Journal of Combustion http://www.hindawi.com The latest articles from Hindawi Publishing Corporation © 2014 , Hindawi Publishing Corporation . All rights reserved. Experimental Study of Gas Explosions in Hydrogen Sulfide-Natural Gas-Air Mixtures Thu, 21 Aug 2014 00:00:00 +0000 http://www.hindawi.com/journals/jc/2014/905893/ An experimental study of turbulent combustion of hydrogen sulfide (H2S) and natural gas was performed to provide reference data for verification of CFD codes and direct comparison. Hydrogen sulfide is present in most crude oil sources, and the explosion behaviour of pure H2S and mixtures with natural gas is important to address. The explosion behaviour was studied in a four-meter-long square pipe. The first two meters of the pipe had obstacles while the rest was smooth. Pressure transducers were used to measure the combustion in the pipe. The pure H2S gave slightly lower explosion pressure than pure natural gas for lean-to-stoichiometric mixtures. The rich H2S gave higher pressure than natural gas. Mixtures of H2S and natural gas were also studied and pressure spikes were observed when 5% and 10% H2S were added to natural gas and also when 5% and 10% natural gas were added to H2S. The addition of 5% H2S to natural gas resulted in higher pressure than pure H2S and pure natural gas. The 5% mixture gave much faster combustion than pure natural gas under fuel rich conditions. André Vagner Gaathaug, Dag Bjerketvedt, Knut Vaagsaether, and Sandra Hennie Nilsen Copyright © 2014 André Vagner Gaathaug et al. All rights reserved. Augmenting the Structures in a Swirling Flame via Diffusive Injection Wed, 13 Aug 2014 07:48:06 +0000 http://www.hindawi.com/journals/jc/2014/280501/ Small scale experimentation using particle image velocimetry investigated the effect of the diffusive injection of methane, air, and carbon dioxide on the coherent structures in a swirling flame. The interaction between the high momentum flow region (HMFR) and central recirculation zone (CRZ) of the flame is a potential cause of combustion induced vortex breakdown (CIVB) and occurs when the HMFR squeezes the CRZ, resulting in upstream propagation. The diffusive introduction of methane or carbon dioxide through a central injector increased the size and velocity of the CRZ relative to the HMFR whilst maintaining flame stability, reducing the likelihood of CIVB occurring. The diffusive injection of air had an opposing effect, reducing the size and velocity of the CRZ prior to eradicating it completely. This would also prevent combustion induced vortex breakdown CIVB occurring as a CRZ is fundamental to the process; however, without recirculation it would create an inherently unstable flame. Jonathan Lewis, Agustin Valera-Medina, Richard Marsh, and Steven Morris Copyright © 2014 Jonathan Lewis et al. All rights reserved. Testing Vegetation Flammability: The Problem of Extremely Low Ignition Frequency and Overall Flammability Score Thu, 26 Jun 2014 13:44:37 +0000 http://www.hindawi.com/journals/jc/2014/970218/ In the recent decades changes in fire regimes led to higher vulnerability of fire prone ecosystems, with vegetation being the only component influencing fire regime which can be managed in order to reduce probability of extreme fire events. For these management practices to be effective reliable information on the vegetation flammability is being crucial. Epiradiator based testing methods are one of the methods commonly used to investigate vegetation flammability and decrease in ignition frequency is always interpreted as a decrease in flammability. Furthermore, gathered information is often combined into a single flammability score. Here we present results of leaf litter testing which, together with previously conducted research on similar materials, show that material with very low ignition frequency under certain testing conditions can be extremely flammable if testing conditions are slightly changed. Additionally, our results indicate that combining measured information into one single flammability score, even though sometimes useful, is not always meaningful and should be performed with caution. Zorica Kauf, Andreas Fangmeier, Roman Rosavec, and Željko Španjol Copyright © 2014 Zorica Kauf et al. All rights reserved. Nonpremixed Counterflow Flames: Scaling Rules for Batch Simulations Sun, 22 Jun 2014 04:58:54 +0000 http://www.hindawi.com/journals/jc/2014/484372/ A method is presented to significantly improve the convergence behavior of batch nonpremixed counterflow flame simulations with finite-rate chemistry. The method is applicable to simulations with varying pressure or strain rate, as it is, for example, necessary for the creation of flamelet tables or the computation of the extinction point. The improvement is achieved by estimating the solution beforehand. The underlying scaling rules are derived from theory, literature, and empirical observations. The estimate is used as an initialization for the actual solver. This enhancement leads to a significantly improved robustness and acceleration of batch simulations. The extinction point can be simulated without cumbersome code extensions. The method is demonstrated on two test cases and the impact is discussed. Thomas Fiala and Thomas Sattelmayer Copyright © 2014 Thomas Fiala and Thomas Sattelmayer. All rights reserved. Development and Parametric Evaluation of a Tabulated Chemistry Tool for the Simulation of n-Heptane Low-Temperature Oxidation and Autoignition Phenomena Tue, 10 Jun 2014 00:00:00 +0000 http://www.hindawi.com/journals/jc/2014/237049/ Accurate modelling of preignition chemical phenomena requires a detailed description of the respective low-temperature oxidative reactions. Motivated by the need to simulate a diesel oil spray evaporation device operating in the “stabilized” cool flame regime, a “tabulated chemistry” tool is formulated and evaluated. The tool is constructed by performing a large number of kinetic simulations, using the perfectly stirred reactor assumption. n-Heptane is used as a surrogate fuel for diesel oil and a detailed n-heptane mechanism is utilized. Three independent parameters (temperature, fuel concentration, and residence time) are used, spanning both the low-temperature oxidation and the autoignition regimes. Simulation results for heat release rates, fuel consumption and stable or intermediate species production are used to assess the impact of the independent parameters on the system’s thermochemical behaviour. Results provide the physical and chemical insight needed to evaluate the performance of the tool when incorporated in a CFD code. Multidimensional thermochemical behaviour “maps” are created, demonstrating that cool flame activity is favoured under fuel-rich conditions and that cool flame temperature boundaries are extended with increasing fuel concentration or residence time. George Vourliotakis, Dionysios I. Kolaitis, and Maria A. Founti Copyright © 2014 George Vourliotakis et al. All rights reserved. Combustion Characteristics for Turbulent Prevaporized Premixed Flame Using Commercial Light Diesel and Kerosene Fuels Sun, 01 Jun 2014 09:20:02 +0000 http://www.hindawi.com/journals/jc/2014/363465/ Experimental study has been carried out for investigating fuel type, fuel blends, equivalence ratio, Reynolds number, inlet mixture temperature, and holes diameter of perforated plate affecting combustion process for turbulent prevaporized premixed air flames for different operating conditions. CO2, CO, H2, N2, C3H8, C2H6, C2H4, flame temperature, and gas flow velocity are measured along flame axis for different operating conditions. Gas chromatographic (GC) and CO/CO2 infrared gas analyzer are used for measuring different species. Temperature is measured using thermocouple technique. Gas flow velocity is measured using pitot tube technique. The effect of kerosene percentage on concentration, flame temperature, and gas flow velocity is not linearly dependent. Correlations for adiabatic flame temperature for diesel and kerosene-air flames are obtained as function of mixture strength, fuel type, and inlet mixture temperature. Effect of equivalence ratio on combustion process for light diesel-air flame is greater than for kerosene-air flame. Flame temperature increases with increased Reynolds number for different operating conditions. Effect of Reynolds number on combustion process for light diesel flame is greater than for kerosene flame and also for rich flame is greater than for lean flame. The present work contributes to design and development of lean prevaporized premixed (LPP) gas turbine combustors. Mohamed S. Shehata, Mohamed M. ElKotb, and Hindawi Salem Copyright © 2014 Mohamed S. Shehata et al. All rights reserved. Consistent Conditional Moment Closure Modelling of a Lifted Turbulent Jet Flame Using the Presumed -PDF Approach Mon, 19 May 2014 08:18:34 +0000 http://www.hindawi.com/journals/jc/2014/507459/ A lifted turbulent jet flame issuing into a vitiated coflow is investigated using the conditional moment closure. The conditional velocity (CV) and the conditional scalar dissipation rate (CSDR) submodels are chosen such that they are fully consistent with the moments of the presumed probability density function (PDF). The CV is modelled using the PDF-gradient diffusion model. Two CSDR submodels based on the double integration of the homogeneous and inhomogeneous mixture fraction PDF transport equations are implemented. The effect of CSDR modelling is investigated over a range of coflow temperatures () and the stabilisation mechanism is determined from the analysis of the transport budgets and the history of radical build-up ahead of the stabilisation height. For all , the balance between chemistry, axial convection, and micromixing, and the absence of axial diffusion upstream of the stabilisation height indicate that the flame is stabilized by autoignition. This conclusion is confirmed from the rapid build-up of ahead of , , and . The inhomogeneous CSDR modelling yields higher dissipation levels at the most reactive mixture fraction, which results in longer ignition delays and larger liftoff heights. The effect of the spurious sources arising from homogeneous modelling is found to be small but nonnegligible, mostly notably within the flame zone. Ahmad El Sayed and Roydon A. Fraser Copyright © 2014 Ahmad El Sayed and Roydon A. Fraser. All rights reserved. Numerical Simulation of the Deflagration-to-Detonation Transition in Inhomogeneous Mixtures Mon, 19 May 2014 07:22:23 +0000 http://www.hindawi.com/journals/jc/2014/686347/ In this study the hazardous potential of flammable hydrogen-air mixtures with vertical concentration gradients is investigated numerically. The computational model is based on the formulation of a reaction progress variable and accounts for both deflagrative flame propagation and autoignition. The model is able to simulate the deflagration-to-detonation transition (DDT) without resolving all microscopic details of the flow. It works on relatively coarse