Equilibrium and Thermodynamic Studies on the Biosorption of Lead (II) by Living and Nonliving Biomass of <i>Penicillium notatum</i>

<table class="table-group" id="tab2"><tr><td><table class="table"><tr><td class="thead-hr" colspan="7"><hr/></td></tr><tr class="thead"><td class="align_left" rowspan="2"><i>T</i>(<sup>˚</sup><i>K</i>)</td><td class="align_center" colspan="2"><span style="width: 62.1042ptpx;"><svg height="14.9752pt" id="M26" style="vertical-align:-3.3838pt" version="1.1" viewbox="-0.0498162 -11.5914 62.1042 14.9752" width="62.1042pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M600 0V24L339 665L311 657L43 24V0H600ZM497 50H107L303 539L497 50Z"></path></g><g transform="matrix(.013,0,0,-0.013,8.327,0)"><path d="M673 297H417L411 270C517 261 522 258 506 183L487 92C476 38 428 19 360 19C207 19 123 132 123 287C123 472 243 631 441 631C557 631 617 583 617 469L647 472C650 545 655 604 658 632C625 643 554 666 467 666C201 666 23 502 23 278C23 90 156 -16 339 -16C410 -16 501 6 569 24C566 43 567 70 573 101L589 183C604 259 607 262 667 271L673 297Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,17.219,-5.741)"><path d="M245 635C92 635 37 457 37 312C37 149 91 -12 244 -12C395 -12 449 166 449 312C449 469 395 635 245 635ZM243 598C332 598 358 454 358 312C358 173 334 26 245 26C158 26 128 174 128 313S152 598 243 598Z"></path></g><g transform="matrix(.013,0,0,-0.013,23.688,0)"><path d="M300 -147C201 -63 143 98 143 270S200 602 300 686L282 710C136 610 70 450 70 271V270C70 89 136 -72 282 -170L300 -147Z"></path></g><g transform="matrix(.013,0,0,-0.013,28.186,0)"><path d="M135 536C163 536 185 560 185 587C185 617 163 639 136 639C108 639 85 617 85 587C85 560 108 536 135 536ZM34 389C96 380 101 376 101 308V113C101 22 99 -37 93 -80C87 -114 80 -137 68 -152C54 -170 28 -182 -5 -190C-19 -193 -26 -200 -26 -213C-26 -237 -3 -257 10 -257C18 -257 26 -253 36 -246C59 -226 122 -150 157 -50C176 3 180 46 180 111V451C137 433 86 420 34 412V389Z"></path></g><g transform="matrix(.013,0,0,-0.013,31.514,0)"><path d="M368 703H309L44 -163H104L368 703Z"></path></g><g transform="matrix(.013,0,0,-0.013,36.875,0)"><path d="M797 0V26C739 32 732 36 732 103V296C732 394 682 449 605 449C576 449 550 437 529 423C504 407 475 389 446 366C425 418 382 449 334 449C303 449 279 437 253 421C222 403 201 385 180 371V452C135 432 85 419 41 411V388C99 379 102 374 102 310V103C102 38 93 32 27 26V0H238V26C189 32 180 38 180 103V338C210 363 250 390 289 390C351 390 377 348 377 275V103C377 37 368 32 306 26V0H520V26C465 32 456 38 456 101V296C456 314 455 326 453 338C491 369 529 390 565 390C628 390 653 345 653 274V107C653 36 642 32 583 26V0H797Z"></path></g><g transform="matrix(.013,0,0,-0.013,47.47,0)"><path d="M257 449C165 449 37 374 37 209C37 98 119 -12 256 -12C355 -12 473 65 473 226C473 349 381 449 257 449ZM244 416C333 416 380 320 380 204C380 67 329 21 267 21C184 21 130 115 130 241C130 354 184 416 244 416Z"></path></g><g transform="matrix(.013,0,0,-0.013,54.009,0)"><path d="M238 0V26C174 32 166 38 166 104V712C132 700 70 683 18 677V653C81 647 87 645 87 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122L719 524C735 610 741 615 822 622L828 650Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,19.25,-5.741)"><path d="M245 635C92 635 37 457 37 312C37 149 91 -12 244 -12C395 -12 449 166 449 312C449 469 395 635 245 635ZM243 