Star Poly(N-isopropylacrylamide) Tethered to Polyhedral Oligomeric Silsesquioxane (POSS) Nanoparticles by a Combination of ATRP and Click Chemistry

Table 1

Molecular characterization of the alkyne-PNIPAm homopolymer during ATRP.

	Monomer ∶ initiator	𝑀𝑤^a	𝑀𝑛^a	PDI^a	𝑇𝑔^b
PNIPAM1	200 : 1	11700	10100	1.15	140
PNIPAM2	100 : 1	7300	6300	1.16	141
PNIPAM3	80 : 1	5700	5100	1.12	140
PNIPAM4	50 : 1	3600	3100	1.14	112

^aPolydispersity index and molecular weight, measured by GPC. ^bObtained from DSC by 20°C/min.