grids and shows good agreement with experiments. It is found that a mixture with a vertical concentration gradient can have a much higher tendency to undergo DDT than a homogeneous mixture of the same hydrogen content. In addition, the pressure loads occurring can be much higher. However, the opposite effect can also be observed, with the decisive factor being the geometric boundary conditions. The model gives insight into different modes of DDT. Detonations occurring soon after ignition do not necessarily cause the highest pressure loads. In mixtures with concentration gradient, the highest loads can occur in regions of very low hydrogen content. These new findings should be considered in future safety studies. Florian Ettner, Klaus G. Vollmer, and Thomas Sattelmayer Copyright © 2014 Florian Ettner et al. All rights reserved. Local Strain Rate and Curvature Dependences of Scalar Dissipation Rate Transport in Turbulent Premixed Flames: A Direct Numerical Simulation Analysis Thu, 03 Apr 2014 07:13:49 +0000 http://www.hindawi.com/journals/jc/2014/280671/ The statistical behaviours of the instantaneous scalar dissipation rate of reaction progress variable in turbulent premixed flames have been analysed based on three-dimensional direct numerical simulation data of freely propagating statistically planar flame and V-flame configurations with different turbulent Reynolds number . The statistical behaviours of and different terms of its transport equation for planar and V-flames are found to be qualitatively similar. The mean contribution of the density-variation term is positive, whereas the molecular dissipation term acts as a leading order sink. The mean contribution of the strain rate term is predominantly negative for the cases considered here. The mean reaction rate contribution is positive (negative) towards the unburned (burned) gas side of the flame, whereas the mean contribution of the diffusivity gradient term assumes negative (positive) values towards the unburned (burned) gas side. The local statistical behaviours of , , , , , and have been analysed in terms of their marginal probability density functions (pdfs) and their joint pdfs with local tangential strain rate and curvature . Detailed physical explanations have been provided for the observed behaviour. Y. Gao, N. Chakraborty, and N. Swaminathan Copyright © 2014 Y. Gao et al. All rights reserved. Experimental Gasification of Biomass in an Updraft Gasifier with External Recirculation of Pyrolysis Gases Thu, 23 Jan 2014 15:57:27 +0000 http://www.hindawi.com/journals/jc/2014/832989/ The updraft gasifier is a simple type of reactor for the gasification of biomass that is easy to operate and has high conversion efficiency, although it produces high levels of tar. This study attempts to observe the performance of a modified updraft gasifier. A modified updraft gasifier that recirculates the pyrolysis gases from drying zone back to the combustion zone and gas outlet at reduction zone was used. In this study, the level of pyrolysis gases that returned to the combustion zone was varied, and as well as measurements of gas composition, lower heating value and tar content. The results showed that an increase in the amount of pyrolysis gases that returned to the combustion zone resulted in a decrease in the amount of tar produced. An increase in the amount of recirculated gases tended to increase the concentrations of H2 and CH4 and reduce the concentration of CO with the primary (gasification) air flow held constant. Increasing the primary air flow tended to increase the amount of CO and decrease the amount of H2. The maximum of lower heating value was 4.9 MJ/m3. Adi Surjosatyo, Fajri Vidian, and Yulianto Sulistyo Nugroho Copyright © 2014 Adi Surjosatyo et al. All rights reserved. Large Eddy Simulation of a Bluff Body Stabilized Lean Premixed Flame Tue, 14 Jan 2014 07:10:49 +0000 http://www.hindawi.com/journals/jc/2014/710254/ The present study is devoted to verify current capabilities of Large Eddy Simulation (LES) methodology in the modeling of lean premixed flames in the typical turbulent combustion regime of Dry Low gas turbine combustors. A relatively simple reactive test case, presenting all main aspects of turbulent combustion interaction and flame stabilization of gas turbine lean premixed combustors, was chosen as an affordable test to evaluate the feasibility of the technique also in more complex test cases. A comparison between LES and RANS modeling approach is performed in order to discuss modeling requirements, possible gains, and computational overloads associated with the former. Such comparison comprehends a sensitivity study to mesh refinement and combustion model characteristic constants, computational costs, and robustness of the approach. In order to expand the overview on different methods simulations were performed with both commercial and open-source codes switching from quasi-2D to fully 3D computations. A. Andreini, C. Bianchini, and A. Innocenti Copyright © 2014 A. Andreini et al. All rights reserved. Influence of Sorbent Characteristics on Fouling and Deposition in Circulating Fluid Bed Boilers Firing High Sulfur Indian Lignite Mon, 09 Dec 2013 10:08:23 +0000 http://www.hindawi.com/journals/jc/2013/438384/ 125 MWe circulating fluidized bed combustion (CFBC) boiler experienced severe fouling in backpass of the boiler leading to obstruction of gas flow passage, while using high sulfur lignite with sorbent, calcium carbonate, to capture sulfur dioxide. Optical