Research Article

Separation/Preconcentration and Speciation Analysis of Trace Amounts of Arsenate and Arsenite in Water Samples Using Modified Magnetite Nanoparticles and Molybdenum Blue Method

Table 2

Comparison of the characteristic data between typical published methods and the proposed method in this work.

SorbentSpeciesEnrichment factorSorbent capacity (mg g−1)RSD (%)Detection limit ( g mL−1)Detection method Reference

APDCa/C-18As(III), As(V)50NRbNRb0.0012c, 0.09cICP-MSd[15]
TiO2As(III)20NR2.40.1cGFAAS[36]
APDC/CNTseAs(III), As(V)2509.13.50.02cGFAAS[37]
PVPf-impregnated SPE membrane disk As(III)NRNRNR0.01Colorimetry[38]
CTACg/CNTsAs(V)NRNR5.32.0AFh[39]
Hybrid nano ZrO2/B2O3As(III), As(V)2098.045.09.25HGAASj[40]
CTAB@ACMNPsAs(V), As(III)
converted to As(V)
1759.42.80.028Molybdenum blueThis work

Ammonium pyrrolidine dithiocarbamate, bnot reported, cis in g L−1.
dIductively coupled plasma-mass spectrometry, ecarbon nanotubes, fpoly(vinyl-pyrrolidone), gcetyltrimethylammonium chloride, hatomic fluorescence spectrophotometry, jhydride generation atomic absorption spectrometry.