Synthesis, Characterization, and Physicochemical Studies of Mixed Ligand Complexes of Inner Transition Metals with Lansoprazole and Cytosine

<table class="table-group" id="tab3"><tr><td><table class="table"><tr><td class="thead-hr" colspan="5"><hr/></td></tr><tr><td align="left">Serial  no.</td><td align="center">Complex</td><td align="center">Color</td><td align="center">Melting point</td><td align="center">Molar conductance (<svg height="25.875" id="M37" style="vertical-align:-6.19705pt" version="1.1" viewbox="0 0 104.775 25.875" width="104.775" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.012,-0,0,-.012,2.9,6.587)"><path d="M574 0h-62l-217 479h-2l-217 -479h-62l249 548h62z" id="x2227"></path></g>
<g transform="matrix(.017,-0,0,-.017,10.5,18.35)"><path d="M537 944l-411 -1348h-64l411 1348h64z" id="xF6122"></path></g><g transform="matrix(.017,-0,0,-.017,23.513,18.088)"><path d="M409 504l-29 -5q-16 60 -44.5 96t-86.5 36q-54 0 -82.5 -32t-28.5 -77q0 -51 30.5 -82.5t96.5 -65.5l35.5 -18t33 -19.5t33.5 -23.5l27 -25.5t24.5 -32t13.5 -36.5t6 -45q0 -80 -62 -134.5t-160 -54.5q-47 0 -98 15q-22 7 -50 21q-8 23 -27 155l30 7q7 -27 18 -52
t30 -51.5t49 -42.5t67 -16q56 0 88 32.5t32 87.5q0 51 -31.5 82t-98.5 67q-80 44 -110 73q-55 53 -55 124q0 75 56 126.5t150 51.5q53 0 126 -23z" id="x53"></path></g><g transform="matrix(.017,-0,0,-.017,34.409,18.088)"><path d="M390 111l17 -21q-34 -45 -80 -73.5t-89 -28.5q-91 0 -146 62t-55 147q0 118 101 195q74 57 149 57h1q59 0 90 -27q16 -14 16 -30q0 -15 -12 -29t-21 -14q-8 0 -19 11q-44 41 -101 41q-52 0 -87.5 -42.5t-35.5 -117.5q0 -49 15 -87t39 -58t49 -30t48 -10q33 0 60.5 12
t60.5 43z" id="x63"></path></g><g transform="matrix(.017,-0,0,-.017,41.599,18.088)"><path d="M797 0h-214v26q46 5 58 17.5t12 63.5v167q0 116 -88 116q-48 0 -112 -52q3 -18 3 -42v-195q0 -46 11 -58t53 -17v-26h-214v26q48 5 59.5 17t11.5 60v172q0 115 -88 115q-47 0 -109 -52v-235q0 -47 10 -59.5t48 -17.5v-26h-211v26q50 5 62.5 17t12.5 60v207q0 48 -9 59.5
t-52 18.5v23q79 14 139 41v-81q3 2 29 20.5t44 29.5q45 28 81 28t66 -22t46 -61q25 20 83 57q39 26 76 26q59 0 93 -40t34 -113v-193q0 -49 10.5 -60.5t54.5 -16.5v-26z" id="x6D"></path></g>
<g transform="matrix(.012,-0,0,-.012,55.525,9.938)"><path d="M412 140l28 -9q0 -2 -35 -131h-373v23q112 112 161 170q59 70 92 127t33 115q0 63 -31 98t-86 35q-75 0 -137 -93l-22 20l57 81q55 59 135 59q69 0 118.5 -46.5t49.5 -122.5q0 -62 -29.5 -114t-102.5 -130l-141 -149h186q42 0 58.5 10.5t38.5 56.5z" id="x32"></path></g>
<g transform="matrix(.017,-0,0,-.017,64.688,18.087)"><path d="M797 0h-214v26q46 5 58 17.5t12 63.5v167q0 116 -88 116q-48 0 -112 -52q3 -18 3 -42v-195q0 -46 11 -58t53 -17v-26h-214v26q48 5 59.5 17t11.5 60v172q0 115 -88 115q-47 0 -109 -52v-235q0 -47 10 -59.5t48 -17.5v-26h-211v26q50 5 62.5 17t12.5 60v207q0 48 -9 59.5
t-52 18.5v23q79 14 139 41v-81q3 2 29 20.5t44 29.5q45 28 81 28t66 -22t46 -61q25 20 83 57q39 26 76 26q59 0 93 -40t34 -113v-193q0 -49 10.5 -60.5t54.5 -16.5v-26z" id="x6D"></path></g><g transform="matrix(.017,-0,0,-.017,78.558,18.087)"><path d="M257 449q92 0 154 -65t62 -158q0 -112 -67 -175t-150 -63q-98 0 -158.5 66.5t-60.5 154.5q0 59 21 106.5t54.5 75.5t71 43t73.5 15zM244 416q-48 0 -81 -47t-33 -128q0 -96 38 -158t99 -62q51 0 82 43.5t31 139.5q0 91 -36 151.5t-100 60.5z" id="x6F"></path></g><g transform="matrix(.017,-0,0,-.017,87.109,18.087)"><path d="M238 0h-223v26q48 5 60 17t12 61v473q0 50 -10.5 60.5t-58.5 15.5v24q73 8 148 35v-608q0 -49 11.5 -61t60.5 -17v-26z" id="x6C"></path></g>
<g transform="matrix(.012,-0,0,-.012,91.4,9.938)"><path d="M535 230h-483v50h483v-50z" id="x2212"></path></g><g transform="matrix(.012,-0,0,-.012,98.385,9.938)"><path d="M384 0h-275v27q67 5 81.5 18.5t14.5 68.5v385q0 38 -7.5 47.5t-40.5 10.5l-48 2v24q85 15 178 52v-521q0 -55 14.5 -68.5t82.5 -18.5v-27z" id="x31"></path></g>