microscopy of the hard deposits showed mainly anhydrite (CaSO4) and absence of intermediate phases such as calcium oxide or presence of sulfate rims on decarbonated limestone. It is hypothesized that loose unreacted calcium oxides that settle on tubes are subjected to recarbonation and further extended sulfation resulting in hard deposits. Foul probe tests were conducted in selected locations of backpass for five different compositions of lignite, with varied high sulfur and ash contents supplied from the mines along with necessary rates of sorbent limestone to control SO2, and the deposits build-up rate was determined. The deposit build-up was found increasing, with increase in ash content of lignite, sorbent addition, and percentage of fines in limestone. Remedial measures and field modifications to dislodge deposits on heat transfer surfaces, to handle the deposits in ash conveying system, and to control sorbent fines from the milling circuit are explained. Selvakumaran Palaniswamy, M. Rajavel, A. Leela Vinodhan, B. Ravi Kumar, A. Lawrence, and A. K. Bakthavatsalam Copyright © 2013 Selvakumaran Palaniswamy et al. All rights reserved. Physical and Combustion Characteristics of Briquettes Made from Water Hyacinth and Phytoplankton Scum as Binder Mon, 30 Sep 2013 08:21:24 +0000 http://www.hindawi.com/journals/jc/2013/549894/ The study investigated the potential of water hyacinths and phytoplankton scum, an aquatic weed, as binder for production of fuel briquettes. It also evaluated some physical and combustion characteristics. The water hyacinths were manually harvested, cleaned, sun-dried, and milled to particle sizes distribution ranging from <0.25 to 4.75 mm using hammer mill. The water hyacinth grinds and binder (phytoplankton scum) at 10% (B1), 20% (B2), 30% (B3), 40% (B4), and 50% (B5) by weight of each feedstock were fed into a steel cylindrical die of dimension 14.3 cm height and 4.7 cm diameter and compressed by hydraulic press at pressure 20 MPa with dwell time of 45 seconds. Data were analysed using analysis of variance and descriptive statistics. Initial bulk density of uncompressed mixture of water hyacinth and phytoplankton scum at different binder levels varied between 113.86 ± 3.75 (B1) and 156.93 ± 4.82 kg/m3 (B5). Compressed and relaxed densities of water hyacinth briquettes at different binder proportions showed significant difference . Durability of the briquettes improved with increased binder proportion. Phytoplankton scum improved the mechanical handling characteristics of the briquettes. It could be concluded that production of water hyacinth briquettes is feasible, cheaper, and environmentally friendly and that they compete favourably with other agricultural products. R. M. Davies and O. A. Davies Copyright © 2013 R. M. Davies and O. A. Davies. All rights reserved. Effects of Electric Field on the SHS Flame Propagation of the Si-C System, Examined by the Use of the Heterogeneous Theory Tue, 24 Sep 2013 14:46:01 +0000 http://www.hindawi.com/journals/jc/2013/752068/ Relevant to the self-propagating high-temperature synthesis (SHS) process, an analytical study has been conducted to investigate the effects of electric field on the combustion behavior because the electric field is indispensable for systems with weak exothermic reactions to sustain flame propagation. In the present study, use has been made of the heterogeneous theory which can satisfactorily account for the premixed mode of the bulk flame propagation supported by the nonpremixed mode of particle consumption. It has been confirmed that, even for the SHS flame propagation under electric field, being well recognized to be facilitated, there exists a limit of flammability, due to heat loss, as is the case for the usual SHS flame propagation. Since the heat loss is closely related to the representative sizes of particles and compacted specimen, this identification provides useful insight into manipulating the SHS flame propagation under electric field, by presenting appropriate combinations of those sizes. A fair degree of agreement has been demonstrated through conducting an experimental comparison, as far as the trend and the approximate magnitude are concerned, suggesting that an essential feature has been captured by the present study. Atsushi Makino Copyright © 2013 Atsushi Makino. All rights reserved. A Comparison of the Characteristics of Planar and Axisymmetric Bluff-Body Combustors Operated under Stratified Inlet Mixture Conditions Tue, 10 Sep 2013 08:41:24 +0000 http://www.hindawi.com/journals/jc/2013/860508/ The work presents comparisons of the flame stabilization characteristics of axisymmetric disk and 2D slender bluff-body burner configurations, operating with inlet mixture stratification, under ultralean conditions. A double cavity propane air premixer formed along three concentric disks, supplied with a radial equivalence ratio gradient the afterbody disk recirculation, where the first flame configuration is stabilized. Planar fuel injection along the center plane of the leading face of a slender square cylinder against the approach cross-flow results in a stratified flame configuration stabilized alongside the wake formation region in the second setup. Measurements of velocities, temperatures, and chemiluminescence, local extinction criteria, and large-eddy simulations are employed to examine a range of ultralean and close to extinction flame conditions. The variations of the reacting front disposition within these diverse reacting