Cast Nanostructured Films of Poly(methyl methacrylate-b-butyl acrylate)/Carbon Nanotubes: Influence of Poly(butyl acrylate) Content on Film Evaporation Rate, Morphology, and Electrical Resistance

Table 2

Results of the synthesis of macrochains transfer agents and block copolymers by RITP.

	Step 1. Synthesis of PMMA				Step 2. Copolimerization PMMA-b-PBuA
Exp	^aXPMMA	^bMnTh1	^cMnPMMA (g/mol)	^dIPMMA	XPMMA	XPBuA	^eMnTh2	^fMnCopol (g/mol)	ICopol	^gPMMA : PBuA
1	0.85	54000	44500	1.4	0.99	0.70	56000	48000	1.6	93 : 7
2	0.89	44000	29000	1.6	0.99	0.60	41000	38000	1.9	80 : 20
3	0.90	32000	24000	1.8	0.99	0.44	38000	31000	1.9	70 : 30

^aX is the fractional conversion; ^bMn_Th1 is the theoretical Mn for PMMA macrochain transfer agent; ^cMn_PMMA is the experimental Mn for PMMA; ^dI is the polydispersity index; ^eMn_Th2 is the theoretical Mn for the copolymer; ^fMn_Copol is the experimental Mn for the copolymer; ^gPMMA : PBuA is the PMMA and PBuA composition calculated by ¹H NMR.