1Methyl1.437.1
2Ethyl1.08.3
3Propyl 4.2

EntryOilEster yield after 1 hour reaction (%)b

4Andiroba3.823
5Babaçu12.535.6
6Palm tree8.516.2

aReaction conditions: alcohol : vegetable oil : catalyst molar ratio (400 : 100 : 1), 60°C temperature, and magnetically stirred.