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Journal of Nanomaterials

Volume 2011 (2011), Article ID 746029, 9 pages

http://dx.doi.org/10.1155/2011/746029

## Fracture Toughness of Carbon Nanotube-Reinforced Metal- and Ceramic-Matrix Composites

^{1}AML, Department of Engineering Mechanics, Tsinghua University, Beijing 100084, China^{2}Department of Mechanical Engineering, The Ohio State University, Columbus, OH 43210, USA^{3}Department of Civil and Environmental Engineering and Department of Mechanical Engineering, Northwestern University, Evanston, IL 60208, USA

Received 15 July 2010; Accepted 1 November 2010

Academic Editor: Teng Li

Copyright © 2011 Y. L. Chen et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

#### Abstract

Hierarchical analysis of the fracture toughness enhancement of carbon nanotube- (CNT-) reinforced hard matrix composites is carried out on the basis of shear-lag theory and facture mechanics. It is found that stronger CNT/matrix interfaces cannot definitely lead to the better fracture toughness of these composites, and the optimal interfacial chemical bond density is that making the failure mode just in the transition from CNT pull-out to CNT break. For hard matrix composites, the fracture toughness of composites with weak interfaces can be improved effectively by increasing the CNT length. However, for soft matrix composite, the fracture toughness improvement due to the reinforcing CNTs quickly becomes saturated with an increase in CNT length. The proposed theoretical model is also applicable to short fiber-reinforced composites.

#### 1. Introduction

Carbon nanotubes (CNTs) possess exceptionally superior physical and mechanical properties, such as high strength, low density, high flexibility, and high toughness and therefore hold great promise for employment as reinforcements in advanced composites [1–10]. However, experimental and numerical studies show that the performance of such composites depends critically on the CNT/matrix interfacial characteristics [11–13]. Interface strength and interface length are two of the most important factors that affect the mechanical properties of CNT-reinforced composites and therefore have drawn the attention of many researchers.

As a type of extraordinary reinforcements, CNTs can be incorporated in a polymer, metal, or ceramic matrix. The focus of many previous studies in CNT-reinforced composites has been on polymer-matrix materials [14–21], and researchers have tried in various ways, such as nonionic surfactant and ion bombardment [11, 16, 22, 23], to form covalent bonds between CNTs and the polymer matrix to strengthen the interface. In order to know whether longer CNTs and stronger interfaces definitely result in better mechanical properties of CNT-reinforced composites, Chen et al. [24] studied the fracture toughness enhancement of CNT-reinforced polymer-matrix composites. They found that neither longer reinforcing CNTs nor stronger CNT/matrix interfaces can definitely lead to the better fracture toughness, and the optimal interfacial chemical bond density and the optimal CNT length are those making the failure mode just in the transition from CNT pull-out to CNT break.

Meanwhile, the production and application of CNT-reinforced metal- and ceramic-matrix composites draw more and more attention. Ma and coworkers [25] formed CNT-nano-silicon-carbide (SiC)/ceramic composites and reported a 10% improvement in the strength and fracture toughness as compared to the monolithic ceramics. These modest improvements are attributed to nanotube/matrix debonding and crack deflection. The techniques to form CNT/metal-oxide composites as well as CNT/metal-matrix composites have been developed [26–31]. However, they did not provide the expected improvement in mechanical properties. Is Chen et al.’s conclusion [24] still valid for these hard matrix composites? Is there some difference between the soft matrix and hard matrix CNT-reinforced composites? This paper will focus on the case with higher matrix stiffness and study the influence factors on the fracture toughness of CNT-reinforced composites.

#### 2. Roadmap for Hierarchical Failure Analysis of CNT-Reinforced Composites

In CNT-reinforced composites with macroscopic cracks, the high strength of CNTs can retard crack propagation, and a fracture zone bridged by CNTs at the crack tip is formed, as shown in Figure 1(a). This toughening effect of bridging CNTs is equivalent to that of nonlinear springs connecting the upper and lower crack surfaces, as shown in Figure 1(b). The force-displacement relation for these springs can be obtained by studying the pulling force and pull-out displacement of a single CNT, as in Figure 1(c). This curve depends on the interfacial atomic bond properties, that is, on the interaction between atoms, as shown in Figure 1(d). Therefore, CNT-reinforced composites have three failure mode levels: a bond break at the atomistic level, CNT fiber failure mode at the mesoscopic level, and macroscopic crack propagation at the macroscopic level. To better understand and optimize the toughness of CNT-reinforced composites, this paper presents hierarchical failure analysis. We first adopt shear-lag theory to investigate CNT fiber in Section 3 and then use facture mechanics to study macroscopic-level failure in Section 4. Our conclusions are summarized in the last section.