wake topologies, the effect of the successive suppression of heat release on the near flame region characteristics, and the reemergence of large-scale vortical activity on approach to lean blowoff (LBO) are investigated. The cross-correlation of the performance of these two popular flame holders that are at the opposite ends of current applications might offer helpful insights into more effective control measures for expanding the operational margin of a wider range of stabilization configurations. G. Paterakis, K. Souflas, E. Dogkas, and P. Koutmos Copyright © 2013 G. Paterakis et al. All rights reserved. Homogeneous Charge Compression Ignition Combustion: Challenges and Proposed Solutions Mon, 26 Aug 2013 15:03:01 +0000 http://www.hindawi.com/journals/jc/2013/783789/ Engine and car manufacturers are experiencing the demand concerning fuel efficiency and low emissions from both consumers and governments. Homogeneous charge compression ignition (HCCI) is an alternative combustion technology that is cleaner and more efficient than the other types of combustion. Although the thermal efficiency and emission of HCCI engine are greater in comparison with traditional engines, HCCI combustion has several main difficulties such as controlling of ignition timing, limited power output, and weak cold-start capability. In this study a literature review on HCCI engine has been performed and HCCI challenges and proposed solutions have been investigated from the point view of Ignition Timing that is the main problem of this engine. HCCI challenges are investigated by many IC engine researchers during the last decade, but practical solutions have not been presented for a fully HCCI engine. Some of the solutions are slow response time and some of them are technically difficult to implement. So it seems that fully HCCI engine needs more investigation to meet its mass-production and the future research and application should be considered as part of an effort to achieve low-temperature combustion in a wide range of operating conditions in an IC engine. Mohammad Izadi Najafabadi and Nuraini Abdul Aziz Copyright © 2013 Mohammad Izadi Najafabadi and Nuraini Abdul Aziz. All rights reserved. FT-IR Investigation of the Structural Changes of Sulcis and South Africa Coals under Progressive Heating in Vacuum: Correlation with Volatile Matter Wed, 10 Jul 2013 11:15:41 +0000 http://www.hindawi.com/journals/jc/2013/134234/ The analysis of gas evolving during the pyrolysis of two very different rank coals was studied by using FT-IR spectroscopy. These coals, coming from Sulcis (Sardinia, Italy) and from South Africa, respectively, were subjected to progressive heating up to 800°C in vacuum. The thermal destruction of coal was followed by monitoring the production of gases in this range of temperature. The gases evolving in the heating from room temperature to 800°C were collected at intervals of 100°C and analysed by infrared spectroscopy. The relative pressures were plotted against temperature. These graphs clearly show the correlation among qualitative gas composition, temperature, and the maximum value of emissions, thus confirming FT-IR analysis as a powerful key for pyrolysis monitoring. Aldo D'Alessio, Anna Maria Raspolli-Galletti, Domenico Licursi, and Marco Martinelli Copyright © 2013 Aldo D'Alessio et al. All rights reserved. The Principal Aspects of Application of Detonation in Propulsion Systems Thu, 20 Jun 2013 11:07:56 +0000 http://www.hindawi.com/journals/jc/2013/945161/ The basic problems of application of detonation process in propulsion systems with impulse and continuous burning of combustible mixture are discussed. The results on propagation of detonation waves in supersonic flow are analyzed relatively to air-breathing engine. The experimental results are presented showing the basic possibility of creation of an engine with exterior detonation burning. The base results on optimization of initiation in impulse detonation engine are explained at the expense of spatial and temporal redistribution of an energy, entered into a mixture. The method and technique for construction of highly effective accelerators for deflagration to detonation transition are discussed also. A. A. Vasil'ev Copyright © 2013 A. A. Vasil'ev. All rights reserved. Measurements of Gasification Characteristics of Coal and Char in CO2-Rich Gas Flow by TG-DTA Sun, 02 Jun 2013 09:31:53 +0000 http://www.hindawi.com/journals/jc/2013/985687/ Pyrolysis, combustion, and gasification properties of pulverized coal and char in CO2-rich gas flow were investigated by using gravimetric-differential thermal analysis (TG-DTA) with changing O2%, heating temperature gradient, and flow rate of CO2-rich gases provided. Together with TG-DTA, flue gas generated from the heated coal, such as CO, CO2, and hydrocarbons (HCs), was analyzed simultaneously on the heating process. The optimum O2% in CO2-rich gas for combustion and gasification of coal or char was discussed by analyzing flue gas with changing O2 from 0 to 5%. The experimental results indicate that O2% has an especially large effect on carbon oxidation at temperature less than 1100°C, and lower O2 concentration promotes gasification reaction by producing CO gas over 1100°C in temperature. The TG-DTA results with gas analyses have presented basic reference data that show the effects of O2 concentration and heating rate on coal physical and chemical behaviors for the expected technologies on coal gasification in CO2-rich gas and oxygen combustion