598C332 598 358 454 358 312C358 173 334 26 245 26C158 26 128 174 128 313S152 598 243 598Z"></path></g><g transform="matrix(.013,0,0,-0.013,24.196,0)"><path d="M300 -147C201 -63 143 98 143 270S200 602 300 686L282 710C136 610 70 450 70 271V270C70 89 136 -72 282 -170L300 -147Z"></path></g><g transform="matrix(.013,0,0,-0.013,28.694,0)"><path d="M135 536C163 536 185 560 185 587C185 617 163 639 136 639C108 639 85 617 85 587C85 560 108 536 135 536ZM34 389C96 380 101 376 101 308V113C101 22 99 -37 93 -80C87 -114 80 -137 68 -152C54 -170 28 -182 -5 -190C-19 -193 -26 -200 -26 -213C-26 -237 -3 -257 10 -257C18 -257 26 -253 36 -246C59 -226 122 -150 157 -50C176 3 180 46 180 111V451C137 433 86 420 34 412V389Z"></path></g><g transform="matrix(.013,0,0,-0.013,32.022,0)"><path d="M368 703H309L44 -163H104L368 703Z"></path></g><g transform="matrix(.013,0,0,-0.013,37.384,0)"><path d="M797 0V26C739 32 732 36 732 103V296C732 394 682 449 605 449C576 449 550 437 529 423C504 407 475 389 446 366C425 418 382 449 334 449C303 449 279 437 253 421C222 403 201 385 180 371V452C135 432 85 419 41 411V388C99 379 102 374 102 310V103C102 38 93 32 27 26V0H238V26C189 32 180 38 180 103V338C210 363 250 390 289 390C351 390 377 348 377 275V103C377 37 368 32 306 26V0H520V26C465 32 456 38 456 101V296C456 314 455 326 453 338C491 369 529 390 565 390C628 390 653 345 653 274V107C653 36 642 32 583 26V0H797Z"></path></g><g transform="matrix(.013,0,0,-0.013,47.978,0)"><path d="M257 449C165 449 37 374 37 209C37 98 119 -12 256 -12C355 -12 473 65 473 226C473 349 381 449 257 449ZM244 416C333 416 380 320 380 204C380 67 329 21 267 21C184 21 130 115 130 241C130 354 184 416 244 416Z"></path></g><g transform="matrix(.013,0,0,-0.013,54.517,0)"><path d="M238 0V26C174 32 166 38 166 104V712C132 700 70 683 18 677V653C81 647 87 645 87 577V104C87 38 78 32 15 26V0H238Z"></path></g><g transform="matrix(.013,0,0,-0.013,57.806,0)"><path d="M275 270C275 450 212 609 64 710L45 686C145 604 203 442 203 270S147 -63 45 -147L64 -170C213 -68 275 89 275 270Z"></path></g></svg></span></td><td class="align_center" colspan="2"><span style="width: 57.8152ptpx;"><svg height="14.9752pt" id="M28" style="vertical-align:-3.3838pt" version="1.1" viewbox="-0.0498162 -11.5914 57.8152 14.9752" width="57.8152pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M600 0V24L339 665L311 657L43 24V0H600ZM497 50H107L303 539L497 50Z"></path></g><g transform="matrix(.013,0,0,-0.013,8.327,0)"><path d="M449 634C442 637 425 643 405 650C376 660 341 666 307 666C181 666 98 590 98 485C98 400 170 343 215 310L246 288C307 243 343 204 343 147C343 67 291 18 219 18C104 18 61 124 51 202L23 199C28 124 27 71 27 47C47 22 122 -16 204 -16C324 -16 428 60 428 174C428 256 379 309 307 360L276 382C223 419 179 455 179 516C179 576 221 632 293 632C379 632 410 564 418 487L448 490C446 536 446 592 449 634Z"></path></g><g transform="matrix(.0091,0,0,-0.0091,14.463,-5.741)"><path d="M245 635C92 635 37 457 37 312C37 149 91 -12 244 -12C395 -12 449 166 449 312C449 469 395 635 245 635ZM243 598C332 598 358 454 358 312C358 173 334 26 245 26C158 26 128 174 128 313S152 598 243 598Z"></path></g><g transform="matrix(.013,0,0,-0.013,19.41,0)"><path d="M300 -147C201 -63 143 98 143 270S200 602 300 686L282 710C136 610 70 450 70 271V270C70 89 136 -72 282 -170L300 -147Z"></path></g><g