Synthesis, Characterization, and Applications of ZnO Nanowires

Zhang, Yangyang; Ram, Manoj K.; Stefanakos, Elias K.; Goswami, D. Yogi

doi:https://doi.org/10.1155/2012/624520

Journal of Nanomaterials

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Review Article | Open Access

Volume 2012 | Article ID 624520 | https://doi.org/10.1155/2012/624520

Synthesis, Characterization, and Applications of ZnO Nanowires

Yangyang Zhang,¹Manoj K. Ram,¹Elias K. Stefanakos,¹and D. Yogi Goswami¹

Academic Editor: Tong Lin

Received13 Jan 2012

Accepted18 Apr 2012

Published17 Jul 2012

Abstract

ZnO nanowires (or nanorods) have been widely studied due to their unique material properties and remarkable performance in electronics, optics, and photonics. Recently, photocatalytic applications of ZnO nanowires are of increased interest in environmental protection applications. This paper presents a review of the current research of ZnO nanowires (or nanorods) with special focus on photocatalysis. We have reviewed the semiconducting photocatalysts and discussed a variety of synthesis methods of ZnO nanowires and their corresponding effectiveness in photocatalysis. We have also presented the characterization of ZnO nanowires from the literature and from our own measurements. Finally, a wide range of uses of ZnO nanowires in various applications is highlighted in this paper.

1. Introduction

Nanomaterials have attracted tremendous interest due to their noticeable performance in electronics, optics, and photonics. Nanomaterials are typically classified into three groups: 0-dimensional, 1-dimensional, and 2-dimensional. 0-dimensional nanostructures, referred to as quantum dots or nanoparticles with an aspect ratio near unity, have been extensively used in biological applications [1, 2]. 2-dimensional nanomaterials, such as thin films, have also been widely used as optical coatings, corrosion protection, and semiconductor thin film devices. One-dimensional (1D) semiconductor nanostructures such as nanowires, nanorods (short nanowires), nanofibres, nanobelts, and nanotubes have been of intense interest in both academic research and industrial applications because of their potential as building blocks for other structures [3]. 1D nanostructures are useful materials for investigating the dependence of electrical and thermal transport or mechanical properties on dimensionality and size reduction (or quantum confinement) [4]. They also play an important role as both interconnects and functional units in the fabrication of electronic, optoelectronic, electrochemical, and electromechanical nanodevices [5]. Among the one-dimensional (1D) nanostructures, zinc oxide (ZnO) nanowire is one of the most important nanomaterials for nanotechnology in today’s research [6].

ZnO is a semiconductor material with a direct wide band gap energy (3.37 eV) and a large exciton binding energy (60 meV) at room temperature [7]. ZnO is also biocompatible, biodegradable, and biosafe for medical and environmental applications [8]. ZnO crystallizes in two main forms, hexagonal wurtzite and cubic zinc blende. Under general conditions, ZnO exhibits a hexagonal wurtzite structure. The crystalline nature of ZnO could be indexed to known structures of hexagonal ZnO, with nm, nm, and nm (JCPS card no. 36–1451) [9]. The ratio of of about 1.60 is close to the ideal value for a hexagonal cell [10]. The structure of ZnO could be described as a number of alternating planes composed of tetrahedrally coordinated O^2- and Zn²⁺ stacked alternately along the c-axis (Figure 1(a)). The O^2- and Zn²⁺ form a tetrahedral unit, and the entire structure lacks central symmetry (Figure 1(b)). Due to their remarkable performance in electronics, optics, and photonics, ZnO nanowires are attractive candidates for many applications such as UV lasers [11], light-emitting diodes [12], solar cells [13], nanogenerators [14], gas sensors [15], photodetectors [16], and photocatalysts [17]. Among these applications, ZnO nanowires are being increasingly used as photocatalysts to inactivate bacteria and viruses and for the degradation of environmental pollutants such as dyes, pesticides, and volatile organic compounds under appropriate light irradiation [18, 19].

(a)

(b)

This paper reviews recent research in ZnO nanowires (or nanorods) with an emphasis on ZnO nanowires used in photocatalysis. In the following sections we have reviewed different semiconductor photocatalysts, compared their properties, and discussed a variety of synthesis methods of ZnO nanowires. We have also presented the characterization of ZnO nanowires from both the literature and our own measurements. Finally, a wide range of ZnO nanowires in various applications is highlighted in this paper.

2. Photocatalysts

Photocatalysis is a promising process for environmental protection because it is able to oxidize low concentrations of organic pollutants into benign products [20–26]. Photocatalysis utilizes semiconductor photocatalysts to carry out a photo-induced oxidation process to break down organic contaminants and inactivate bacteria and viruses [27–29]. Figure 2 illustrates the process of photocatalysis. When photons with energies greater than the band gap energy of the photocatalyst are absorbed, the valence band (VB) electrons are excited to the conduction band to facilitate a number of possible photoreactions. The photocatalytic surface with sufficient photo energy leads to the formation of a positive hole (h⁺) in the valence band and an electron (e⁻) in the conduction band (CB). The positive hole could either oxidize organic contaminants directly or produce very reactive hydroxyl radicals (OH^∙). The hydroxyl radicals (OH^∙) act as the primary oxidants in the photocatalytic system [30], which oxidize the organics. The electron in the conduction band reduces the oxygen that is adsorbed on the photocatalyst.

There are a number of semiconductors that could be used as photocatalysts, such as TiO₂, ZnO, and WO₃, Fe₂O₃. The band gap energy plays a significant role in the photocatalytic process. Figure 3 shows the band gap energies and the band edge positions of common semiconductor photocatalysts [31–33]. It is necessary to point out that the band gap values of ZnO, reported in the literature, are not all equivalent due to the different levels of the O vacancy in ZnO [34]. Although TiO₂ is the most widely investigated photocatalyst, ZnO has also been considered as a suitable alternative of TiO₂ because of its comparability with TiO₂ band gap energy and its relatively lower cost of production [18, 35, 36]. Moreover, ZnO has been reported to be more photoactive than TiO₂ [37–40] due to its higher efficiency of generation and separation of photoinduced electrons and holes [18, 41, 42].

