Relationship between Synthesis Conditions and Photocatalytic Activity of Nanocrystalline TiO<sub>2</sub>

Han, Yosep; Kim, Hyung-Seok; Kim, Hyunjung

doi:https://doi.org/10.1155/2012/427453

Journal of Nanomaterials

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Abstract Introduction Materials and Methods Results and Discussion Conclusions Acknowledgments References Copyright Related Articles

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Synthesis, Characterization, Properties, and Applications of Nanosized Photocatalytic Materials

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Research Article | Open Access

Volume 2012 | Article ID 427453 | https://doi.org/10.1155/2012/427453

Relationship between Synthesis Conditions and Photocatalytic Activity of Nanocrystalline TiO₂

Yosep Han,¹Hyung-Seok Kim,²and Hyunjung Kim³

Academic Editor: Jiaguo Yu

Received25 Mar 2012

Revised03 Jun 2012

Accepted03 Jun 2012

Published24 Jul 2012

Abstract

The degradation efficiency of methylene blue by TiO₂ nanoparticles, which were synthesized under different synthesis conditions (i.e., molar ratio of water and titanium tetraisopropoxide (TTIP), pH, and calcination temperature) in a sol-gel process, was systematically investigated. The results showed that increasing the molar ratio of water and TTIP led to the enhanced photocatalytic activity of TiO₂ nanoparticles, which were likely attributed to the increased specific surface area of TiO₂ nanoparticles synthesized with high molar ratio. The results were supported by the relative increase in the size of interaggregated pores of the aggregated TiO₂ nanoparticles. The best photocatalytic activity of TiO₂ nanoparticles was observed at acidic synthesis conditions; however, the results were not consistent with physical properties for the crystallinity and the crystallite size of TiO₂ nanoparticles but rather explained by the presence of abundant hydroxyl groups and water molecules existing on the surface of TiO₂ under acidic synthesis environments. Furthermore, methylene blue degradation experiments revealed that the photocatalytic activity of TiO₂ nanoparticles was maximized at the calcination temperature of 700°C. The trend was likely due to the combined effect of the anatase crystallinity which showed the highest value at 700°C and the crystallite size/specific surface area which did not excessively increase up to 700°C.

1. Introduction

TiO₂ is utilized in different environmental applications, such as gas sensors [1, 2] and photocatalytic degradation of various contaminants in waste-air and/or wastewater treatment [3–6]. TiO₂ usually has two crystalline phases, anatase ( eV) and rutile ( eV), and the anatase phase frequently exhibits higher photocatalytic activity than the rutile phase [7–10]. The most popular commercial TiO₂ named by Degussa P25, containing around 70% anatase and 30% rutile, is known to possess excellent photocatalytic activity [7, 11]. The high activity of Degussa P25 was mainly attributed to the mixed phase composition and the high anatase crystallinity, which would favor photo-induced charge separation as well as large specific surface area.

In addition to the phase composition, the specific surface area and anatase crystallinity are important factors influencing the photocatalytic performance of TiO₂. Photocatalytic reactions using TiO₂ particles degrade pollutants by interaction with contaminants on the surfaces of the particles. Therefore, as the specific surface area of the particles increases, the contact area with contaminants increases and consequently the degradation efficiency increases. Also, increasing anatase crystallinity results in the decrease in the recombination rate of the electrons and holes so that the photocatalytic efficiency improves [7, 12, 13].

Generally, a sol-gel method based on the hydrolysis of titanium alkoxide is widely used to synthesize TiO₂ nanoparticles [14]. However, this method encounters some problems, such as weak anatase crystallinity and poor monodispersity. In addition, nanocrystalline TiO₂ prepared by the sol-gel method undergoes both phase transformation and crystallite size growth even at relative low temperature [15]. To apply TiO₂ particles synthesized from the sol-gel process as photocatalytic catalysts, it is important to maintain high anatase crystallinity [16]. Previous study reported that high degree of anatase crystallinity can be achieved without high temperature calcination when TiO₂ particles were synthesized at low temperature due to fast hydrolysis and slow condensation [17]. In addition, many studies regarding the evaluation of the photocatalytic activity of TiO₂ nanoparticles have been conducted (e.g., [12, 18–20]); however, few focused on the correlation between parameters used in the synthesis process of TiO₂ nanoparticles and their photocatalytic activity [18, 21].