and underground coal gasification. Zhigang Li, Xiaoming Zhang, Yuichi Sugai, Jiren Wang, and Kyuro Sasaki Copyright © 2013 Zhigang Li et al. All rights reserved. Characteristics of Flameless Combustion in 3D Highly Porous Reactors under Diesel Injection Conditions Thu, 23 May 2013 08:34:52 +0000 http://www.hindawi.com/journals/jc/2013/267631/ The heat release process in a free volume combustion chamber and in porous reactors has been analyzed under Diesel engine-like conditions. The process has been investigated in a wide range of initial pressures and temperatures simulating engine conditions at the moment when fuel injection starts. The resulting pressure history in both porous reactors and in free volumes significantly depends on the initial pressure and temperature. At lower initial temperatures, the process in porous reactors is accelerated. Combustion in a porous reactor is characterized by heat accumulation in the solid phase of the porous structure and results in reduced pressure peaks and lowered combustion temperature. This depends on reactor heat capacity, pore density, specific surface area, pore structure, and heat transport properties. Characteristic modes of a heat release process in a two-dimensional field of initial pressure and temperature have been selected. There are three characteristic regions represented by a single- and multistep oxidation process (with two or three slopes in the reaction curve) and characteristic delay time distribution has been selected in five characteristic ranges. There is a clear qualitative similarity of characteristic modes of the heat release process in a free volume and in porous reactors. A quantitative influence of porous reactor features (heat capacity, pore density, pore structure, specific surface area, and fuel distribution in the reactor volume) has been clearly indicated. M. Weclas and J. Cypris Copyright © 2013 M. Weclas and J. Cypris. All rights reserved. N2O and NO Emissions from CFBC Cofiring Dried Sewage Sludge, Wet Sewage Sludge with Coal and PE Tue, 21 May 2013 10:03:11 +0000 http://www.hindawi.com/journals/jc/2013/749321/ Experiments on cofiring dried sewage sludge, wet sewage sludge with coal and polyethylene (PE) were carried out on a pilot scale 0.15MWt circulating fluidized bed combustion (CFBC) plant, and the influence of furnace temperatures, cofiring rates on N2O and NO emissions was investigated. Temperature is an effective parameter influencing N2O emission, and higher temperature leads to significant N2O reduction and decrease of conversion ratio of fuel-N to N2O. Increasing in cofiring rates leads to higher nitrogen content in the mixed fuel, which could result in higher NO and N2O emissions from combustion. With more sewage sludge addition, higher NO but lower N2O emissions are observed. N2O emission from cofiring wet sewage sludge with coal is higher than that from cofiring dried sewage sludge with coal and PE, and fuel-N conversion ratio to N2O and NO is much higher in cofiring wet sewage sludge with coal than that in cofiring dried sewage sludge with coal and PE. Zhiwei Li and Hongzhou He Copyright © 2013 Zhiwei Li and Hongzhou He. All rights reserved. Combustion Rate of Solid Carbon in the Axisymmetric Stagnation Flowfield Established over a Sphere and/or a Flat Plate Tue, 23 Apr 2013 15:52:08 +0000 http://www.hindawi.com/journals/jc/2013/790672/ Carbon combustion in the forward stagnation flowfield has been examined through experimental comparisons, by conducting aerothermochemical analyses, with the surface C-O2 and C-CO2 reactions and the gas-phase CO-O2 reaction taken into account. By virtue of the generalized species-enthalpy coupling functions, close coupling of those reactions has been elucidated. Explicit combustion-rate expressions by use of the transfer number in terms of the natural logarithmic term, just like that for droplet combustion, have further been obtained for the combustion response in the limiting situations. It has been confirmed that before the establishment of CO flame, the combustion rate can fairly be represented by the expression in the frozen mode, that after its establishment by the expression in the flame-attached or flame-detached modes, and that the critical condition derived by the asymptotics can fairly predict the surface temperature for its establishment. The formulation has further been extended to include the surface C-H2O and gas-phase H2-O2 reactions additionally, so as to evaluate the combustion rate in humid airflow. Since those expressions are explicit and have fair accuracy, they are anticipated to make various contributions not only for qualitative/quantitative studies, but also for various aerospace applications, including propulsion with high-energy-density fuels. Atsushi Makino, Masahiro Hojo, and Masahito Shintomi Copyright © 2013 Atsushi Makino et al. All rights reserved. Combustion of Submillimeter Heptane/Methanol and Heptane/Ethanol Droplets in Reduced Gravity Tue, 12 Feb 2013 11:56:22 +0000 http://www.hindawi.com/journals/jc/2013/154202/ Reduced-gravity experiments were performed on combustion of droplets composed of n-heptane mixed with methanol or ethanol. The initial alcohol mass fraction in a droplet was 0% (pure heptane) or 5%. The experiments were performed at 0.1 MPa and 25°C with air or with ambients of oxygen and helium with oxygen mole fractions of 0.3 or 0.4. Initial droplet diameters were in the range 0.67 mm to 0.92 mm. After considering measurement uncertainties, burning rates