Since the contaminant molecules need to be adsorbed on the photocatalytic surface before the reactions take place, the surface area plays a significant role in the photocatalytic activity. Although nanoparticles offer a large surface area, they have mostly been used in water suspensions, which limit their practical use due to difficulties in their separation and recovery. Moreover, additional equipment is needed for catalyst nanoparticle separation. Photocatalyst supported on a steady substrate can eliminate this issue. One-dimensional nanostructures, such as nanowires grown on a substrate, offer enhanced photocatalytic efficiency due to their extremely large surface-to-volume ratio as compared to a catalyst deposition on a flat surface [28, 44]. Table 1 compares different ZnO nanostructures for photocatalytic applications. There are many advantages in nanowire structures that could be used as photocatalysts.

3. Synthesis of ZnO Nanowires

ZnO nanowires can be either grown independently or grown on certain substrates. However, a vertical aligned growth on a substrate has more advantages in photocatalytic applications. The anisotropy of the ZnO crystal structure assists the growth of nanowires. The most common polar surface is the basal plane (0 0 1) with one end of the basal polar plane terminating in partially positive Zn lattice points and the other end terminating in partially negative oxygen lattice points. The anisotropic growth of the nanowires takes place along the c-axis in the 0 0 0 2 direction [45]. The growth velocities under hydrothermal conditions along the different directions are following the pattern [46]. The relative growth rate of these crystal faces will determine the final shape and aspect ratio of the ZnO nanostructures.

The synthesis methods of ZnO nanowires could mainly be classified as vapor phase and solution phase synthesis.

3.1. The Vapor Phase Synthesis

Vapor phase synthesis is probably the most extensively explored approach in the formation of 1D nanostructures [5]. A typical vapor phase synthesis method takes place in a closed chamber with a gaseous environment. Vapor species are first produced by evaporation, chemical reduction, and gaseous reaction. After that, the species are transferred and condensed onto the surface of a solid substrate. Generally, the vapor phase synthesis process is carried out at higher temperatures from 500°C to 1500°C and produces high-quality nanowires. The typical vapor phase synthesis method includes vapor liquid solid (VLS) growth [47], chemical vapor deposition (CVD) [48], metal organic chemical vapor deposition (MOCVD) [49], physical vapor deposition (PVD) [50], molecular beam epitaxy (MBE) [51], pulsed laser deposition (PLD) [52], and metal organic vapor phase epitaxy (MOVPE) [53]. Among the vapor phase synthesis methods, VLS and MOCVD are two of the most important methods for the ZnO nanowires synthesis.

Compared to other vapor phase techniques, VLS method is a simpler and cheaper process, and is advantageous for growing ZnO on large wafers [54]. The VLS process has been widely used for the growth of 1D nanowires and nanorods. A typical VLS process is used with nanosized liquid metal droplets as catalysts. The gaseous reactants interact with the nanosized liquid facilitating nucleation and growth of single crystalline rods and wires under the metal catalyst. Typical metal catalysts in the VLS process are Au, Cu, Ni, Sn, and so forth. ZnO nanowires have been successfully grown on sapphire, GaN, AlGaN, and ALN substrates through the VLS process [55]. The quality and growth behavior of the ZnO nanowires are strongly affected by the chamber pressure, oxygen partial pressure, and thickness of the catalyst layer [56, 57]. Chu et al. [58] synthesized well-aligned ZnO nanowires using VLS mechanism on Si substrate with chamber temperature varying from 600 to 950°C and pressure from 0.75 to 3 torr. They showed that ZnO nanowires with high aspect ratio grew vertically on the substrate at 700 to 750°C, the density of nanowires decreased when the temperature was higher than 800°C, and the growth rate and length of nanowires were decreased with increasing total chamber pressure.

Catalyst-free metal-organic chemical vapor deposition (MOCVD) is another important synthesis method for ZnO nanowires [49, 59]. The catalyst-free method eliminates the possible incorporation of catalytic impurities and produces high-purity ZnO nanowires. Moreover, the growth temperature of catalyst-free MOCVD is lower than a typical VLS growth temperature [60]. The ability to grow high-purity ZnO nanowires at low temperatures is expected to greatly increase the versatility and power of these building blocks for nanoscale photonic and electronic device applications [5]. Zeng et al. [61] reported that well-aligned ZnO nanowires were prepared by MOCVD on Si substrate without catalysts. In their grown process, high-purity diethyl zinc (99.999%) and N₂O (99.999%) were used as zinc and oxygen sources, respectively, and N₂ as the carrier gas. The base pressure of the reactor chamber and the working pressure were 10⁻⁵ and 50 torr, respectively. A thin nucleation layer of ZnO was grown at a low substrate temperature of 400°C at the beginning. After annealing the nucleation layer, ZnO nanowires were grown on the nucleation layer at the substrate temperature of 650°C.

Physical vapor deposition (PVD) technique has also been used to fabricate ZnO nanowires. The advantages of PVD technique are the following: (1) composition of products can be controlled, (2) there is no pollution such as drain water, discharge gas, and waste slag, and (3) simple process of making samples [62]. The process of PVD usually is direct thermal evaporation and oxidation of Zn powder at a high temperature and then deposition on the substrate to form the final product [50]. Zhang et al. [62] demonstrate the fabrication of ZnO nanowire arrays on Si substrates by PVD method at a relatively low temperature of about 500°C. In their synthesis process, high-purity Zn powder as source material was placed in a ceramic boat located at the center of a horizontal tube furnace. The Si substrates were placed on top of the boat to collect the products. The system was quickly heated to 500°C under 50 cm³/min N₂ flowing at a pressure of about 10⁻³torr for 1 h and then cooled to room temperature. The optical investigation showed that the ZnO nanowires were of high crystal quality and had attractive optical properties.

3.2. Solution Phase Synthesis

Solution phase synthesis has many advantages when compared to vapor phase synthesis, such as low cost, low temperature, scalability, and ease of handling. Generally, solution phase reactions occur at relatively low temperatures (<200°C) compared to vapor phase synthesis methods. Thus, solution synthesis methods allow for a greater choice of substrates including inorganic and organic substrates. Due to the many advantages, solution phase synthesis methods have attracted increasing interest. In solution phase synthesis, the growth process could be carried out in either an aqueous or organic solution or a mixture of the two [63, 64].