Therefore, this study was designed to investigate the effect of synthesis conditions (i.e., molar ratio (water: titanium tetraisopropoxide (TTIP)), pH, and calcination temperature) on physicochemical surface characteristics (e.g., specific surface area, pore volume, crystallinity, and crystallite size of synthesized TiO₂, and functional groups onto the surface of TiO₂ nanoparticles) as well as initial photocatalytic activity of TiO₂ nanoparticles for the samples synthesized under different conditions.

2. Materials and Methods

2.1. Preparation of TiO₂ Nanoparticles

The nanocrystalline TiO₂ particles were prepared via a sol-gel process using TTIP (Sigma-Aldrich, St. Louis, MO) and deionized water (Milli-Q, Millipore, Bedford, MA) as the starting materials. TTIP was dissolved in anhydrous alcohol (Sigma-Aldrich). The molar composition of the prepared solution was 1 : 30 (TTIP : alcohol). The controlled solution was then added dropwise to a known amount of deionized water. The molar ratios of deionized water and TTIP were set to 2, 5, 10, 20, and 50. In order to investigate the effect of the synthesis pH value on the phase transformation (anatase to rutile) and crystallite size, hydrochloric acid or aqueous ammonia was dropped into the mixed solution to yield gels with different pH values. The hydrolysis reaction was maintained under agitation condition at a reaction temperature of 20°C for 24 h. Under these conditions, the precipitation took place rapidly. The as-synthesized samples were recovered by centrifugation (MF80, Hanil, Seoul, Korea), rinsed with deionized water and alcohol, and dried at 80°C for 24 h. The synthesized TiO₂ nanoparticles were calcined with a heat rising rate of 3°C min⁻¹ and a keeping time of 2 h. The temperature range investigated herein was 400–1000°C.

2.2. Photocatalytic Activity

A quartz glass reactor with a lamp immersed in the inner part of the reactor was used for all the photocatalytic experiments. The batch reactor was filled with 250 mL of an aqueous dispersion in which the concentrations of TiO₂ and methylene blue were 0.5 g L⁻¹ and 10 mg L⁻¹, respectively. Photocatalytic activity of the synthesized TiO₂ was compared with that of P25, and the solution without TiO₂ catalysts was set as the point of comparison to consider the effect of pure degradation by the light source. In order to quantitatively compare the relative photocatalytic activity of TiO₂ samples, first-order reaction rate constant () for each sample was obtained from the degradation data with irradiation time [22]. Prior to the emission of UV light, the reactor containing TiO₂ particles and methylene blue was left for 30 min in a dark room to allow the adsorption/desorption equilibrium condition to be met [23]. A 120 W high pressure mercury lamp (Daesung Lamp Co., Republic of Korea) with a wavelength of 320–400 nm (a maximum emission at about 350 nm) and a light intensity of 12.0 MW cm⁻² at 350 nm was used as UV light sources. After photocatalytic reaction, the samples were immediately centrifuged and the quantitative determination of methylene blue was performed by a UV-vis spectrophotometer (CE 3041, Cecil, UK).

