Synthesis, Crystal Structure, and Characterization of a New Organic-Inorganic Hybrid Material: (H₃AEP)₂⋅(BiCl₆)⋅3Cl⋅2H₂O

Table 1

Crystal data and structure refinement details for (H₃AEP)₂·(BiCl₆)·3Cl·2H₂O.

Empirical formula	(H3AEP)2·(BiCl6)·3Cl·2H2O
Formula weight (g/mol)	828.53
Crystal system, space group	Orthorhombic, Pbca
𝑎 (Å)	12.108 (4)
𝑏 (Å)	19.403 (3)
𝑐 (Å)	24.933 (6)
𝑉 (Å^3)	5858 (3)
𝑍	8
µ (mm^−1)	6.86
𝐷𝑥 (Mg m^−3)	1.88
𝐹(000)	3248
Crystal size (mm)	0.38 × 0.42 × 0.49
Crystal habit	Orange prism
𝑇min/𝑇max	0.7564/0.9992
Measured reflections	5418
Independent reflections	4863
Observed reflection with 𝐼>2𝜎(𝐼)	3105
𝑅int	0.029
Data/restraints/parameters	4863/3/280
𝑅[𝐹^2>2𝜎(𝐹^2)]	0.039
𝑤𝑅(𝐹^2)	0.095
Goo𝐹 = 𝑆	1.02
Δ𝜌max/Δ𝜌min (e·Å^−3)	0.96/−0.67