3.2.1. Hydrothermal Method

Generally, solution phase synthesis is carried out in an aqueous solution, and the process is then referred to as the hydrothermal growth method [65, 66]. Hydrothermal methods have received a lot of attention and have been widely used for synthesis of 1D nanomaterials. In addition, hydrothermally grown ZnO nanowires have more crystalline defects than others primarily due to oxygen vacancies [28]. Nanowires with inherent defects are capable of exhibiting visible light photocatalysis even without doping with transition metals [67]. The general process for vertically aligned ZnO nanowires grown on a substrate by the hydrothermal method is the following.(a)A thin layer of ZnO nanoparticles is seeded on a certain substrate. The seeding layer promotes nucleation for the growth of nanowires due to the lowering of the thermodynamic barrier [68].(b)An alkaline reagent (such as NaOH or hexamethylenetetramine) and Zn²⁺ salt (Zn(NO₃)₂, ZnCl₂, etc.) mixture aqueous solution is used as a precursor (or growth solution).(c)The ZnO seeded substrate is kept in the growth solution at a certain temperature and a certain period of time.(d)The resultant substrate and growth layer is washed and dried.

When hexamethylenetetramine ((CH₂)₆N₄, or HTMA) and Zn(NO₃)₂ are chosen as precursor, the chemical reactions can be summarized in the following equations [35].

Decomposition reaction:

Hydroxyl supply reaction:

Supersaturation reaction:

ZnO nanowire growth reaction:

One of the key parameters for the growth of ZnO nanowires is controlling the supersaturation of the reactants. It is believed that high supersaturation levels favor nucleation and low supersaturation levels favor crystal growth [3]. If a lot of OH⁻ is produced in a short period, the Zn²⁺ ions in the solution will precipitate out quickly due to the high pH environment, and, therefore, Zn²⁺ would contribute little to the ZnO nanowire growth and eventually result in the fast consumption of the nutrient and prohibit further growth of the ZnO nanowires [69]. Thus, the concentration of OH^- should be controlled in the solution to maintain low supersaturation levels during the whole nanowire growth process.

Effect of the ZnO Seeding Layer
Typical preseeding methods include thermal decomposition of zinc acetate, spin coating of ZnO nanoparticles, sputter deposition, and physical vapor deposition. In order to seed ZnO particles on the substrate, ZnO seeds must be annealed at certain temperature to improve ZnO particle adhesion to the substrate and nanowire vertical growth alignment. Greene et al. [70] studied the minimum temperature required to form textured seeds from zinc acetate on a silicon substrate from 100 to 350°C. The results suggest that temperatures between 150 and 200°C are needed for seed alignment, whereas higher temperatures promote seed crystallinity and growth. Baruah and Dutta [71] have reported that a very uniform thin layer of ZnO nanoparticles could be observed when ZnO seeds are annealed at a temperature of 350°C. However, when the annealing temperature was further increased to 450°C, ZnO crystallized into nanoparticles as well as nanorod-like structures. The authors hinted that ZnO seeds annealing at a temperature of about 350°C could give the best results for the ZnO nanowire growth.

The texture, thickness, and crystal size of ZnO seed layers also affect the quality of ZnO nanowire growth [72–75]. Ghayour et al. [72] reported the effect of seed layer thickness on alignment and morphology of ZnO nanorods. The results showed that the diameter increased, the density decreased, and the length of the nanorods slightly decreased when the thickness of the seed layer increased (Table 2). Wu et al. [73] studied the effects of seed layer characteristics on the synthesis of ZnO nanowires. The SEM images showed the density of nanowires decreased from 35 to 12 μm⁻² when the thickness increased from 106 to 191 nm and the diameter of the nanowires was found to increase with the seed layer (002) grain size. Ji et al. [75] found that the average diameter of nanowires is increased from 50 to 130 nm and the density is decreased from 110 to 60 μm⁻² when the seed layer thickness is changed from 20 to 1000 nm. Baruah and Dutta [71] reported that the nanorods grown on seeds crystallized from a zinc acetate solution have a higher aspect ratio (of the order of 3) than those grown using nanoparticle-seeded substrates.

Without a ZnO seeding layer, ZnO nanowires could be grown on an Au/substrate by introducing a suitable content of ammonium hydroxide into the precursor solution [76]. Au is used as an “intermediate layer” to assist the growth of ZnO nanowires [76].

Effect of an Alkaline Reagent
There are some alkaline reagents that have been used to supply OH^- during the reaction process such as NaOH, hexamethylenetetramine (HMTA), Na₂CO₃, ammonia, and ethylenediamine. When NaOH, KOH, or Na₂CO₃ is chosen, the synthesis process usually is carried out at elevated temperatures (>100°C) and pressures in a Teflon-sealed stainless autoclave [77–80]. When HMTA, ammonia, or ethylenediamine is chosen, the synthesis process can be carried out at lower temperatures (<100°C) and an atmospheric pressure. However, HMTA is the most often used due to its advantage in producing high-quality ZnO nanowires [81]. HMTA plays different significant roles during the synthesis process. First, HMTA supplies the OH⁻ ions to drive the precipitation reaction by thermal degradation [82]. Second, HMTA acts as a pH buffer by slowly releasing OH⁻ ions through thermal decomposition [81]. The hydrolysis rate of HMTA is decreased with an increase in pH and vice versa. Third, HMTA attaches to the nonpolar facets of the ZnO nanowires and prevents access of the Zn²⁺ ions to them thus leaving only the polar (001) face for epitaxial growth [68].

Effect of Precursor Concentration
To ascertain the relationship between the precursor concentration and the ZnO nanowire growth, Wang et al. [83] carried out a series of experiments by varying the precursor concentration and different ratios of [Zn(NO₃)₂]/[C₆H₁₂N₄]. The effect of the concentration of the precursor on the growth of ZnO nanorods is to increase the average diameter of ZnO nanorods almost linearly from 43 to 70 nm and the average length from 65 to 320 nm, as the precursor concentration increases from 0.008 to 0.04M (Figure 4). The corresponding aspect ratio of the ZnO nanorods increases from 1.8 to 5.8 and then slightly decreases to 4.6 (Figure 4 insert). Changes in the [Zn(NO₃)₂]/[C₆H₁₂N₄] ratio did not have a significant effect on the diameters of the ZnO nanorods (Figure 5). The aspect ratio of the ZnO nanorod arrays reached a maximum value of 7.25 when the [Zn(NO₃)₂]/[C₆H₁₂N₄] ratio was set to unity (Figure 5 insert). Xu et al. [69] studied the nanowire density by varying the precursor concentration with equal molar concentrations of the zinc salt and HMTA. The experimental results showed that the density of the nanowires is closely related with the precursor concentration. From 0.1 to 5 mM, the ZnO nanowire density was increased from 55/100 μm² to 108/100 μm². When the precursor concentration is further increased, the density of ZnO nanowires remains approximately steady with a slight decreasing tendency. The authors explained that the zinc chemical potential inside the body of the solution increases with zinc concentration. To balance the increased zinc chemical potential in the solution, more nucleation sites on the substrate surface will be generated, and, therefore, the density of the ZnO nanowires will increase. However, a continuous increase in the solution concentration may not increase the density of the nanowires when its density is larger than the saturation density. Kim et al. [84] reported that the density and diameter of ZnO nanorods are especially sensitive to the concentration of the reactants. Furthermore, the structural transition is shown by increasing the concentration. At the lowest concentration of Zn²⁺, the ZnO nanorods grow as single crystals with a low density and variable orientations. On the other hand, at the highest concentration, the nanorods grow as polycrystals due to the supersaturated Zn²⁺ source.