#### 3. Force-Displacement Relation of a Single CNT Pulled from the Matrix

There are a large number of continuum mechanics studies on the fiber-reinforced composites, especially the widely used shear-lag theory [32–37]. Chon and Sun [33] studied stress distribution along a single reinforcing fiber of a randomly oriented chopped-fiber composite under the assumption of perfect bonding. Lawrence [34] assumed the stiffness of the fiber is lower than that of the matrix and investigated fiber pull-out from an elastic matrix. For ceramic composites, Marshall et al. [35] studied the cracking in brittle matrix. Hutchinson and Jensen [36] treated debonding process as a mode 2 crack to study fiber debonding and pull-out, and based on these studies, Budiansky et al. [37] accounted for an interfacial debonding resistance and studied the effects of debonding and initial stress on overall composite toughness. Many of these models are also applicable to CNT-reinforced composites. However, for the completeness and convenience to readers, the related analysis is still briefly presented in this section.

##### 3.1. Shear-Lag-Model-Based Stress Analysis of the CNT and Matrix

According to the shear-lag theory, the interaction between the CNTs and the matrix that results from the chemical bonds shown in Figure 2 is shear stress, which is related to the relative displacement between the CNT fiber and the matrix . A bond break occurs when reaches the critical shear displacement , which depends only on the type of functionalization bond at the interface, whereas the corresponding interface strength also depends on the interface bond density. The interface shear stress is assumed to be proportional to the relative displacement , that is, where is the shear stiffness of the interface and and are the axial or -direction displacements of the matrix and the CNT fiber, respectively.

Suppose the CNT and the matrix are both linear elastic, with Young’s modulus and , respectively. A representative volume element (RVE) including a single CNT with embedded length and diameter , as shown in Figure 2, is adopted for analysis. With the balance conditions of the fiber and the matrix, the shear stress distribution can be derived [24] where and are the cross-section areas of the CNT and the matrix in the RVE, is the pulling force, and depends on the material constants and geometry parameters as The distribution of the axial normal stress in the CNT can also be derived as

##### 3.2. Critical Pull-Out/Break Condition of CNTs

The two main fiber-level failure modes are usually interfacial debonding and fiber break, depending on the interfacial shear stress and the axial normal stress, respectively. When the composite is under increasing tension, both the shear stress on the interface and the axial normal stress in the CNT increase.

###### 3.2.1. Critical Condition for CNT Fiber Break

Obviously, the maximum axial normal stress in the CNT is located at position and can be expressed as CNT break occurs when the maximum axial normal stress reaches CNT strength , and the corresponding critical pulling force is

###### 3.2.2. Critical Condition for Interfacial Debonding

According to (2), the maximum shear stress on the interface may appear at either for or for . In CNT/polymer composites, the stiffness of the CNT is usually greater than that of the matrix, that is, , as Chen et al. have previously discussed in [24], but in metal- and ceramic-matrix composites Young’s modulus of the matrix is close to that of the CNTs, so the stiffness of the CNT is less than that of the matrix, that is, . The current paper is focused on this hard matrix regime and sometimes also presents the results of soft matrix regime for comparison.

*(1) Case (Hard Matrix)*

From (2), the maximum shear stress on the interface can be found at the position, and
The corresponding critical pulling force is
Together with (6) and (8), the transition condition between the pull-out and break failure modes is
that is, a weak interface results in interfacial debonding and fiber pull-out, whereas a strong interface leads to fiber break.

*(2) Case (Soft Matrix)*

The most important difference from the hard matrix case (i.e., ) is that the maximum shear stress on the interface is found at the position, so the critical pulling force is [24]
and the transition condition between the pull-out and break failure modes is [24]

##### 3.3. Relation between Pulling Force and Pull-Out Displacement

For different possible failure modes, there are three types of curves, as shown in Figures 3(a), 3(b), and 3(c). Here, is the pulling force, and is the pull-out displacement. The corresponding relations are given as below.

###### 3.3.1. CNT Break Case

The relation can be obtained as where is the stiffness ratio of the matrix to the CNT, and

###### 3.3.2. Interface Debonding from the End of Pulling Force (Hard Matrix)

If , the interface begins to debond at the position where the relative displacement reaches . So the critical pull-out displacement for the interfacial debonding case is At this time, the relative displacement at the position is , which is less than , so the interface is not debonded completely and can still stand some degree of shear stress. After this point, the curve decreases until the interface debonds completely. In the process of debonding, the CNT and the matrix can be analyzed as a similar system but with a shorter interface length (). Both the pulling force and the pull-out displacement are dependent on the new interface length as follows: Getting rid of from the above two equations, we can get the relation between the pulling force and the pull-out displacement after the beginning of interface debonding as So the relation between the pulling force and the relative displacement is where is solved from (16) and the maximum pull-out displacement is determined by This process is shown in Figure 3(b), and the critical point is given by (14) and (8), respectively. It is interesting to notice that after the initial debonding at , the interface first debonds gradually and steadily, with the gradual deceasing pulling force, but when the pull-out displacement reaches , the whole bonding interface debonds simultaneously and the pulling force drops down to zero suddenly.

