Journal of Nanomaterials
Volume 2009 (2009), Article ID 613813, 14 pages
doi:10.1155/2009/613813
Research Article

Reversible and Irreversible Binding of Nanoparticles to Polymeric Surfaces

Wolfgang H. Binder,1 Marina Lomoschitz,2 Robert Sachsenhofer,1 and Gernot Friedbacher3

1Institute of Macromoleculare Chemistry, Martin-Luther-Universität Halle-Wittenberg, Heinrich-Damerowstrasse 4/TGZ III, 06120 Halle, Germany
2Institut für Materialchemie 165, Technische Universität Wien, Getreidemarkt 9/165, 1080 Wien, Austria
3Institut für Chemische Technologien und Analytik 164, Technische Universität Wien, Getreidemarkt 9/164, 1080 Wien, Austria

Received 15 October 2008; Accepted 24 March 2009

Academic Editor: Michael Wong

Copyright © 2009 Wolfgang H. Binder et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. A. Burns, H. Ow, and U. Wiesner, “Fluorescent core-shell silica nanoparticles: towards “Lab on a Particle” architectures for nanobiotechnology,” Chemical Society Reviews, vol. 35, no. 11, pp. 1028–1042, 2006. View at Publisher · View at Google Scholar · View at PubMed
  2. D. J. Milliron, I. Gur, and A. P. Alivisatos, “Hybrid organic-nanocrystal solar cells,” MRS Bulletin, vol. 30, no. 1, pp. 41–44, 2005.
  3. P. Ghosh, G. Han, M. De, C. K. Kim, and V. M. Rotello, “Gold nanoparticles in delivery applications,” Advanced Drug Delivery Reviews, vol. 60, no. 11, pp. 1307–1315, 2008. View at Publisher · View at Google Scholar · View at PubMed
  4. M.-C. Daniel and D. Astruc, “Gold nanoparticles: assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology,” Chemical Reviews, vol. 104, no. 1, pp. 293–346, 2004. View at Publisher · View at Google Scholar · View at PubMed
  5. S. Kinge, M. Crego-Calama, and D. N. Reinhoudt, “Self-assembling nanoparticles at surfaces and interfaces,” ChemPhysChem, vol. 9, no. 1, pp. 20–42, 2008. View at Publisher · View at Google Scholar · View at PubMed
  6. Y. Min, M. Akbulut, K. Kristiansen, Y. Golan, and J. Israelachvili, “The role of interparticle and external forces in nanoparticle assembly,” Nature Materials, vol. 7, no. 7, pp. 527–538, 2008. View at Publisher · View at Google Scholar · View at PubMed
  7. W. H. Binder, “Supramolecular assembly of nanoparticles at liquid-liquid interfaces,” Angewandte Chemie International Edition, vol. 44, no. 33, pp. 5172–5175, 2005. View at Publisher · View at Google Scholar · View at PubMed
  8. L. M. Demers, D. S. Ginger, S.-J. Park, Z. Li, S.-W. Chung, and C. A. Mirkin, “Direct patterning of modified oligonucleotides on metals and insulators by dip-pen nanolithography,” Science, vol. 296, no. 5574, pp. 1836–1838, 2002. View at Publisher · View at Google Scholar · View at PubMed
  9. H. Duan, D. Wang, D. G. Kurth, and H. Möhwald, “Directing self-assembly of nanoparticles at water/oil interfaces,” Angewandte Chemie, vol. 116, no. 42, pp. 5757–5760, 2004. View at Publisher · View at Google Scholar
  10. A. Böker, Y. Lin, K. Chiapperini, et al., “Hierarchical nanoparticle assemblies formed by decorating breath figures,” Nature Materials, vol. 3, no. 5, pp. 302–306, 2004. View at Publisher · View at Google Scholar · View at PubMed
  11. R. B. Thompson, V. V. Ginzburg, M. W. Matsen, and A. C. Balazs, “Predicting the mesophases of copolymer-nanoparticle composites,” Science, vol. 292, no. 5526, pp. 2469–2472, 2001. View at Publisher · View at Google Scholar · View at PubMed
  12. M. R. Bockstaller, R. A. Mickiewicz, and E. L. Thomas, “Block copolymer nanocomposites: perspectives for tailored functional materials,” Advanced Materials, vol. 17, no. 11, pp. 1331–1349, 2005. View at Publisher · View at Google Scholar
  13. A. C. Balazs, T. Emrick, and T. P. Russell, “Nanoparticle polymer composites: where two small worlds meet,” Science, vol. 314, no. 5802, pp. 1107–1110, 2006. View at Publisher · View at Google Scholar · View at PubMed
  14. A. Haryono and W. H. Binder, “Controlled arrangement of nanoparticle arrays in block-copolymer domains,” Small, vol. 2, no. 5, pp. 600–611, 2006. View at Publisher · View at Google Scholar · View at PubMed
  15. W. H. Binder and R. Zirbs, “Supramolecular polymers and networks with hydrogen bonds in the main- and side-chain,” in Hydrogen Bonded Polymers, vol. 207 of Advances in Polymer Science, pp. 1–78, Springer, Berlin, Germany, 2007. View at Publisher · View at Google Scholar · View at PubMed
  16. H. Xu, R. Hong, T. Lu, O. Uzun, and V. M. Rotello, “Recognition-directed orthogonal self-assembly of polymers and nanoparticles on patterned surfaces,” Journal of the American Chemical Society, vol. 128, no. 10, pp. 3162–3163, 2006. View at Publisher · View at Google Scholar · View at PubMed