Effect of Growth Duration Time
Yuan et al. [85] synthesized ZnO nanowires by using equimolar (50 mM) zinc nitrate and HMTA at 93°C. The authors reported that the average diameter of ZnO nanowires is increased with growth duration time when the growth time is less than 2.5 h (Table 3). However, the average diameter is almost unchanged after that. The authors explained that the growth rate is slowed down after this period due to depletion of the precursor. Baruah and Dutta [71] carried out ZnO nanowire experiments on zinc-acetate-seeded substrates for different growth durations from 5 to 15 h. The SEM images showed that both length and diameter of the nanowires were increased with increasing growth duration time but the aspect ratio was reduced. Although nanowire growth slowed down after a certain period, the precursor supply for the ZnO nanowire growth can be replenished by repeatedly introducing fresh solution into the baths to keep up the growth rate [18, 86]. However, the diameter of the nanowires will also continue to increase and eventually connect together to form a ZnO film.

Effect of Initial Solution pH
Baruah and Dutta [45] studied the effect of pH variation on the dimension and morphology of ZnO nanorods grown by the hydrothermal synthesis method. ZnO nanorods were grown on preseeded glass substrates using the same concentration of zinc nitrate and HTMA as the precursors. The pH of the reaction bath was found to change gradually from 6.4 to 7.3 in 5 h during the growth process. When the growth process was initiated in basic condition (pH 8–12), flower petal like ZnO nanostructures were obtained. Akhavan et al. [88] studied the effect of pH change from 7.5 to 11.44 on the growth of ZnO nanorods by using zinc nitrate and NaOH as precursors. They reported that the diameters of the nanowires are increased with increased pH until they formed a ZnO film when the pH reached a value of 11.44. For a precursor pH value of 11.33, fast growth of ZnO nanorods was observed on the seed layer. The fast growth of ZnO nanorods resulted in a reduction of the optical band gap energy due to the creation of greater number of defects in the nanorods during this fast growth.

Effect of Growth Substrate
One major advantage of the hydrothermal synthesis method is that almost any substrate can be used for the growth of vertical ZnO nanowires by using ZnO seeding layer. In this way, ZnO nanowires can grow on flat surface regardless of the substrate (polymer, glass, semiconductor, metal, and more) by only controlling the growth conditions. ZnO nanowires can also be grown on organic substrates. ZnO nanowires have been successfully grown on polydimethylsiloxane (PDMS) [89], polystyrene (PS) [90], polyethylene terephthalate (PET) [91], polyethylene fibers [92], microfibers [93], polyurethane [94], polyimide [95], paper [96], and other organic substrates like lotus leaf [97].

Effect of Growth Temperature
Sugunan et al. [68] carried out growth of ZnO nanowires at different temperatures by using equimolar zinc nitrate and HMTA from 60 to 95°C. They reported that hydrothermal growth carried out with 1 mM solution of the precursors at 95°C produced similar nanowire lengths as those grown at 65°C in the same growth period. Thus, the authors suggested that there is no significant difference in the nanowire growth process for different chemical bath temperatures.

Effect of Additives
The aspect ratio of ZnO nanowires could be affected by the addition of additives. Zhou et al. [98] reported the effect of the addition of polyethyleneimine (PEI) on ZnO nanorods and showed that the average diameter of the nanorods was reduced drastically from 300 nm to 40 nm as the PEI amount increased from 0 to 12% (v/v) in solution. The authors explained that the PEI molecules were adsorbed on the lateral facets of the ZnO nanorods due to the electrostatic affinity. Thus, the lateral growth of the nanorods could be largely limited. Chen et al. [99] studied the influence of PEI and NH₃ on the growth of ZnO nanowires. The SEM image showed that the diameter and length of ZnO nanowires decreased with the addition of PEI. With the addition of NH₃, the diameter of the ZnO nanowires was reduced even further.

Other Factors
Other factors affecting ZnO growth include the heating source, the Zn²⁺ source, the external electric field, and mechanical stirring. The use of microwave heating instead of conventional heating has recently received great interest [28, 100, 101]. The hydrolyzed method creates defective crystallites under microwave irradiation and leads to a faster growth process as compared to the conventional process [28, 102]. Zinc salts include acetates, nitrates, perchlorates, and chlorides. The counter ion of zinc often affects the crystallite morphology by acting as promoter or inhibitor in the nucleation and growth processes [80]. An external electric field could also affect the growth rate and depends on the electric field direction and the applied voltage. Mechanical stirring could increase the growth rate.

3.2.2. Other Solution Phase Synthesis Methods

Other solution phase synthesis methods include the microemulsion and ethanol base methods. Lim et al. [103] reported the preparation of ZnO nanorods by the microemulsion synthesis. The surfactant, such as ethyl benzene acid sodium salt (EBS), dodecyl benzene sulfonic acid sodium salt (DBS), and zinc acetate dispersed in xylene by stirring until a homogenous mixture, was obtained. Then the hydrazine and ethanol mixture solution was added drop by drop to the well-stirred mixture at room temperature. The resulting precursor-containing mixture was subsequently heated to 140°C and refluxed for 5 h. The resultant ZnO nanorods had an average diameter of 80 nm. In the microemulsion synthesis, the process is referred to as hydrothermal when it is carried out in an aqueous solution [104]. Wu et al. [105] synthesized ZnO nanorods by using a solvothermal base in an ethanol solution. The synthesis process consisted of a NaOH ethanol solution added drop by drop in a Zn(NO₃)₂ ethanol solution and the mixture transferred into a Teflon-lined stainless autoclave and heated at 160°C for 12 h.