###### 3.3.3. Interface Debonding from the End Away from Pulling Force (Soft Matrix)

As discussed by Chen et al. in [24], if , the relation is where

The curve is shown in Figure 3(c), and the critical point is given by (20) and (10), respectively. Different from the other debonding case in Section 3.3.2, the interface debonds gradually and steadily, until it goes down to zero.

#### 4. Macroscopic-Level Fracture Failure Analysis

##### 4.1. Fracture Toughness Enhancement

In CNT-reinforced composites, crack propagation is retarded by the pulling force of the CNTs at the crack surface, the so-called “bridge-toughening effect.” The displacement of the crack surface (i.e., half of the crack opening displacement) is [38] where is the distance to the crack tip and depends only on Young’s modulus and Poisson’s ratio . According to (12), (17), and (19), for all different types of failure modes, the pulling force can be expressed as a function of the distance to the macroscopic crack tip , that is, . The homogenized traction on the crack surface is then and the fracture toughness enhancement can be computed as [39]

##### 4.2. Factors Affecting the Fracture Toughness Enhancement

For the case of hard matrix (), the factors affecting the fracture toughness enhancement are discussed below, and some results of soft matrix regime in [24] are also presented briefly for comparison.

###### 4.2.1. Effect of Interface Length

From the pull-out/break critical condition (9), we know that if , the failure mode should always be the CNT pull-out, as shown in Figure 4(a). In this case, the fracture toughness enhancement increases with an increase in the interface length infinitely. This phenomenon is different from the case of weak interface in the soft matrix CNT-reinforced composites shown in Figure 4(b), in which an upper limit of the fracture toughness enhancement exists so any further lengthening of the CNTs improves the fracture toughness of the composites only slightly [24].

For the case with strong interface , as shown in Figure 4(c), a critical length exists and can be determined from the pull-out/break critical condition (9): When , the CNT is pulled out, and the fracture toughness enhancement increases with an increase in the interface length . If is further increased beyond the critical length , the failure mode is converted from CNT pull-out to CNT break and drops significantly. In this regime, the fracture toughness enhancement decreases with an increase in and finally approaches the following value: It is interesting to note that, in this case, lengthening the interface beyond the critical length can even decrease the fracture toughness, which is very similar to the result shown is Figure 4(d) for the soft matrix CNT-reinforced composites [24].

###### 4.2.2. Effect of Interface Strength

Another important factor affecting the toughness enhancement is interface strength , and its effect is shown in Figure 5(a). When is small, the failure mode is CNT pull-out, and the fracture toughness enhancement increases with an increase in . Further increasing beyond the critical interface strength , which can be determined by the pull-out/break critical condition (9), leads the failure mode to be converted from CNT pull-out to CNT break, and drops significantly. In this regime, the toughness enhancement decreases with an increase in . This result agrees with the experimental and numerical studies of Xia et al.’s work on ceramic-matrix composites [40, 41], as well as the theoretical studies for soft matrix CNT-reinforced composites in Figure 5(b) [24]. Therefore, for CNTs with a given length, the maximum fracture toughness of the composite is achieved when is only slightly smaller than the critical interface strength .

##### 4.3. Optimization of Fracture Toughness Enhancement

In this subsection, we attempt to optimize the composite fracture toughness for the case of by tailoring both the interface length and interface strength , which is essentially a bivariate optimization problem. For convenience, we use another group of variables, normalized interface length and , instead. According to (9), the maximum with a given can be achieved when Figure 6 shows the normalized fracture toughness enhancement versus for cases with different stiffness ratios: . It is found that when , reaches an infinite value. And according to (26), the corresponding optimal interface strength is This result is different from the case of studied by Chen et al. [24], which presents the upper limit of the fracture toughness enhancement, as shown in Figure 6 with the dashed lines. When , the value of the dimensionless fracture toughness enhancement increases with unlimitedly, as shown in Figure 6 by the solid lines. So, there is neither upper limit for nor optimal value for the CNT length . The optimal CNT length can only depend on the preparation level and some other factors such as the critical CNT length for clustering and self-folding [42].

#### 5. Conclusions

Combining the shear-lag model and fracture mechanics, we have carried out the hierarchical failure analysis on CNT-reinforced composites with hard matrix. The following conclusions have been reached.

(1) Stronger CNT/matrix interfaces cannot definitely lead to a better fracture toughness of these composites. In contrast, the optimal interfacial chemical bond density is that making the failure mode just in the transition from CNT pull-out to CNT break.

(2) For composites with hard matrix, there exists a critical interface strength, below which the CNT is always pulled out, and the fracture toughness can be effectively improved by increasing the interface length . However, for soft matrix composite, the fracture toughness improvement due to the reinforcing CNTs quickly becomes saturated with an increase in CNT length.

It should be noted that the theoretical analysis and conclusions drawn in this paper can also be extended to fiber-reinforced composites.

#### Acknowledgments

The authors acknowledge the support of the National Natural Science Foundation of China (Grant nos. 10702034, 10732050, 90816006 and 10820101048) and the National Basic Research Program of China (973 Program), Grant nos. 2007CB936803 and 2010CB832701.

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