decreased appreciably as the initial droplet diameter increased for combustion in air but not for combustion in the oxygen/helium environments. It was also found that addition of either methanol or ethanol did not influence burning rates appreciably and that burning rates were larger for the oxygen/helium environments than for air if initial droplet diameter dependences were accounted for. I. Aharon, V. K. Tam, and B. D. Shaw Copyright © 2013 I. Aharon et al. All rights reserved. Effects of Turbulent Reynolds Number on the Performance of Algebraic Flame Surface Density Models for Large Eddy Simulation in the Thin Reaction Zones Regime: A Direct Numerical Simulation Analysis Thu, 06 Dec 2012 07:51:03 +0000 http://www.hindawi.com/journals/jc/2012/353257/ A direct numerical simulation (DNS) database of freely propagating statistically planar turbulent premixed flames with a range of different turbulent Reynolds numbers has been used to assess the performance of algebraic flame surface density (FSD) models based on a fractal representation of the flame wrinkling factor. The turbulent Reynolds number Ret has been varied by modifying the Karlovitz number Ka and the Damköhler number Da independently of each other in such a way that the flames remain within the thin reaction zones regime. It has been found that the turbulent Reynolds number and the Karlovitz number both have a significant influence on the fractal dimension, which is found to increase with increasing Ret and Ka before reaching an asymptotic value for large values of Ret and Ka. A parameterisation of the fractal dimension is presented in which the effects of the Reynolds and the Karlovitz numbers are explicitly taken into account. By contrast, the inner cut-off scale normalised by the Zel’dovich flame thickness does not exhibit any significant dependence on Ret for the cases considered here. The performance of several algebraic FSD models has been assessed based on various criteria. Most of the algebraic models show a deterioration in performance with increasing the LES filter width. Mohit Katragadda, Nilanjan Chakraborty, and R. S. Cant Copyright © 2012 Mohit Katragadda et al. All rights reserved. Moving Bed Gasification of Low Rank Alaska Coal Mon, 26 Nov 2012 08:43:52 +0000 http://www.hindawi.com/journals/jc/2012/918754/ This paper presents process simulation of moving bed gasifier using low rank, subbituminous Usibelli coal from Alaska. All the processes occurring in a moving bed gasifier, drying, devolatilization, gasification, and combustion, are included in this model. The model, developed in Aspen Plus, is used to predict the effect of various operating parameters including pressure, oxygen to coal, and steam to coal ratio on the product gas composition. The results obtained from the simulation were compared with experimental data in the literature. The predicted composition of the product gas was in general agreement with the established results. Carbon conversion increased with increasing oxygen-coal ratio and decreased with increasing steam-coal ratio. Steam to coal ratio and oxygen to coal ratios impacted produced syngas composition, while pressure did not have a large impact on the product syngas composition. A nonslagging moving bed gasifier would have to be limited to an oxygen-coal ratio of 0.26 to operate below the ash softening temperature. Slagging moving bed gasifiers, not limited by operating temperature, could achieve carbon conversion efficiency of 99.5% at oxygen-coal ratio of 0.33. The model is useful for predicting performance of the Usibelli coal in a moving bed gasifier using different operating parameters. Mandar Kulkarni and Rajive Ganguli Copyright © 2012 Mandar Kulkarni and Rajive Ganguli. All rights reserved. Interactive Combustion in a Linear Array of 2D Laminar Isolated and Triple Burner Jets Mon, 19 Nov 2012 15:33:24 +0000 http://www.hindawi.com/journals/jc/2012/716050/ Many practical combustion systems such as residential gas burners contain dense groupings or clusters of jet flames with sufficiently small spacing between them, which causes flame interaction. The interaction effect, due in part to Oxygen deficiency in the interstitial space between the flames, causes the spreading of flames, which may merge together to form larger group flames. This interactive effect is studied analytically by revisiting the laminar isolated flame theory for 2D jets, for which similarity solutions are readily available in compressible form, and symmetrical interaction zones can be observed. Flame characteristics were studied by obtaining analytical expressions for flame specific parameters such as height and width, lift-off height and blow-off velocity, air entrainment and mixing layer growth. The theory for multiple interacting jets describes an approximate criterion for interburner spacing at which flame interaction and group flame formation are first observed. The analytical framework presented in this paper presented in this paper produced results which were compared with experimental measurements. The experimental apparatus allowed the interburner spacing to be varied from 7.87 mm to 50.8 mm, and measurements of flame height, width, lift-off height and group-flame formation under interactive modes. Images of the evolving flow field were taken and Schlieren images of the multiple 2D jets were also recorded using a digital camera. S. T. Tillman, S. Kuchibhatla, K. Annamalai, J. A. Caton, and D. Ranjan Copyright © 2012 S. T. Tillman et al. All rights