3.3. Doping of ZnO Nanowires

Doping is the primary method of controlling semiconductor properties such as the band gap, electrical conductivity, and ferromagnetism. Many metals and nonmetals have been successfully used to dope ZnO nanowires by various synthesis methods. ZnO nanowire metal doping includes Ni [41], Co [106], Ga [107], Eu [108], Al [109], and Cu [110], and nonmetal doping includes C [111], N [112], P [113], and Cl [114]. Two different element codoped nanowires such as Mn + Co [115], Mn + Li [116], and Li + N [117], have also been studied by some research groups.

Li et al. [118] have reported doping of ZnO nanowires with Mn, Cr, and Co by a hydrothermal method from aqueous solutions of zinc nitrate hydrate, TM (TM=Mn, Cr, Co) nitrate hydrate, and HTMA. The experiments were carried out in vials and heated in an oven at 90°C for 3 h. Marzouki et al. [119] studied nitrogen-doped ZnO nanowires by using the MOCVD method. The precursors chosen were dimethylzinc-triethylamine (DMZn-TEN) for zinc, nitrous oxide (N₂O) for oxygen, and diallylamine for the nitrogen source. The MOCVD reactor operated at atmospheric pressure and 850°C. Das et al. [117] synthesized Li and N co-doped ZnO nanowires on a Si substrate by using the hydrothermal method. The process was carried out in three steps First, a thin ZnO seed layer (10 nm) was predeposited on Si by a sputtering technique. Second, Li-doped nanowires were synthesized by using Zn(NO₃)₂, HTMA, and LiCl for precursor growth at 80°C for 8 h in an oven. Finally, the nanowires were treated by rapid thermal annealing at 500°C in NH₃ environment for 30 min. It has been reported that Indium doping of ZnO nanowires cannot be carried out by hydrothermal synthesis due to formation of the In(OH)₃ phase [120]. Nevertheless, it could be realized by a postdeposition thermal annealing in an inert atmosphere [120] or by a vapor phase transport process [121].

4. Characterization/Properties

Under general conditions, ZnO is single crystalline and exhibits a hexagonal wurtzite structure. The structure of ZnO nanowires could be revealed by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Figure 6 shows the XRD pattern of the ZnO nanowire growth on a silicon substrate by using the hydrothermal synthesis method. A dominant diffraction peak for (002) indicates a high degree of orientation with the c-axis vertical to the substrate surface. Figure 7 shows a top down image of ZnO nanowires [122]. Both XRD and SEM demonstrate the hexagonal wurtzite structure of the ZnO nanowires.

Further structural characterizations can be carried out by transmission electron microscopy (TEM) and high-resolution transmission electron microscopy (HRTEM). Figure 8(a) shows a low-resolution TEM image of ZnO nanowires with a homogeneous diameter size that does not vary significantly along the wire length. The HRTEM pattern measured for one individual nanowire is shown in Figure 8(b). The crystal lattice fringes spacing in the HRTEM image are 0.52 nm and fringes perpendicular to the wire axis is 0.26 nm. This measured plane spacing is characteristic of the (002) planes, showing the ZnO nanowire with a perfect lattice structure and verifing that the nanowires grow along the c-axis direction [124].

The ZnO nanowires obtained at different reaction times and examined by Raman spectra are presented in Figure 9. The peaks of the ZnO nanowires at 327, 378, 437, 537, and 1090 cm⁻¹ were observed in all the samples. A narrow strong band at 437 cm⁻¹ has been assigned to modes involving mainly a Zn motion corresponding to the band characteristic of the wurtzite phase. The band at 378 cm⁻¹ ( mode) indicates the presence of some degree of structural order-disorder in the ZnO lattice. The band bands at 327 cm⁻¹ should be assigned to the second-order Raman spectrum. A band at 537 cm⁻¹ is the contribution of the (LO) mode of ZnO associated with oxygen deficiency. The envelope of bands above 1090 cm^{− 1} can be attributed to overtones and/or combination bands [125].

Figure 10 shows the UV-Visible absorption spectra of ZnO nanoparticles, ZnO nanowires, and ZnO/Fe nanowires. ZnO nanowires showed a larger enhancement absorption in the visible range as compared to ZnO nanoparticles. The ZnO/Fe nanowires exhibit even stronger absorption than the ZnO nanowires and nanoparticles in both the UV and the visible range implying that ZnO/Fe nanowires could more fully utilize most of the UV and visible light than the other two.

Figure 11 shows the FTIR spectrum of ZnO nanorods in the range of 2000–300 cm⁻¹. There is only one significant spectroscopic band around 417 cm⁻¹ associated with the characteristic vibrational mode of Zn–O bonding [126].

The X-ray photoelectron spectroscopy (XPS) result Zn(2p) of the ZnO nanorods is shown in Figure 12. The peaks at 1021.4 and 1044.6 eV in the spectrum corresponding to the doublet of Zn (2p_3/2) and (2p_1/2), respectively, can be attributed to the formation of hexagonal ZnO nanorods [9].

Figure 13 shows the photopotential response of a ZnO nanowire electrode under UV irradiation. When the UV light is switched on, electron-hole pairs are generated and produce a photocurrent. The UV irradiation changes the current abruptly with some variation, and the photo-potential is sharply reduced when the light is switched off [35].

In addition to the above characterizations, ZnO nanowires also exhibit many other unique chemical and physical properties for many applications such as large surface areas, piezoelectric, piezotronic, and optical.

5. Applications

ZnO nanowires can be used for a number of applications in different fields due to the unique electrical, optical, and mechanical properties.

