Research Article
Electrochemical Studies for Cation Recognition with Diazo-Coupled Calix[4]arenes
Table 2
Anodic peak potential differences between o-CAC or o-EAC and o-CAC– or o-EAC–metal ion complexes in DPVs.
| mV | Li+ | Na+ | K+ | Rb+ | Cs+ | Mg2+ | Ca2+ | Sr2+ | Ba2+ | Cu2+ | Zn2+ | Co2+ | Pb2+ | Cr2+ | Fe2+ | Fe3+ | Ni2+ |
| o-CAC | | −4 | 0 | −8 | 0 | −4 | −32 | −44 | −40 | −44 | −40 | −36 | −20 | −56 | −32 | −8 | −32 | −12 | | 12 | 4 | 4 | 4 | 8 | 12 | 16 | 16 | 16 | 4 | 12 | 12 | 20 | 12 | 24 | 24 | 8 |
| o-EAC | | −4 | −8 | −12 | −8 | −4 | −20 | −12 | −12 | −12 | −16 | −20 | −12 | −28 | −36 | −16 | −28 | −20 | | −4 | 0 | −4 | −4 | −4 | −4 | 0 | −4 | −4 | −8 | −4 | −4 | 0 | −8 | 0 | −4 | −4 |
|
|