reserved. Effect of Gas Phase Heat Sink on Suppression of Opposed Flow Flame Spread over Thin Solid Fuels in Microgravity Environment Wed, 14 Nov 2012 15:48:11 +0000 http://www.hindawi.com/journals/jc/2012/837019/ A two-dimensional numerical model of opposed flow flame spread over thin solid fuel is formulated and modeled to study the effect of gas phase heat sink (a wire mesh placed parallel to the fuel surface) on the flame-spread rate and flame extinction. The work focuses on the performance of the wire mesh in microgravity environment at an oxygen concentration 21%. The simulations were carried out for various mesh parameters (wire diameter, “” and number of wires per unit length, “”) and mesh distance perpendicular to fuel surface “”. Simulations show that wire mesh is effective in reducing flame-spread rate when placed at distance less than flame width (which is about 1 cm). Mesh wire diameter is determined not to have major influence on heat transfer. However, smaller wire diameter is preferred for better aerodynamics and for increasing heat transfer surface area (here prescribed by parameter “”). Flame suppression exhibits stronger dependence on number of wires per unit length; however, it is relatively insensitive to number of wires per unit length beyond certain value (here 20 cm−1). Vinayak Malhotra, Chenthil Kumar, and Amit Kumar Copyright © 2012 Vinayak Malhotra et al. All rights reserved. Modelling of the Curvature Term of the Flame Surface Density Transport Equation for Large Eddy Simulations Wed, 07 Nov 2012 14:15:47 +0000 http://www.hindawi.com/journals/jc/2012/915482/ A simplified chemistry based three-dimensional Direct Numerical Simulation (DNS) database of freely propagating statistically planar turbulent premixed flames with a range of different values of turbulent Reynolds number has been used for the a priori modelling of the curvature term of the generalised Flame Surface Density (FSD) transport equation in the context of Large Eddy Simulation (LES). The curvature term has been split into the contributions arising due to the reaction and normal diffusion components of displacement speed and the term originating from the tangential diffusion component of displacement speed. Subsequently, these contributions of the curvature term have been split into the resolved and subgrid contributions. New models have been proposed for the subgrid curvature terms arising from the combined reaction and normal diffusion components and the tangential diffusion component of displacement speed. The performances of the new model and the existing models for the subgrid curvature term have been compared with the corresponding quantity extracted from the explicitly filtered DNS data. The new model for the subgrid curvature term is shown to perform satisfactorily in all cases considered in the current study, accounting for wide variations in LES filter size. Mohit Katragadda and Nilanjan Chakraborty Copyright © 2012 Mohit Katragadda and Nilanjan Chakraborty. All rights reserved. Effect of Cetane Number on Specific Fuel Consumption and Particulate Matter and Unburned Hydrocarbon Emissions from Diesel Engines Wed, 31 Oct 2012 16:04:25 +0000 http://www.hindawi.com/journals/jc/2012/738940/ This paper discusses the effect of ignition delay time in diesel engines on the formation of particulate matter, using fuel formulations with different sulfur concentrations from various sources. Our findings indicate that the cetane number has a significant influence on particulate matter emissions, especially in engines with mechanical fuel injection. The maximum pressure in the combustion chamber increases as the cetane number increases, favoring the increase in the cracking reactions of high molecular weight fractions remaining in the liquid state and thus increasing the production of particulate matter. In certain conditions, this increase in pressure has a beneficial effect on the thermal efficiency of the cycle. Higher temperatures in the combustion chamber augment the speed of oxidation, reducing unburned hydrocarbon emissions. The ignition delay time of fuel has a strong effect on the formation of particulate matter and on the emission of unburned hydrocarbons. Renato Cataluña and Rosangela da Silva Copyright © 2012 Renato Cataluña and Rosangela da Silva. All rights reserved. A Simulation of the Effects of Varying Repetition Rate and Pulse Width of Nanosecond Discharges on Premixed Lean Methane-Air Combustion Sun, 21 Oct 2012 08:45:09 +0000 http://www.hindawi.com/journals/jc/2012/137653/ Two-dimensional kinetic simulation has been carried out to investigate the effects of repetition rate and pulse width of nanosecond repetitively pulsed discharges on stabilizing premixed lean methane-air combustion. The repetition rate and pulse width are varied from 10 kHz to 50 kHz and from 9 ns to 2 ns while the total power is kept constant. The lower repetition rates provide larger amounts of radicals such as O, H, and OH. However, the effect on stabilization is found to be the same for all of the tested repetition rates. The shorter pulse width is found to favor the production of species in higher electronic states, but the varying effects on stabilization are also found to be small. Our results indicate that the total deposited power is the critical element that determines the extent of stabilization over this range of discharge properties studied. Moon Soo Bak and Mark A. Cappelli Copyright © 2012 Moon Soo Bak and Mark A. Cappelli. All rights reserved.