2.3. Characterization of TiO₂ Nanoparticles

X-ray diffraction (XRD) studies were carried out by using an X-ray diffractometer (Bruker D8 HRXRD, Germany). X-ray diffraction patterns were recorded using CuKα radiation in the step-scan mode with a 2 range of 10° to 80°. The scanning was performed in steps of 0.015° 2 with an interval of 10 sec. The crystallite size and the relative amounts of the anatase and rutile phase were calculated from the (101) reflection of anatase and the (110) reflection of rutile. The crystallite size of anatase and rutile phase was calculated using the Scherrer’s equation [22]: where is the crystallite size, is the wavelength of the X-ray radiation (CuKα = 0.15406 nm, 40 kV, 40 mV), k is a constant that was set to 0.94, is the diffraction angle, and is the line width at half maximum height. The weight fractions of anatase present in TiO₂ nanoparticles synthesized under various conditions were calculated using the equation given below [24]: where is the weight fraction of the anatase phase, is the diffraction peak intensity of the anatase (101) phase, and is the diffraction peak intensity of the rutile (110) phase. Nitrogen adsorption to synthesized nanoparticles was measured using an AutoSorb-1 system from Quantachrome Instruments (Syosset, NY). The samples were evacuated prior to each measurement at 300°C in a high vacuum for 6 h. Specific surface area, pore size distributions, and pore volume were calculated from nitrogen adsorption isotherms. Specific surface area () was calculated from the data obtained from partial relative pressure ranged between 0.05 and 0.25 using the Brunauer-Emmett-Teller (BET) method [25, 26]. Pore volume and pore size distributions were determined from the amount of nitrogen adsorbed at a relative pressure of 0.99 and by the Barrett-Joyner-Halenda (BJH) method [27, 28]. The morphology of prepared TiO₂ nanoparticles was determined by transmission electron microscopy (FE-TEM, JEM-2100F, JEOL, Japan). The accelerating voltage of the electron beam was 220 kV. The samples for TEM measurements were suspended in ethanol and dropped onto holey carbon films supported on Cu grids for imaging. Surface functional groups were examined using a Fourier transform infrared spectrometer (FT-IR, FT/IR-4100, JASCO, Japan) in the range of 650–4000 cm⁻¹.

3. Results and Discussion

3.1. Effect of Molar Ratio of Water and TTIP on Photocatalytic Activity of TiO₂

Figure 1 and Table 1 represent the initial adsorption amount of methylene blue and the photocatalytic activity of synthesized TiO₂ according to the amount of water added during TiO₂ synthesis process. The pH of the water added was 7, and the calcination temperature was set to 600°C. The adsorption amount of methylene blue increased with increasing molar ratio, which is consistent with increasing specific surface area of TiO₂ samples with increasing molar ratio (Table 2). For the photocatalytic activity of TiO₂ samples, greater degree of degradation for methylene blue was observed for higher water concentration ranges, and particularly the enhancement of photocatalytic activity was pronounced when the molar ratio was greater than 20 (i.e., and 0.846 h⁻¹ for the samples with molar ratio of 50 and 20, resp.). Moreover, except for the TiO₂ sample produced with a molar ratio of 2, all samples were found to have higher activity than P25.

Figure 2 and Table 2 show an XRD pattern of the synthesized TiO₂ prepared with different molar ratios of water and TTIP. The XRD peaks at and are known to be the characteristic peaks of anatase (101) and rutile (110) crystal phases, respectively [5]. An anatase (101) phase started to appear from the sample with a molar ratio of 2, and the phase was maintained until the molar ratio was 20. The existence of the anatase phase over the broad range of molar ratio is likely due to the calcination temperature (i.e., 600°C) [15]. However, the TiO₂ samples with the molar ratio of 50 exhibited a rutile peak, indicating that phase transition from anatase to rutile started to occur at this point (Figure 2 and Table 2). This suggests that excessive water additive caused a phase transition for the synthesized TiO₂ as observed from a previous study [29]. However, regardless of the molar ratio, the crystallite size for the synthesized TiO₂ samples was consistently measured to be about 18-19 nm (Table 2), indicating that the crystallite size of the synthesized TiO₂ was not significantly affected by the water amount added.

In order to understand the effect of molar ratio of water and TTIP on the photocatalytic activity of synthesized TiO₂, physical properties (i.e., pore volume and specific surface area) of the synthesized TiO₂ particles were evaluated, and the results are presented in Table 2. The results showed that the specific surface area and pore volume increased with increasing molar ratio (i.e., increasing water amount). Particularly, for the TiO₂ sample synthesized with the largest molar ratio of 50, the specific surface area and pore volume were determined to be 63.9 m²g⁻¹ and 110 mm³g⁻¹, respectively. Figure 3 shows TEM images to show the morphology of the synthesized TiO₂ nanoparticles for the highest and lowest molar ratio (molar ratio = 50 for Figures 3(a) and 3(b) and molar ratio = 2 for Figures 3(c) and 3(d)). No difference in the particle shape was observed for the two samples with respect to the TiO₂ synthesis conditions. In addition, the synthesized particles were found to be aggregated and form many inter-aggregated pores. Hence, it is reasonable to hypothesize that the greater specific surface area and pore volume for the TiO₂ nanoparticles with higher molar ratio are likely due to the formation of more pores by the cohesion between aggregated particles. This hypothesis is supported by the result for the distribution of the pore sizes (Figure 4) for the synthesized TiO₂ samples according to the amount of water added. When a relatively small amount of water was added (molar ratio ≤ 10), the TiO₂ nanoparticles were found to mostly possess pores with the size of 2–5 nm; however, when molar ratio was greater than 20, the extra pores greater than 5 nm were observed to form. Moreover, for the samples with molar ratio of 20 and 50, it was observed that large quantity of extra pores with the size of 10 and 8 nm, respectively, formed as compared to those with low molar ratio. This result further confirmed that higher dosage of water led to the greater formation of the inter-aggregated pores due to the cohesion between TiO₂ nanoparticles. Consequently, larger specific surface area and higher pore volume for the synthesized TiO₂ nanoparticles with high molar ratio are thought to lead to better degradation efficiency for methylene blue [30–32].

