Synthesis, Crystal Structure and Electrical Properties of the Molybdenum Oxide Na_{𝟏.𝟗𝟐}Mg_{𝟐.𝟎𝟒}Mo_𝟑O_𝟏𝟐

Table 3

Main interatomic distances (Å) in Na_1.92Mg_2.04Mo₃O₁₂ compound.

Bond distances (Å)
Mo1–O3	1.718(3)
Mo1–O12^i	1.762(3)
Mo1–O5	1.780(3)
Mo1–O11	1.800(3)
Mo2–O7	1.732(3)
Mo2–O6	1.765(3)
Mo2–O8	1.766(3)
Mo2–O9	1.785(3)
Mo3–O4	1.736(3)
Mo3–O1	1.740(4)
Mo3–O10	1.758(3)
Mo3–O2	1.780(3)
Mg1–O4^vii	2.056(3)
Mg1–O9^viii	2.067(3)
Mg1–O5	2.076(3)
Mg1–O7^ii	2.080(3)
Mg1–O2	2.109(3)
Mg1–O5^iii	2.167(3)
Mg2–O10	1.989(4)
Mg2–O12^ix	2.070(3)
Mg2–O11	2.119(3)
Mg2–O11^iv	2.132(3)
Mg2–O6	2.148(3)
Mg2–O8^iv	2.149(3)
Na1–O8^ii	2.158(3)
Na1–O1	2.211(6)
Na1–O9^v	2.232(3)
Na1–O2^vi	2.250(3)
Na1–O12	2.298(4)
Na2–O3	2.279(8)
Na2–O3^ii	2.411(9)
Na2–O6^ii	2.780(3)
Na2–O1^ii	2.859(9)
Na3–O3	2.272(18)
Na3–O6^ii	2.371(19)
Na3–O3^x	2.437(17)
Na3–O6^vii	2.440(19)
Na3–O1^ii	2.518(11)
Na3–O1^vii	2.989(10)

Symmetry codes: ⁱ𝑥−1, 𝑦−1, 𝑧; ⁱⁱ−𝑥+1, −𝑦+1, −𝑧+1; ⁱⁱⁱ−𝑥, −𝑦, −𝑧; ^iv−𝑥+1, −𝑦, −𝑧+1; ^v−𝑥+1, −𝑦+1, −𝑧+1; ^vi−𝑥+1, −𝑦+1, −𝑧; ^vii𝑥−1, 𝑦, 𝑧; ^viii𝑥−1, 𝑦, 𝑧−1; ^ix𝑥, 𝑦−1, 𝑧; ^x−𝑥, −𝑦+1, −𝑧+1.