5.1. Sensor

5.1.1. Gas Sensor

ZnO is one of the earliest discovered and most widely used oxide gas sensing materials. ZnO functions as a gas sensitive material due to its electrical conductivity that can be dramatically affected by the adsorption or desorption of gas molecules on its surface [127]. 1D nanostructured devices such as nanowires are more sensitive and selective due to their high aspect ratio giving rise to a large surface area. There are many gasses that can be detected by ZnO nanowires, such as NO [128], NO₂ [129], CO [130], NH₃ [127], H₂ [131], O₂ [132], and ethanol [133]. A resistor type NO₂ gas sensor based on the ZnO nanorod was reported by Oh et al. [134] using a sonochemical route. The vertically aligned ZnO nanorods were grown on a Pt-electrode patterned alumina substrate under ambient conditions. The ZnO nanorod gas sensor was highly sensitive to the NO₂ gas with a very low detection limit of 10 ppb at 250°C and short response and recovery time (Figure 14). Wei et al. [135] reported a room temperature NH₃ gas sensor based on a ZnO nanorod array produced by hydrothermal decomposition on an Au electrode. Recently, Oh and Jeong [136] fabricated CO sensors based on aligned ZnO nanorods on a substrate and exhibited high sensitivity to CO gas with the low detection limit of 1 ppm at 350°C.

5.1.2. Biosensor

Recently, ZnO nanostructures have attracted interest in biosensor applications due to many advantages, including nontoxicity, biosafety, bio-compatibility, high electron-transfer rates, and combination with immobilized enzymes [137]. The high isoelectric point (IEP) of ZnO (IEP 9.5) makes it a good matrix for immobilizing low IEP acidic proteins or DNA by electrostatic interactions with high binding stability [138]. In addition, ZnO has high ionic bonding (60%), and it dissolves very slowly at normal biological pH environments. Liu et al. [139] have constructed an ampere-metric glucose biosensor based on aligned ZnO nanorod films formed directly on the surface of ITO glass. The biosensor exhibited a linear response to glucose from 5 μM to 300 μM and a limit of detection of 3 μM (Figure 15(a)). The biosensor also showed good selectivity for glucose. In an air-saturated and stirred 0.01 M PBS containing 5 μM glucose, there was no significant change of the ampere-metric response by the injection of 10 μM UA and AA, respectively (Figure 15(b)). Ibupoto et al. [140] have demonstrated the fabrication of a ZnO-nanorod-based biosensor with good reproducibility and selectivity for the quick monitoring of penicillin with the immobilization of the penicillinase enzyme by the simple physical adsorption method. The authors showed that the potentiometric response of the sensor configuration revealed good linearity over a large concentration range from 100 μM to 100 mM. Choi et al. [141] described a ZnO nanowire field-effect-transistor- (FET-) based biosensor for the detection of low level biomolecular interactions. The ZnO nanowire biosensor could detect as low as 2.5 nM of the streptavidin with a current increase of 7.5 nA.

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5.2. UV Detector

UV detection is another promising optical application of ZnO nanowires [142–144]. The UV detector utilizes the electric potential of the ZnO nanowires changed under UV irradiation. Chen et al. [143] constructed a UV photodetector by contacting a circular spiral structure ZnO nanowire with 30 nm IrO₂ electrodes. The I-V measurement showed that the curve corresponded to the Schottky metal-semiconductor contacts with the photo-generated current reaching 5.11 × 10⁻⁷A, under a bias voltage of 5 V, and the photocurrent being 2 orders of magnitude larger than the dark current (Figure 16). Li et al. [145] proposed a method of fabricating a ZnO bridging nanowire structure exhibiting nanowatt UV detection. The electrodes were formed by the thick ZnO layers covering the Au-catalyst-patterned areas on the substrate, and the sensing elements consisted of the ultralong ZnO nanowires bridging the electrodes. The device exhibited drastic changes (10–10⁵ times) in current under a wide range of UV irradiance (10⁻⁸–10⁻² W cm⁻²). Moreover, the detector showed fast response (rise and decay times of the order of 1 s) to UV illumination in air. Yang et al. [146] synthesized a simple self-assembled lateral growth ZnO nanowire photodetector with the photocurrent of the ZnO nanowires under UV illumination being twice as larger as the dark current with a bias voltage of 5 V. Lin et al. [147] reported that loading of Ag particles in ZnO nanowires produces an enhanced photoresponse. Chang et al. [148] combined the ZnO nanorods with graphene enabling the UV sensor to reach 22.7 A/W.

5.3. UV Laser

Room temperature of ZnO-nanowire-based UV lasing has been recently demonstrated [149]. Figure 17 shows a typical room temperature photoluminescence (PL) spectrum of ZnO nanorods with an excitation wavelength of 325 nm at room temperature [150]. The spectrum exhibits two bands including a strong ultraviolet emission at 378 nm (or 3.28 eV) and a weak spectral band in the visible region. The UV emission was contributed to the near band edge emission of the wide band gap of ZnO. Visible emission is due to the presence of various point defects such as oxygen vacancies.

5.4. Light-Emitting Diode

The output power of GaN LEDs with ZnO nanotip arrays can be enhanced by up to 50% times [151]. A heterojunction LED could be fabricated by the growth of vertically aligned ZnO nanowires on a p-GaN substrate and employed indium tin oxide (ITO)/glass to combine and package [152, 153]. Figure 18 shows the electroluminescence (EL) spectra of ZnO NWs/p-GaN/ZnO nanowire heterostructure at a DC current of 20 mA. A UV-blue electroluminescence (EL) emission was observed from the nanowire-film heterojunction diodes. Most of the currently developed ZnO LEDs are based on heterojunctions. However, a ZnO rod p-n homojunction LED with an ion-implanted P-doped p-type ZnO could also be fabricated [154].

5.5. Dye-Sensitized Solar Cells

Dye-sensitized solar cells (DSSCs), which are based on oxide semiconductors and organic dyes or metal organic complex dyes, are one of the most promising candidate systems to achieve efficient solar-energy because they are flexible, inexpensive, and easier to manufacture than silicon solar cells [155]. ZnO-based DSSC technology alternative to TiO₂ is considered as one of the most promising materials for solar cells due to a faster electron transport with reduced recombination loss and its ease of crystallization and anisotropic growth. Ko et al. [87] compared different fabricated ZnO nanowire DSSCs that included lengthwise growth (LG) and branched growth (BG). They showed that the overall light-conversion efficiency of the branched ZnO nanowire DSSCs was much higher than the upstanding ZnO nanowires (Figure 19 and Table 4). The reason for the improvement is the enhanced surface area for higher dye loading and light harvesting and the reduction of charge recombination by providing direct conduction pathways along the crystalline ZnO “nanotree” multigeneration branches.

