Synthesis, Characterization, and Crystal Structure of [Co₄(CH₃CO₂)₂L₄]₂[BPh₄]₄0.5H₂O, Where HL = 4-(Salicylaldiminato)antipyrine

Table 2

Selected bond lengths (Å) and angles (°) of the title compound.

Bond lengths
Co1–O17	2.045(5)	Co1–O2	2.107(4)	Co1–O1	2.107(4)
Co1–N1	2.109(6)	Co1–O8	2.154(4)	Co1–O4	2.157(4)
Co2–O18	2.030(5)	Co2–O4	2.087(4)	Co2–N4	2.091(6)
Co2–O3	2.110(4)	Co2–O6	2.150(5)	Co2–O2	2.201(4)
Co3–O19	2.014(5)	Co3–N7	2.083(5)	Co3–O6	2.108(4)
Co3–O2	2.145(4)	Co3–O5	2.152(5)	Co3–O8	2.152(4)
Co4–O20	2.015(5)	Co4–O8	2.084(4)	Co4–N10	2.098(6)
Co4–O7	2.122(5)	Co4–O6	2.154(4)	Co4–O4	2.208(5)
Co5–O21	2.005(5)	Co5–N13	2.099(6)	Co5–O10	2.113(4)
Co5–O14	2.136(5)	Co5–O9	2.146(5)	Co5–O12	2.176(4)
Co5–Co6	2.9972(13)	Co6–O22	2.029(5)	Co6–O12	2.091(5)
Co6–N16	2.094(6)	Co6–O11	2.126(5)	Co6–O10	2.144(5)
Co6–O16	2.231(5)	Co7–O23	2.041(6)	Co7–O13	2.098(5)
Co7–O14	2.098(4)	Co7–N19	2.110(6)	Co7–O12	2.155(5)
Co7–O16	2.159(5)	Co7–Co8	2.977(14)	Co8–O24	2.035(6)
Co8–O16	2.067(5)	Co8–O15	2.074(5)	Co8–N22	2.100(6)
Co8–O14	2.176(5)	Co8–O10	2.181(5)
Bond angles
Co1–O2–Co3	101.32(17)	C98–O2–Co2	122.8(4)	Co1–O2–Co2	89.06(15)
Co3–O2–Co2	96.65(17)	Co2–O4–Co1	90.78(16)	Co2–O4–Co4	99.85(17)
Co1–O4–Co4	97.17(16)	Co3–O6–Co2	99.34(19)	Co3–O6–Co4	89.33(16)
Co2–O6–Co4	99.59(17)	Co4–O8–Co3	90.03(16)	Co4–O8–Co1	101.14(17)
Co3–O8–Co1	99.57(16)	Co5–O10–Co6	89.51(17)	Co5–O10–Co8	97.97(19)
Co6–O10–Co8	100.00(18)	Co6–O12–Co7	102.1(2)	Co6–O12–Co5	89.23(17)
Co7–O12–Co5	98.95(18)	Co7–O14–Co5	102.1(2)	Co7–O14–Co8	88.28(17)
Co5–O14–Co8	97.4(2)	Co8–O16–Co7	89.53(19)	Co8–O16–Co6	100.78(19)
Co7–O16–Co6	97.59(19)