(a)

(b)

(c)

(d)

3.2. Effect of Synthesis pH on Photocatalytic Activity of TiO₂

In order to investigate the effect of synthesis pH on photolysis efficiency of TiO₂ nanoparticles, the degradation rate of methylene blue by TiO₂ nanoparticles, which was synthesized under various pH levels of water, was examined and the results are presented in Figure 5 and Table 1. The amount of water added as a hydrolysis reagent was 5 mol (i.e., molar ratio of water and TTIP = 5), and the calcination temperature was fixed to 600°C. Similar with the results for molar ratio, the adsorption amount of methylene blue was greater than for the samples with high specific surface area (Tables 1 and 3).

Overall, the samples synthesized at low pH conditions exhibited greater photocatalytic activity than P25 (i.e., h⁻¹ for P25 and h⁻¹ for all samples synthesized) (Table 1). Especially, the TiO₂ sample synthesized at pH 2.5 showed the best photocatalytic activity (i.e., h⁻¹). The above results indicate that photocatalytic activity of synthesized TiO₂ nanoparticles is a function of the synthesis pH of water which was used as a hydrolysis reagent [33].

Figure 6 and Table 3 illustrate XRD patterns of TiO₂ samples synthesized under different pH conditions. Anatase phase was observed when hydrolysis reagent was acidic (pH ≤ 7), but as pH increased, crystalline phase of synthesized TiO₂ showed a transition to the rutile phase (pH ≥ 9), which is consistent with the results observed from a previous study [29]. Specifically, an anatase phase was observed at pH 2.5, and the anatase peak increased up to pH 7 with maximum peak value (Figure 5); however, rutile peak started to be observed at pH 9, and the peak was more pronounced for the sample at pH 11.

The sizes of TiO₂ synthesized under different pH were observed to increase in accordance with increasing pH (Table 3). It has been known that phase transition of TiO₂ led to the increase in crystallite size [34], which is consistent with our results. Specifically, as the synthesis pH increased, phase transition occurred in synthesized TiO₂ nanoparticles, and eventually crystallite size slightly increased. The results from both crystalline phase and crystallite size for synthesized TiO₂, suggest that photocatalytic activity of TiO₂ is expected to be maximized at pH 7 since anatase crystallinity was greatest at pH 7 with similar crystallite size as compared to that at other pH conditions [35–37]. However, samples synthesized at acidic conditions (i.e., pH 2 and 4) showed the best photocatalytic activity, implying that it was not enough to explain the result of photocatalytic performance only by the properties of crystallinity and crystallite size of TiO₂ nanoparticles.

