Research Article

Computational, Kinetics, and Corrosion Protection Aspects of Electrodeposited Poly(Salicylic Acid) Coatings as a Corrosion Inhibitor for Mild Steel

Table 4

Infrared absorption bands of SA and PSA.

AssignmentsWavenumber (cm −1)
SAPSA

CH out-of-plane bending for 1, 2 di-substituted benzene ring.580s680s
768w763m

CH out-of-plane bending for 1, 2, and 4 tri-substituted benzene ring.869m886s
Stretching vibration for C-O group.1024w
Stretching for incorporation in the polymer sulfate group.1218b1193b

Stretching vibration of C=C in benzene ring1456s1454m
1656b1660s
2600w2597b
2876w2856s

Stretching vibration for CH aromatic2999w
3233b

Stretching vibration intermolecular hydrogen of solvated OH group or end group OH of polymeric chain.3496b3437w

(where s: strong, w: weak, b: broad, and m: medium).