Synthesis and Structural Study of Tris(𝝁-pyrazolyl)hexakis(pyrazole)dicobalt(III) Nitrate

Table 2

Selected bond lengths and angles (°) for [(Hpyz)₃Co(-pyz)₃Co(Hpyz)₃](NO₃)₃.

Co–N1	1.973(2)	N1–N2	1.345(3)
Co–N3	1.966(2)	N3–N4	1.353(3)
Co–N5	1.960(2)	N5–N6	1.339(3)
Co–N7	1.913(2)	N7–N7′	1.372(4)
Co–N9	1.919(2)	N8–N8′	1.369(4)
Co–N11	1.921(2)	N9–N9′	1.366(4)
N10–O1	1.259(5)	N10–O2	1.232(3)
N11–O3	1.278(5)	N11–O4	1.234(3)
N12–O5	1.268(5)	N12–O6	1.225(3)
Bond angles
N1–Co–N3	90.18(9)	Co–N1–N2	122.4(2)
N1–Co–N5	89.59(9)	Co–N3–N4	122.9(2)
N1–Co–N7	92.44(9)	Co–N5–N6	122.7(2)
N1–Co–N8	87.45(9)	Co–N1–C1	132.1(2)
N1–Co–N9	175.99(9)	Co–N3–C4	131.1(2)
N3–Co–N5	89.79(9)	Co–N5–C7	130.8(2)
N3–Co–N7	87.26(9)	O1–N10–O2	118.8(2)
N3–Co–N8	176.70(9)	O2–N10–O2′	122.4(4)
N3–Co–N9	92.51(9)	O3–N11–O4	119.2(2)
N5–Co–N7	176.42(9)	O4–N11–O4′	121.6(4)
N5–Co–N8	92.49(9)	O5–N12–O6	118.3(2)
N5–Co–N9	87.44(9)	O6–N12–O6′	123.4(5)
N7–Co–N8	90.54(9)	N8–Co–N9	89.98(9)
N7–Co–N9	90.66(9)