Synthesis, Crystal Structure, and Electrical Properties of a New Molybdylarsenate LiNa₅K₃Mo₁₁As₃O₄₅

Table 5

Bond valence sums.

Polyhedra	BVS
As(1)–O4	4.904
As(2)–O4	4.924
As(3)–O4	4.859
Mo(1)–O5	5.963
Mo(2)–O6	6.101
Mo(3)–O6	6.042
Mo(4)–O6	6.087
Mo(5)–O6	6.117
Mo(6)–O6	6.117
Mo(7)–O6	6.083
Mo(8)–O6	5.991
Mo(9)–O6	6.142
Mo(10)–O6	6.007
Mo(11)–O5	5.988
K(1)–O8	0.927
K(2)–O8	0.966
K(3)–O6	0.976
Na(1)-O8	1.001
Na(2)–O8	0.905
Na(3)–O7	0.715
Na(4)–O7	1.052
Na(5)–O6	0.915
Li-O4	0.727