New Quasi-One-Dimensional Organic-Inorganic Hybrid Material: 1,3-Bis(4-piperidinium)propane Pentachlorobismuthate(III) Synthesis, Crystal Structure, and Spectroscopic Studies

Table 2

Selected bond distances (Å) and angles (°) for (H₂TMDP)BiCl₅.

Bond distances (Å)
Bi–Cl1^i	2.6936(14)	C1–C2	1.498(8)
Bi–Cl1	2.6936(14)	C2–C3	1.522(7)
Bi–Cl2	2.533(3)	C3–C4	1.533(9)
Bi–Cl3	2.665(3)	C4–C5	1.520(8)
Bi–Cl4	2.769(3)	C3–C6	1.519(9)
Bi–Cl4^ii	3.046(2)	C6–C7	1.580(14)
N–C1	1.497(7)	C3–C4	1.533(9)
N–C5	1.498(7)
Angles (°)
Cl2–Bi–Cl3	95.49(10)	C6–C3–C2	110.7(7)
Cl2–Bi–Cl1	84.77(5)	C6–C3–C4	113.6(8)
Cl3–Bi–Cl1	90.13(7)	C2–C3–C4	109.1(6)
Cl1^i–Bi–Cl1	169.52(10)	C5–C4–C3	113.4(6)
Cl2–Bi–Cl4	90.81(9)	N–C5–C4	109.3(6)
Cl3–Bi–Cl4	173.70(7)	N–C1–C2	109.4(5)
Cl1–Bi–Cl4	90.45(6)	C1–C2–C3	113.1(6)
Cl2–Bi–Cl4^ii	172.17(8)	C3–C6–C7	111.4(9)
Cl3–Bi–Cl4^ii	92.34(8)	C6^i–C7–C6	105.8(13)
Cl1–Bi–Cl4^ii	95.23(5)
Cl4–Bi–Cl4^ii	81.36(3)
Bi–Cl4–Bi^iii	165.87(10)
C1–N–C5	112.8(5)

Symmetry codes: ⁱ−𝑥, 𝑦, 𝑧; ⁱⁱ−𝑥, −𝑦, 𝑧−1/2; ⁱⁱⁱ−𝑥, −𝑦, 𝑧+1/2.