Research Article
Synthesis and Characterization of Novel Thiourea Derivatives and Their Nickel and Copper Complexes
Table 1
Crystal data and the structure refinement details for HL1, HL2, HL4, and Ni(L3)2.
| | Parameters | HL1 | HL2 | HL4 | Ni(L3)2 |
| | Crystal formula | C10H11FN2OS | C12H15N2SOF | C16H23N2SOF | C28H36F2N4NiO2S2 | | Formula weight (g/mol) | 226.28 | 254.32 | 310.42 | 621.44 | | Crystal dimensions, (mm) | 0.33 0.42 0.54 | 0.24 0.30 0.60 | 0.30 0.48 0.60 | 0.39 0.27 0.18 | | Temp, (K) | 293(2) | 293(2) | 293(2) | 120(2) K | | Crystal system | Monoclinic | Monoclinic | Monoclinic | Triclinic | | Space group | P 21/c | P 21/c | P 21/c | P-1 | | , (Å) | 10.917(3) | 6.879(2) | 10.4719(11) | 10.272(3) | | , (Å) | 5.572(5) | 18.8034(19) | 15.714(2) | 12.377(3) | | , (Å) | 18.073(5) | 10.0498(12) | 10.5497(11) | 12.604(3) | | , (°) | 90.00 | 90.00 | 90.00 | 68.014(5) | | , (°) | 92.82(2) | 93.161(17) | 102.093(9) | 87.123(6) | | , (°) | 90.00 | 90.00 | 90.00 | 83.438(6) | | ; , (g/cm−3) | 4; 1.37 | 4; 1.30 | 4; 1.21 | 2; 1.398 | | Range of (°) | 2.9/26.3 | 2.3/26.3 | 2.4/26.3 | 1.74/27.88 | | (MoKα) (mm−1) | 0.283 | 0.247 | 0.201 | 0.843 | | Reflections collected | 2338 | 2856 | 3637 | 13065 | | Reflections used in refinement | 2221 | 2636 | 3448 | 6946 | | Number of refined parameters | 143 | 158 | 205 | 353 | | / values | 0.0380/0.1201 | 0.0410/0.1168 | 0.050/0.1538 | 0.0944/0.2878 | | GOF | 1.0730 | 1.022 | 1.032 | 1.088 | | ()min, ()max (e Å−3) | −0.183, 0.195 | −0.246, 0.181 | −0.262, 0.328 | −0.725, 2.197 |
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