  17. H. Xu, S. Srivastava, and V. M. Rotello, “Nanocomposites based on hydrogen bonds,” in Hydrogen Bonded Polymers, vol. 207 of Advances in Polymer Science, pp. 179–198, Springer, Berlin, Germany, 2007. View at Publisher · View at Google Scholar · View at PubMed
  18. W. H. Binder, C. Kluger, C. J. Straif, and G. Friedbacher, “Directed nanoparticle binding onto microphase-separated block copolymer thin films,” Macromolecules, vol. 38, no. 23, pp. 9405–9410, 2005. View at Publisher · View at Google Scholar
  19. R. Zirbs, F. Kienberger, P. Hinterdorfer, and W. H. Binder, “Directed assembly of Au nanoparticles onto planar surfaces via multiple hydrogen bonds,” Langmuir, vol. 21, no. 18, pp. 8414–8421, 2005. View at Publisher · View at Google Scholar · View at PubMed
  20. W. H. Binder, S. Bernstorff, C. Kluger, L. Petraru, and M. J. Kunz, “Tunable materials from hydrogen-bonded pseudo block copolymers,” Advanced Materials, vol. 17, no. 23, pp. 2824–2828, 2005. View at Publisher · View at Google Scholar
  21. S. S. Kinge, M. Crego-Calama, and D. N. Reinhoudt, “Gold nanoparticle assemblies through hydrogen-bonded supramolecular mediators,” Langmuir, vol. 23, no. 17, pp. 8772–8777, 2007. View at Publisher · View at Google Scholar · View at PubMed
  22. M. J. W. Ludden, A. Mulder, R. Tampé, D. N. Reinhoudt, and J. Huskens, “Molecular printboards as a general platform for protein immobilization: a supramolecular solution to nonspecific adsorption,” Angewandte Chemie International Edition, vol. 46, no. 22, pp. 4104–4107, 2007. View at Publisher · View at Google Scholar · View at PubMed
  23. V. V. Rostovtsev, L. G. Green, V. V. Fokin, and K. B. Sharpless, “A stepwise huisgen cycloaddition process: copper(I)-catalyzed regioselective “ligation” of azides and terminal alkynes,” Angewandte Chemie International Edition, vol. 41, no. 14, pp. 2596–2599, 2002. View at Publisher · View at Google Scholar
  24. C. W. Tornøe, C. Christensen, and M. Meldal, “Peptidotriazoles on solid phase: [1,2,3]-triazoles by regiospecific copper(I)-catalyzed 1,3-dipolar cycloadditions of terminal alkynes to azides,” Journal of Organic Chemistry, vol. 67, no. 9, pp. 3057–3064, 2002. View at Publisher · View at Google Scholar
  25. W. H. Binder and C. Kluger, “Azide/alkyne-“click” reactions: applications in materials science and organic synthesis,” Current Organic Chemistry, vol. 10, no. 14, pp. 1791–1815, 2006. View at Publisher · View at Google Scholar
  26. W. H. Binder and R. Sachsenhofer, ““click” chemistry in polymer and materials science,” Macromolecular Rapid Communications, vol. 28, no. 1, pp. 15–54, 2007. View at Publisher · View at Google Scholar
  27. W. H. Binder and R. Sachsenhofer, ““click” chemistry in polymer and material science: an update,” Macromolecular Rapid Communications, vol. 29, no. 12-13, pp. 952–981, 2008. View at Publisher · View at Google Scholar
  28. W. H. Binder and C. Kluger, “Combining ring-opening metathesis polymerization (ROMP) with sharpless-type “click” reactions: an easy method for the preparation of side chain functionalized poly(oxynorbornenes),” Macromolecules, vol. 37, no. 25, pp. 9321–9330, 2004. View at Publisher · View at Google Scholar
  29. W. H. Binder, C. Kluger, M. Josipovic, C. J. Straif, and G. Friedbacher, “Directing supramolecular nanoparticle binding onto polymer films: film formation and influence of receptor density on binding densities,” Macromolecules, vol. 39, no. 23, pp. 8092–8101, 2006. View at Publisher · View at Google Scholar
  30. C. Kluger and W. H. Binder, “Functionalized poly(oxanorbornene)-block-copolymers: preparation via romp/click-methodology,” Journal of Polymer Science A, vol. 45, no. 3, pp. 485–499, 2007. View at Publisher · View at Google Scholar
  31. W. H. Binder, R. Sachsenhofer, C. J. Straif, and R. Zirbs, “Surface-modified nanoparticles via thermal and Cu(i)-mediated “click” chemistry: generation of luminescent CdSe nanoparticles with polar ligands guiding supramolecular recognition,” Journal of Materials Chemistry, vol. 17, no. 20, pp. 2125–2132, 2007. View at Publisher · View at Google Scholar
  32. Z. A. Peng and X. Peng, “Nearly monodisperse and shape-controlled CdSe nanocrystals via alternative routes: nucleation and growth,” Journal of the American Chemical Society, vol. 124, no. 13, pp. 3343–3353, 2002. View at Publisher · View at Google Scholar