Synthesis and Molecular Structure of cis-Tetracarbonyl[N-(diphenylphosphino-kP)-naphthalen-1-yl-P,P-diphenylphosphinous amide-kP]chromium(0)

Table 2

Selected bond lengths (Å) and bond angles (deg.) for 1.

Cr1−C11	1.883(2)	C14−Cr1−C11	175.52(8)
Cr1−C12	1.859(2)	P1−Cr1−C12	100.26(7)
Cr1−C13	1.865(2)	P1−Cr1−C13	166.57(7)
Cr1−C14	1.881(2)	P1−Cr1−C14	88.05(6)
Cr1−P1	2.347(1)	P2−Cr1−C11	93.51(6)
Cr1−P2	2.347(1)	P2−Cr1−C12	168.99(6)
P1−N1	1.719(1)	P2−Cr1−C13	97.99(7)
P2−N1	1.722(1)	P2−Cr1−C14	90.89(6)
P1−C15	1.829(2)	P1−N1−P2	100.70(7)
P1−C21	1.818(2)	P1−Cr1−P2	68.74(3)
P2−C27	1.819(2)	P1−Cr1−C11	92.79(6)
P2−C33	1.830(2)	N1−P1−Cr1	94.26(5)
N1−C1	1.443(2)	N1−P2−Cr1	94.19(5)
C11−O1	1.136(2)	N1−P1−C15	105.49(7)
C12−O2	1.147(2)	N1−P1−C21	109.46(8)
C13−O3	1.140(2)	N1−P2−C27	106.55(8)
C14−O4	1.146(2)	N1−P2−C33	109.00(7)
C12−Cr1−C11	86.43(9)	C15−P1−C21	100.97(8)
C12−Cr1−C13	93.02(9)	C27−P2−C33	101.42(8)
C12−Cr1−C14	89.09(8)	∑ angles at N1	359.91(9)
C13−Cr1−C11	90.05(9)	P2−Cr1−P1−N1	−9.66(5)
C13−Cr1−C14	90.15(9)	C3−C2−C1−N1	−177.61(2)