Previously, some studies reported that the more OH groups existed on the surface of TiO₂, the greater photocatalytic activity appeared [38, 39]. Hence, the degree of OH groups existing on the surface of synthesized TiO₂ samples was also investigated using FT-IR spectra in this study. The FT-IR spectra of the nanocrystallite TiO₂ powders are shown in Figure 7. The broad peak appearing between 3200 and 3600 cm⁻¹ is assigned to the stretching vibrations of the OH groups [40]. The peaks in the range of 1620–1630 cm⁻¹ are attributed to the bending vibrations of the surface-adsorbed water molecules [41]. The main peak appearing in the range 650–700 cm⁻¹ corresponds to Ti–O and Ti–O–Ti stretching vibrations [41, 42]. The FT-IR spectra of all samples showed the characteristic peaks of Ti–O and Ti–O–Ti stretching vibrations in the range of 650–700 cm⁻¹. However, the amount of adsorbed water molecules and hydroxyl groups was different between the samples synthesized at different pH conditions as evidenced by the intensity of the bands corresponding to the bending vibrations of surface-adsorbed molecules (1620–1630 cm⁻¹) and the stretching vibrations of the hydroxyl groups (3200–3600 cm⁻¹). Relatively huge difference in the FT-IR spectra was observed in the intensity of the peak appearing between 3200 and 3600 cm⁻¹ assigned to the stretching vibrations of the hydroxyl group. Additionally, the sample synthesized under more acidic conditions was observed to possess larger amount of adsorbed water. The FT-IR results indicate that the amount of adsorbed water molecules and hydroxyl groups on the surface of TiO₂ nanoparticles is closely related to their photocatalytic activity. It has been previously reported that, during a sol-gel process under low pH condition, hydrolysis reaction is facilitated and condensation reaction is delayed [17].

Furthermore, it has been also reported that, under acidic conditions, positive charge of OR group partially increased to accelerate the hydrolysis reaction because OH group can easily attach on the surface of titanium ions in accordance with increasing repulsive force between positive charge of titanium ion and the OR group [17, 43, 44]. Consistent with the previous studies, our results also suggest that, under the low pH condition, the interaction between hydrogen and oxygen actively occurred during hydrolysis reaction, leading to the formation of water molecules adsorbed on the surface of the TiO₂ powder, and accordingly, the increasing concentration of hydroxyl group and water molecules on the surface of TiO₂. Therefore, the FT-IR (Figure 7) and methylene blue degradation experimental results (Figure 5 and Table 1) implied that photocatalytic activity of TiO₂ nanoparticles was enhanced under low synthesis pH conditions due to the presence of abundant hydroxyl groups and water molecules existing on the surface of TiO₂. Yu et al. [33] also observed the similar trend which was attributed to the improved acidity (i.e., the number of surface acid sites) of the samples synthesized at acidic pH conditions pH.

3.3. Effect of Calcination Temperature on Photocatalytic Activity of TiO₂

Figure 8 and Table 1 show methylene blue degradation efficiency by TiO₂ nanoparticles synthesized at pH 7 with a 5 mol addition of water (i.e., molar ratio of water and TTIP = 5) according to different calcination temperatures. For the reactors without TiO₂ particles, no degradation was observed above 5 min after UV irradiation. On the other hand, all calcined TiO₂ samples showed continuous methylene blue degradation. The efficiency increased up to 700°C (e.g., h⁻¹ for the sample calcined at 700°C) but decreased with calcination temperature above that point ( h⁻¹ when calcination temperature > 700°C). A similar trend was also observed from several previous studies [45–47]. Additionally, the sample calcined at 1000°C only exhibited photocatalytic activity up to 20 min, and even after about 80 min the degree of activity was almost identical with that of the samples calcined at 500°C or below (Figure 8). The trend is likely due to relatively short reaction time (i.e., ca. 90 min) investigated in this study, which may not be enough to see the distinct difference between both samples (Figure 8) [24, 48, 49]. Another plausible explanation could be the combined effect of the degree of crystallinity which was improved with increasing temperature and the specific surface area which decreased with increasing calcination temperature (Table 4).

In order to understand the trend for the methylene blue degradation efficiency by TiO₂ nanoparticles with different calcination temperatures, crystalline structure and crystallite size of TiO₂ nanoparticles were investigated. Figure 9 and Table 4 show XRD patterns for TiO₂ nanoparticles calcined at different temperatures. Anatase peak started to appear at 400°C and increased up to 700°C. Rutile phase started to appear at 700°C, and the intensity increased from that point with almost no anatase phase at 900°C (i.e., anatase phase content = ~3.7 at 900°C) (Table 4). It was also observed that anatase phase was totally disappeared and transformed to rutile phase at 1000°C. This result is consistent with a previous study which reported that TiO₂ synthesized via a common sol-gel process showed phase transition at around 600°C or higher temperature [15]. Crystallite size of TiO₂ particles with different calcination temperatures is also presented in Table 4. Overall, crystallite size increased with increasing calcination temperature, showing substantial increase at the temperature range between 700 and 800°C. More specifically, the anatase crystallite size of the samples calcined at 700 and 800°C was determined to be 28.5 and 58.9 nm, respectively (Table 4). These results suggest that crystallite size and phase transition were much more influenced by calcination temperature as compared to the amount of water addition (i.e., molar ratio of water and TTIP) and pH among the variables adjusted in the process of TiO₂ synthesis investigated herein.