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Lupan et al. [124] studied the well-aligned arrays of vertically oriented ZnO nanowires electrodeposited on ITO-coated glass for dye-sensitized solar cells. The maximum overall photovoltaic conversion efficiency was 0.66% at 100 mW/cm². Cheng et al. [156] fabricated branched ZnO nanowires on conductive glass substrates via a solvothermal method for dye-sensitized solar cells. The short-circuit current density and the energy conversion efficiency of the branched ZnO nanowire DSSCs are 4.27 mA/cm² and 1.51%, which are higher than those pf the bare ZnO nanowire. Sudhagar et al. [13] reported jacks-like ZnO nanorod architecture as a photoanode in dye-sensitized solar cells and the result exhibited a higher conversion efficiency of ( V, mA cm⁻²) than that of the branch-free ZnO nanorods electrodes (, V, mA cm⁻²).

5.6. NanoGenerator

Due to the noncentrosymmetric symmetry of the wurtzite structure, ZnO exhibits a strong piezoelectric behavior. Recently, nanogenerators (NGs) have been developed by utilizing the piezoelectric effect of ZnO nanowires for scavenging tiny and irregular mechanical energy such as air flow vibrations and body movements [159–162]. Zhu et al. [157] reported a flexible high output nanogenerator (HONG), based on a lateral ZnO nanowire array for harvesting mechanical energy, for driving a small commercial electronic component. The electrical output of a single layer of the HONG structure reached a peak voltage of 2.03 V and a current of 107 nA with a peak power density of 11 mW/cm³ (Figure 20). The energy generation efficiency was 4.6%. The generated electric energy was successfully used to light up a commercial light-emitting diode (LED). The authors also predicted that the peak output power density of 0.44 mW/cm² and a volume density of 1.1 W/cm³ could be realized by optimizing the density of the nanowires on the substrate and using multilayer integration.

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Figure 20

Working principle and output measurement of the HONG. (a) Schematic diagram of the HONG structure without mechanical deformation, in which gold is used to form Schottky contacts with the ZnO nanowire arrays. (b) Demonstration of the output scaling-up when mechanical deformation is induced, where the “±” signs indicate the polarity of the local piezoelectric potential created in the nanowires. (c) Open circuit voltage measurement of the HONG. (d) Short circuit current measurement of the HONG. The measurement is performed at a strain of 0.1% and strain rate of 5% s⁻¹ with a deformation frequency of 0.33 Hz. The insets are the enlarged view of the boxed area for one cycle of deformation (reproduced with permission from [157] © 2010 American Chemical Society).

Hu et al. [163] integrated a nanogenerator onto a tire inner surface and scavenged mechanical energy from the deformation of the tire during its motion. The nanogenerator directly powers a liquid crystal display (LCD) screen. Xu and Wang [164] designed a compact hybrid cell based on the combination of a piezoelectric nanogenerator and a DSSC in one compact structure. The compact hybrid cell showed a significant increase in output power. Cha et al. [165] fabricated a sound-driven piezoelectric ZnO nanowire-based nanogenerator and obtained an AC output voltage of about 50 mV.

5.7. Field Emission Devices

ZnO nanowires are considered as candidates of field emitters due to their high melting point and high stability under an oxygen environment as compared to CNTs [166, 167]. Hwang et al. [166] reported vertical ZnO nanowires grown on grapheme/PDMS substrates for transparent and flexible field emission. The ZnO nanowires/graphene hybrids showed excellent field emission properties with the low turn-on field values of 2.0 V μm⁻¹, 2.4 V μm⁻¹, and 2.8 V μm⁻¹ measured for convex, flat, and concave deformations, respectively. Kang et al. [168] presented ZnO nanowire patterned growth for the field emission device. The optimum patterned ZnO nanowire field emission device fabricated with the current approach was found to exhibit a low turn-on electric field value (1.60 μm V⁻¹) due to the decrease in the field emission screening effect that results from the radial structures of the micropatterned ZnO nanowires arrays. Chen et al. [169] synthesized ZnO nanowires on a ZnO:Ga/glass substrate. UV illumination increased the ZnO nanowire field emission and reduced the turn-on electric field from 5.1 to 2.1 V/μm at a current density of l μA/cm². Doping by certain metals for enhancement of the field emission device performance has also been reported such as Sn [170] and Ga [171].

5.8. Field Effect Transistor

A typical nanowires field effect transistor (FET) consists of a semiconductor nanowire (ZnO, etc.) connected with two electrodes at two ends and placed on a flat substrate that serves as a gate electrode. The current flow from the drain to the source along the nanowire is controlled by the applied gate voltage or the chemical/biochemical species adsorbed on the surface of the nanowires. Recently, piezoelectric-FET (PE-FET) has been demonstrated by coupling the semiconductive and piezoelectric properties of ZnO, which is defined as the piezotronics effect [172–174]. The working principle of PE-FET relies on the piezoelectric potential of the nanowire under straining and serves as the gate voltage for controlling the current flow from the drain to source [175].

5.9. Photocatalysis

ZnO nanowires used as photocatalysts have been recently reported by many research groups [158, 176–178]. Sugunan et al. [158] described a continuous flow water purification system by the fabrication of ZnO nanowires grown on flexible poly-L-lactide nanofibers. The continuous flow photocatalytic decomposition of organic compounds in water has no need for separation of the photochemically active material from the reservoir, and the purified water can be directly collected from the reservoir (Figure 21). The various organic pollutants that have been tested and removed under UV light illumination include methylene blue, monocrotophos, and diphenylamine. The results demonstrated that simultaneous photocatalytic decomposition of more than one organic contaminant is possible by using the polymer-ZnO nanostructure. The authors also stated that the fabrication can be easily scaled up and the whole photocatalytic water treatment setup can easily be adapted either as a point-of-use system or centralized large-scale water purification system. Baruah et al. [92] reported the growth of ZnO nanowires on woven polyethylene fibers for photocatalytic applications. Photocatalytic activity testing was carried out in UV light and degraded 0.01 mM of methylene blue. The results revealed that ZnO nanowires grown on polyethylene fibers accelerate the photocatalytic degradation process by a factor of 3 as compared to just polyethylene fibers. Kuo et al. [179] synthesized ultralong ZnO nanowires on silicon substrates by the vapor transport process and used them as recyclable photocatalysts for the degradation of rhodamine B and 4-chlorophenol. The results showed only a slight decrease in the photodecomposition rate after 10 cycles. SEM images indicated that the nanowire appearance and density did not show noticeable change after 10 experiment cycles. Baruah et al. [96] synthesized ZnO nanorods on a paper substrate as photocatalytic paper. The photocatalytic activity was carried out by the degradation of methylene blue and methyl orange under 963 W/m² visible light and inactivity of Escherichia coli under 11 W/m² visible light. The results showed that the photocatalytic paper could degrade organic dye and also inhibit the growth of Escherichia coli under room light conditions (11 W/m²). Sapkota et al. [18] investigated the inactivation of microbes in water by the visible light photocatalysis of ZnO nanorods. ZnO nanorods were grown on a glass substrate by the hydrothermal route and employed in the inactivation of Escherichia coli and Bacillus subtilis in water. The cell membrane damage and DNA degradation were observed under the visible light photocatalytic process. Wang et al. [19] also studied the photocatalytic degradation of Escherichia coli membrane cell in the presence of ZnO nanowires. The SEM images showed that the outer membrane of Escherichia coli was destroyed completely in the presence of ZnO nanowires under UV irradiation and the cells became twisted shapes without a mechanically strong network.