</svg>)</td></tr><tr><td align="left" colspan="5"><hr/></td></tr><tr><td align="left">1</td><td align="center"><svg height="14.85" id="M38" style="vertical-align:-2.22495pt" version="1.1" viewbox="0 0 5.9875002 14.85" width="5.9875002" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,12.012)"><path d="M290 -163h-170v866h170v-28q-79 -7 -94 -19.5t-15 -72.5v-627q0 -59 14.5 -71.5t94.5 -19.5v-28z" id="x5B"></path></g>
</svg>Th·Lanso·Cyto·4H<sub>2</sub>O]NO<sub>3</sub>·<i>x</i>H<sub>2</sub>O</td><td align="center">Light <br/>brown</td><td align="center">322°C</td><td align="center">96.1</td></tr><tr><td align="left">2</td><td align="center"><svg height="14.85" id="M39" style="vertical-align:-2.22495pt" version="1.1" viewbox="0 0 5.9875002 14.85" width="5.9875002" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,12.012)"><path d="M290 -163h-170v866h170v-28q-79 -7 -94 -19.5t-15 -72.5v-627q0 -59 14.5 -71.5t94.5 -19.5v-28z" id="x5B"></path></g>
</svg>Ce·Lanso·Cyto·4H<sub>2</sub>O]SO<sub>4</sub>·<i>x</i>H<sub>2</sub>O</td><td align="center">Light <br/>brown</td><td align="center">319°C</td><td align="center">89.6</td></tr><tr><td align="left">3</td><td align="center">[Gd·Lanso·Cyto·4H<sub>2</sub>O<svg height="14.85" id="M40" style="vertical-align:-2.22495pt" version="1.1" viewbox="0 0 5.9875002 14.85" width="5.9875002" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,12.012)"><path d="M226 -163h-170v27q79 7 94 20t15 73v627q0 59 -15 72t-94 20v27h170v-866z" id="x5D"></path></g>
</svg>NO<sub>3</sub>·<i>x</i>H<sub>2</sub>O</td><td align="center">Orange</td><td align="center">300°C</td><td align="center">94.2</td></tr><tr><td align="left">4</td><td align="center"><svg height="14.85" id="M41" style="vertical-align:-2.22495pt" version="1.1" viewbox="0 0 5.9875002 14.85" width="5.9875002" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,12.012)"><path d="M290 -163h-170v866h170v-28q-79 -7 -94 -19.5t-15 -72.5v-627q0 -59 14.5 -71.5t94.5 -19.5v-28z" id="x5B"></path></g>
</svg>Nd·Lanso·Cyto·4H<sub>2</sub>O]NO<sub>3</sub>·<i>x</i>H<sub>2</sub>O</td><td align="center">Black</td><td align="center">320°C</td><td align="center">80.2</td></tr><tr><td align="left">5</td><td align="center">[Sm·Lanso·Cyto·4H<sub>2</sub>O<svg height="14.85" id="M42" style="vertical-align:-2.22495pt" version="1.1" viewbox="0 0 5.9875002 14.85" width="5.9875002" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,12.012)"><path d="M226 -163h-170v27q79 7 94 20t15 73v627q0 59 -15 72t-94 20v27h170v-866z" id="x5D"></path></g>
</svg>NO<sub>3</sub>·<i>x</i>H<sub>2</sub>O</td><td align="center">Black</td><td align="center">319°C</td><td align="center">79.2</td></tr><tr><td align="left">6</td><td align="center"><svg height="14.85" id="M43" style="vertical-align:-2.22495pt" version="1.1" viewbox="0 0 5.9875002 14.85" width="5.9875002" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink">
<g transform="matrix(.017,-0,0,-.017,.062,12.012)"><path d="M290 -163h-170v866h170v-28q-79 -7 -94 -19.5t-15 -72.5v-627q0 -59 14.5 -71.5t94.5 -19.5v-28z" id="x5B"></path></g>
</svg>Ytt·Lanso·Cyto·4H<sub>2</sub>O]NO<sub>3</sub>·<i>x</i>H<sub>2</sub>O</td><td align="center">Black</td><td align="center">315°C</td><td align="center">83.2</td></tr><tr class="table-tr"><td colspan="5"><hr class="tbody-hr"/></td></tr></table></td></tr></table>

Analytical data of synthesized mixed ligand complexes of M-Lanso-Cyto.

Journal of Chemistry

tab3

Table 3

Table 3: Synthesis, Characterization, and Physicochemical Studies of Mixed Ligand Complexes of Inner Transition Metals with Lansoprazole and Cytosine 

Table 3 | Synthesis, Characterization, and Physicochemical Studies of Mixed Ligand Complexes of Inner Transition Metals with Lansoprazole and Cytosine 