Specific surface area and pore volume of TiO₂ particles synthesized at different calcination temperatures are listed in Table 4. Specific surface area and pore volume of the sample with lowest calcination temperature (i.e., 400°C) were determined to be 83.3 m²g⁻¹ and 85 mm³g⁻¹, respectively. However, both specific surface area and pore volume gradually decreased with increasing calcination temperature, and the sample calcined at 1000°C showed the lowest values ( = 16.1 m²g⁻¹ and pore volume = 26 mm³g⁻¹). These results are consistent with the finding from the previous study which reported the inverse relationship between crystallite size and specific surface area [23]. If specific surface area and pore volume of TiO₂ nanoparticles were dominant factors controlling the photocatalytic activity of TiO₂, the activity would have decreased with calcination temperature; however, the activity showed the maximum value at 700°C. The trend is likely attributed to the combined effect of anatase crystallinity which showed the highest intensity at 700°C (Figure 9) [13] and crystallite size which did not excessively increase up to 700°C (Table 4). Furthermore, the decreasing photocatalytic activity for the samples with a calcination temperature of 800°C or above could be explained by the decreased specific surface area and the subsequent reduction in the adsorption sites for the degradation reaction due to the decrease in anatase crystallinity and the excessive growth in crystallite size [31, 32].

4. Conclusions

In the present study, the degradation behavior of methylene blue by TiO₂ nanoparticles, which were synthesized under different synthesis conditions (i.e., molar ratio of water and TTIP, pH, and calcination temperature) in a sol-gel process, was investigated. The correlation between physical properties and photocatalytic activity of TiO₂ nanoparticles according to the different synthesis conditions is as follows.(i)The amount of water added (i.e., molar ratio of water and TTIP), which was used as hydrolysis reagent, did not significantly influence the change in the crystallite size of TiO₂ nanoparticles; however, anatase crystallinity slightly decreased for the TiO₂ synthesized with large molar ratio of water and TTIP (i.e., 50). The increasing molar ratio led to the enhanced photocatalytic activity of TiO₂ nanoparticles. The results were likely attributed to the increased specific surface area of TiO₂ nanoparticles synthesized with high molar ratio, which resulted from the relative increase in the size of the inter-aggregated pores of aggregated TiO₂ nanoparticles.(ii)TiO₂ nanoparticles synthesized at acidic conditions (i.e., pH 2 and 4) showed the best photocatalytic activity. However, the results were not explained by the physical properties for the crystallinity and the crystallite size of TiO₂ nanoparticles but explained by the extent of active surface functional groups (e.g., hydroxyl group). Specifically, under low pH conditions, photocatalytic activity of TiO₂ nanoparticles was enhanced by the presence of abundant hydroxyl groups and water molecules existing on the surface of TiO₂.(iii)Methylene blue degradation experiments revealed that the photocatalytic activity of TiO₂ nanoparticles was maximized at the calcination temperature of 700°C. However, specific surface area and pore volume of TiO₂ nanoparticles gradually decreased with increasing calcination temperature, indicating that those physical properties were not critical for controlling the photocatalytic activity of TiO₂ nanoparticles. The trend was likely due to the combined effect of the anatase crystallinity which showed the highest value at 700°C and the crystallite size which did not excessively increase up to 700°C.

The findings from this study indicate that physical properties of TiO₂ nanoparticles, which played an important role on photocatalytic activity of TiO₂, can be controlled by varying the synthesis conditions, such as amount of water addition (i.e., molar ratio of water and TTIP), pH, and calcination temperature.

Acknowledgments

This paper was supported by the Basic Research Project (12-530290) of the Korea Institute of Geoscience and Mineral Resources (KIGAM) and funded by the Ministry of Knowledge Economy of Korea.

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Copyright © 2012 Yosep Han et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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