About this Journal Submit a Manuscript Table of Contents
ISRN Thermodynamics
Volume 2012 (2012), Article ID 204104, 3 pages
Research Article

The Born Formula Describes Enthalpy of Ions Solvation

Institute of Chemical Kinetics and Combustion, Novosibirsk State University, Novosibirsk 630090, Russia

Received 3 February 2012; Accepted 26 February 2012

Academic Editor: M. Manciu

Copyright © 2012 Nikolai Bazhin. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. M. Born, “Volumen und Hydratationswarme der Ionen,” Zeitschrift für Physik, vol. 1, pp. 45–48, 1920.
  2. N. Bjerrum and E. Larson, “Studien uber Ionenverteilungskoeffizienten I.,” Zeitschrift für Physikalische Chemie, vol. 127, pp. 358–384, 1927.
  3. P. W. Atkins and A. J. MacDermott, “The born equation and ionic solvation,” Journal of Chemical Education, vol. 59, no. 4, pp. 359–360, 1982. View at Scopus
  4. P. M. Qureshi, R. K. Varshney, and S. B. Singh, “Empirical correlations for the evaluation of the free energies of solvation of some gaseous monovalent ions,” Journal of Chemical Education, vol. 66, no. 11, pp. 903–906, 1989. View at Scopus
  5. D. Bashford and D. A. Case, “Generalized born models of macromolecular solvation effects,” Annual Review of Physical Chemistry, vol. 51, pp. 129–152, 2000. View at Scopus
  6. P. K. Yang and C. Lim, “The importance of excluded solvent volume effects in computing hydration free energies,” Journal of Physical Chemistry B, vol. 112, no. 47, pp. 14863–14868, 2008. View at Publisher · View at Google Scholar · View at PubMed · View at Scopus
  7. B. Roux, H. A. Yu, and M. Karplus, “Molecular basis for the born model of ion solvation,” Journal of Physical Chemistry, vol. 94, no. 11, pp. 4683–4688, 1990. View at Scopus
  8. G. F. de Lima, H. A. Duarte, and J. R. Pliego, “Dynamical discrete/continuum linear response shells theory of solvation: convergence test for NH4+ and OH ions in water solution using DFT and DFTB methods,” Journal of Physical Chemistry B, vol. 114, no. 48, pp. 15941–15947, 2010. View at Publisher · View at Google Scholar · View at PubMed · View at Scopus
  9. C. S. Babu and C. Lim, “Theory of ionic hydration: insights from molecular dynamics simulations and experiment,” Journal of Physical Chemistry B, vol. 103, no. 37, pp. 7958–7968, 1999. View at Scopus
  10. F. Hirata, P. Redfern, and R. M. Levy, “Viewing the born model for ion hydration through a microscope,” International Journal of Quantum Chemistry, vol. 15, pp. 179–190, 1988.
  11. Ya. I. Gerasimov, Ed., Physical Chemistry, Chimiya, Moscow, Russia, 1980.
  12. L. E. Steiner, Introduction to Chemical Thermodynamic, McGraw-Hill, New York, NY, USA, 2nd edition, 1948.
  13. N. M. Bazhin and V. N. Parmon, “Conversion of the chemical reaction energy into useful work in the Van't Hoff equilibrium box,” Journal of Chemical Education, vol. 84, no. 6, pp. 1053–1055, 2007. View at Scopus
  14. R. A. Alberty, Physical Chemislry, John Wiley & Sons, New York, NY, USA, 7th edition, 1987.