Research Article

Effect of Magnesium Borates on the Fire-Retarding Properties of Zinc Borates

Table 4

Crystallographic data of the synthesised magnesium and zinc borates.

Mineral nameAdmontiteMcallisteriteZinc oxide borate hydrate

Pdf number01-076-054001-070-190200-035-0433
Chemical formulaMgO(B2O3)3·7(H2O)Mg2(B6O7(OH)6)2·9(H2O)Zn3B6O12·3.5(H2O)
Molecular weight (g/mole)375.27768.56596.04
Crystal systemMonoclinic RhombohedralMonoclinic
Space groupP21/c (No. 14)Pr3c (No. 167)P21/n (No. 14)
a (Å)12.661011.54907.6950
b (Å)10.091011.54909.8028
c (Å)11.322035.56706.8378
α (°)90.0090.0090.00
β (°)109.6090.00107.03
γ (°)90.00120.0090.00
z 4.006.002.00
Density (calculated) (g·cm−3)1.831.862.93
Characteristic peaks I (%)/2θ (°)100.0/7.404
56.9/16.848
38.6/12.064
100.0/10.139
35.7/15.332
32.9/31.875
100.0/23.743
96.0/21.770
96.0/25.847