Research Article
Synthesis and Spectroscopic Studies of Axially Ligated Zn(II)5,10,15,20-meso-tetra(p-chlorophenyl)porphyrin with Oxygen and Nitrogen Donors
Table 5
Elemental analytical data of X-ZnII-t(p-Cl)PP (X = phenolates and pyridinates as axial ligand) along with their calculated values.
| | Compound | Calculated percentage | Found percentage | | C | H | N | C | H | N |
| | phO-Zn-t(p-Cl)PP [(C6H5O)Zn(C44N24N4Cl4)] | 65.90 | 3.18 | 6.14 | 66.76 | 3.24 | 6.23 | | p-NH2phO-Zn-t(p-Cl)PP [(C6H7NO)Zn(C44N24N4Cl4)] | 64.72 | 3.34 | 7.54 | 65.19 | 3.39 | 8.25 | | p-NO2phO-Zn-t(p-Cl)PP [(C6H5NO3)Zn(C44N24N4Cl4)] | 62.80 | 3.03 | 7.32 | 63.40 | 3.09 | 7.39 | | 2,4-Cl2phO-Zn-t(p-Cl)PP [(C6H4Cl2O)Zn(C44N24N4Cl4)] | 61.22 | 2.75 | 5.70 | 61.27 | 2.77 | 5.72 | | p-OCH3phO-Zn-t(p-Cl)PP [(C7H8O2)Zn(C44N24N4Cl4)] | 65.04 | 3.29 | 5.70 | 65.35 | 3.33 | 5.98 | | o-NH2py-Zn-t(p-Cl)PP [(C5H6N2)Zn(C44N24N4Cl4)] | 64.52 | 3.28 | 9.20 | 65.22 | 3.35 | 9.31 | | p-CH3py-Zn-t(p-Cl)PP [(C6H7N)Zn(C44N24N4Cl4)] | 65.90 | 3.40 | 7.68 | 66.05 | 3.43 | 7.70 |
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