transform="matrix(.013,0,0,-0.013,23.908,0)"><path d="M135 536C163 536 185 560 185 587C185 617 163 639 136 639C108 639 85 617 85 587C85 560 108 536 135 536ZM34 389C96 380 101 376 101 308V113C101 22 99 -37 93 -80C87 -114 80 -137 68 -152C54 -170 28 -182 -5 -190C-19 -193 -26 -200 -26 -213C-26 -237 -3 -257 10 -257C18 -257 26 -253 36 -246C59 -226 122 -150 157 -50C176 3 180 46 180 111V451C137 433 86 420 34 412V389Z"></path></g><g transform="matrix(.013,0,0,-0.013,27.236,0)"><path d="M368 703H309L44 -163H104L368 703Z"></path></g><g transform="matrix(.013,0,0,-0.013,32.597,0)"><path d="M797 0V26C739 32 732 36 732 103V296C732 394 682 449 605 449C576 449 550 437 529 423C504 407 475 389 446 366C425 418 382 449 334 449C303 449 279 437 253 421C222 403 201 385 180 371V452C135 432 85 419 41 411V388C99 379 102 374 102 310V103C102 38 93 32 27 26V0H238V26C189 32 180 38 180 103V338C210 363 250 390 289 390C351 390 377 348 377 275V103C377 37 368 32 306 26V0H520V26C465 32 456 38 456 101V296C456 314 455 326 453 338C491 369 529 390 565 390C628 390 653 345 653 274V107C653 36 642 32 583 26V0H797Z"></path></g><g transform="matrix(.013,0,0,-0.013,43.192,0)"><path d="M257 449C165 449 37 374 37 209C37 98 119 -12 256 -12C355 -12 473 65 473 226C473 349 381 449 257 449ZM244 416C333 416 380 320 380 204C380 67 329 21 267 21C184 21 130 115 130 241C130 354 184 416 244 416Z"></path></g><g transform="matrix(.013,0,0,-0.013,49.73,0)"><path d="M238 0V26C174 32 166 38 166 104V712C132 700 70 683 18 677V653C81 647 87 645 87 577V104C87 38 78 32 15 26V0H238Z"></path></g><g transform="matrix(.013,0,0,-0.013,53.019,0)"><path d="M275 270C275 450 212 609 64 710L45 686C145 604 203 442 203 270S147 -63 45 -147L64 -170C213 -68 275 89 275 270Z"></path></g></svg></span></td></tr><tr class="thead"><td class="align_center">Nonliving</td><td class="align_center">Live</td><td class="align_center">Nonliving</td><td class="align_center">Live</td><td class="align_center">Nonliving</td><td class="align_center">Live</td></tr><tr><td class="thead-hr" colspan="7"><hr/></td></tr><tr><td class="align_left">283</td><td class="align_center">−1019.74</td><td class="align_center">−470.6</td><td class="align_center" rowspan="5">−8064</td><td class="align_center" rowspan="5">1511</td><td class="align_center" rowspan="5">−24.2</td><td class="align_center" rowspan="5">6.87</td></tr><tr><td class="align_left">296</td><td class="align_center">−1156.6</td><td class="align_center">−487.3</td></tr><tr><td class="align_left">306</td><td class="align_center">−636.1</td><td class="align_center">−585.14</td></tr><tr><td class="align_left">315</td><td class="align_center">−366.7</td><td class="align_center">−654.7</td></tr><tr><td class="align_left">323</td><td class="align_center">−241.7</td><td class="align_center">−725.06</td></tr><tr class="table-tr"><td colspan="7"><hr class="tbody-hr"/></td></tr></table></td></tr></table>

<div>Thermodynamic parameters of Pb (II) uptake by <i>Penicillium notatum</i> in the nonliving state.</div>

Journal of Chemistry

tab2

Table 2

Table 2: Equilibrium and Thermodynamic Studies on the Biosorption of Lead (II) by Living and Nonliving Biomass of <i>Penicillium notatum</i> 

Journal of Chemistry

Equilibrium and Thermodynamic Studies on the Biosorption of Lead (II) by Living and Nonliving Biomass of Penicillium notatum

Table 2