Table 6: Separation factor values (α) of the stereoisomers of some diols and their corresponding acetyl derivatives.

EntryT (°C)IALCOHOLαACαdiACα
RTRTRT

1452949.table.006a12011, 8312,621,0310,0813,681,079,239,501,34a

2452949.table.006b110trans14.23 (S,S)15.76 (R,R)1.1111.14 (S,S)12.13 (R,R)1.108.07 (S,S)9.26 (R,R)1.15 a
cis14.9710.2310.411.029.02

3452949.table.006c120trans14.1214.121.009.5810.151.065.886.861.17 a
cis14.6410.9711.251.027.79

T: GC analysis temperature, (°C); I: isomer; RT: retention time; AC: monoacetyl derivative; diAC: diacetyl derivative; the elution order of the acetylated enantiomers was assumed from the literature [34, 35]; a: 1H and 13C NMR spectral data in the appendix.