Evaluation of Electronic Effects in the Solvolyses of p-Methylphenyl and p-Chlorophenyl Chlorothionoformate Esters

Figure 2

The plot of log (𝑘/𝑘_𝑜) for 4-tolyl chlorothionoformate (6) at 25.0°C against log (𝑘/𝑘_𝑜) for phenyl fluorothionoformate (5) at 10.0°C in the seventeen common pure and binary solvents studied.