Surface properties such as surface defects and oxygen vacancies of photocatalysts play a significant role in the photocatalytic activity. ZnO nanowire crystalline defects exist primarily due to oxygen vacancies [28]. Nanoparticles with crystalline defects are capable of exhibiting visible light photocatalysis even without doping with transition metals [67]. Baruah et al. [28] reported a fast crystallization ZnO nanorods synthesis method to increase the surface defect of the ZnO nanowires. Compared to the conventional hydrothermal synthesis method, an increase in the density of vacancies and surface defects in the nanorod crystals were obtained through accelerated crystallization using microwave hydrothermal and subsequent fast quenching reactions. The authors also compared the photocatalytic activity of conventional and microwave-grown nanorods in the degradation of methylene blue. The photocatalysis was carried out under 72 klx of visible light. The microwave hydrolyzed nanorods showed better photocatalytic activity as compared to the conventional synthesized nanorods. The authors also stated that ZnO nanorods grown through fast crystallization under microwave irradiation not only created defective crystallites for better photocatalysis but also saved time and energy during the growth process due to faster synthesis. Zhang and Zhu [101] reported that ZnO nanostructures have enhanced photocatalytic activity by using the microwave-assisted solvothermal synthesis method. Zhu et al. [180] studied the microwave-assisted hydrothermal synthesis of ZnO nanorod-assembled microspheres for photocatalysis and demonstrated that the as-prepared ZnO had excellent optical properties and higher photocatalytic activity due to surface defects.

To further increase the photoactivity of ZnO nanowires, our group has synthesized ZnO/Fe nanowires by the growth of ZnO nanowires on the Fe-doped ZnO seeding layer using the hydrothermal method. The photocatalytic activity was evaluated by photodegradation of dichlorobenzene (DCB) and methyl orange (MO) in water. The experiments were carried out under white light (60 W/m² in visible plus 2 W/m² in UV) or UV light (30 W/m²) irradiation. The results showed that the ZnO/Fe nanowires exhibited enhanced photocatalytic activity as compared with pure ZnO nanowires under different light irradiation as well as different contaminants. For the decontamination of DCB (Figures 22(a) and 22(b)), ZnO/Fe nanowires exhibited greater photoactivity than pure ZnO nanowires under white light as well as UV light irradiation. When compared to TiO₂ (P25), ZnO/Fe nanowires show better photoactivity than P25 under white light irradiation. For the decontamination of MO (Figures 22(c) and 22(d)), ZnO/Fe nanowires also exhibit an enhanced photocatalytic activity as compared with pure ZnO nanowires under white light as well as UV light irradiation. The results demonstrate that ZnO/Fe nanowires could be a better photocatalyst in sunlight.

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Doping transition metal ions is a strategy for improving the visible light photocatalytic activity, by lowering the band gap, resulting from the creation of dopant energy levels below the conduction band [181]. Wu et al. [182] synthesized 3% Cr-doped ZnO nanowires and showed that Cr-doped ZnO nanowires have better photoactivity for decoloration of methyl orange as compared to pure ZnO and P25 under visible light irradiation. Lu et al. [183] reported cobalt-doped ZnO nanorods as photocatalyst, and revealed that the Co-doped ZnO samples have an extended light absorption range and increased photocatalytic activity of alizarin red dye decomposition under visible light irradiation as compared with pure ZnO nanorods. Jia et al. [184] studied the photocatalytic activity of La-doped ZnO nanowires. The results showed an increase in the photocatalytic activity of La-doped ZnO nanowires in the degradation of Rhodamine B (RhB) with the optimal doping content being about 2% in terms of photocatalytic activity efficiency. Wu et al. [185] reported that the photocatalytic activity of 3% Sb-doped ZnO nanowires is superior to that of undoped ZnO nanowires under both UV and visible-light testing. Mahmood et al. [186] reported enhanced visible light photocatalysis by manganese doping or rapid crystallization with ZnO nanoparticles. Li et al. [187] investigated the structural, electronic, and optical properties of Ag-doped ZnO nanowires using first-principles calculations based on DFT. The results provide theoretical evidence that Ag-doped ZnO nanowires could also have potential applications in photocatalysis due to the increase in visible-photocatalytic activity. Other dopings of ZnO nanowires, such as Sn [105] and Na [188], have also been reported and have shown an enhancement of photocatalytic activity for the degradation of organic compounds in water. In addition to doping, Jung and Yong [189] reported the fabrication of CuO–ZnO nanowires on a stainless steel mesh for highly efficient photocatalytic applications.

6. Conclusions

This paper provides an overview of the synthesis, characterization, and applications of ZnO nanowires. The hydrothermal synthesis method is simple and efficient and it has received increased attention. A mixture of zinc nitrate and hexamine as precursor is the most popular. Due to the unique properties of the material, ZnO nanowires are attractive for a number of potential applications such as photocatalysis, solar cells, sensors, and generators. Among the applications of ZnO nanowires, photocatalysis is being increasingly used for environmental protection. Further research is needed to improve the quality of ZnO nanowires and large-scale produce ZnO nanowires for practical industrial applications. Based on this paper, ZnO nanowires promise to be one of the most important materials in photocatalytic as well as others applications.

Acknowledgment

The research leading to this paper was funded by the State of Florida through the Florida Energy Systems Consortium (FESC) funds.

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Copyright © 2012 Yangyang Zhang et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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