Research Article

Evaluation of Electronic Effects in the Solvolyses of p-Methylphenyl and p-Chlorophenyl Chlorothionoformate Esters

Figure 5

The plot of log ( 𝑘 / 𝑘 𝑜 ) for 4-chlorophenyl chlorothionoformate (7) against 1.79 𝑁 𝑇 + 0.45 𝑌 C l in the nineteen pure and binary solvents studied. The points for TFE-H2O and HFIP-H2O are not included in the correlation. They are added to show the extent of their deviation from the correlation.
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