Assignment of O–O and Mo=O Stretching Frequencies of Molybdenum/Tungsten Complexes Revisited

Table 6

Mo=O and O–O stretching, and Cp’s C–H OOP bending frequencies for 1-Cl.

	/cm^−1	/cm^−1	/cm^−1	Mo=O/Å	O–O/Å
M06L	981.10	963.24	17.86	1.678	1.430
M06	1032.38	1040.76	−8.38	1.662	1.406
M06-2X	1085.37	1066.20	19.17	1.649	1.410
Expt.	881	842	39	1.771	1.352

Bond lengths and IR frequencies are taken from the work of Galakhov et al. [40].