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Journal of Nanomaterials
Volume 2013 (2013), Article ID 341015, 23 pages
http://dx.doi.org/10.1155/2013/341015
Review Article

Function of Nanocatalyst in Chemistry of Organic Compounds Revolution: An Overview

1Organic Chemistry Division, School of Advanced Sciences, VIT University, Vellore, Tamil Nadu 632 014, India
2Department of Materials Science and Engineering, North Carolina State University, Engineering Building I, Raleigh, NC 27695-7907, USA
3Chemistry Research Laboratory, Organic Chemistry Division, School of Advanced Sciences, VIT University, Vellore, Tamil Nadu 632 014, India

Received 2 April 2013; Accepted 21 April 2013

Academic Editor: Minghang Li

Copyright © 2013 Kanagarajan Hemalatha et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. S. M. Roopan and F. R. N. Khan, “ZnO nanoparticles in the synthesis of AB ring core of camptothecin,” Chemical Papers, vol. 64, no. 6, pp. 812–817, 2010. View at Publisher · View at Google Scholar · View at Scopus
  2. G. Madhumitha and S. M. Roopan, “Devastated crops: multifunctional efficacy for the production of nanoparticles,” Journal of Nanomaterials, vol. 2013, pp. 1–12, 2013.
  3. L. Sang-Bum, P. Young In, D. Mi-Sook, and G. Young-Dae, “Identification of 2,3,6-trisubstituted quinoxaline derivatives as a Wnt2/β-catenin pathway inhibitor in non-small-cell lung cancer cell lines,” Bioorganic & Medicinal Chemistry Letters, vol. 20, pp. 5900–5904, 2010.
  4. N. M. Sabry, H. M. Mohamed, E. S. A. E. H. Khattab, S. S. Motlaq, and A. M. El-Agrody, “Synthesis of 4H-chromene, coumarin, 12H-chromeno[2,3-d]pyrimidine derivatives and some of their antimicrobial and cytotoxicity activities,” European Journal of Medicinal Chemistry, vol. 46, no. 2, pp. 765–772, 2011. View at Publisher · View at Google Scholar · View at Scopus
  5. R. Raj, P. Singh, P. Singh, J. Gut, P. J. Rosenthal, and V. Kumar, “Azide-alkyne cycloaddition en route to 1H-1,2,3-triazole-tethered 7-chloroquinoline-isatin chimeras: synthesis and antimalarial evaluation,” European Journal of Medicinal Chemistry, vol. 62, pp. 590–596, 2013.
  6. M. M. Sitônio, C. H. Carvalho Jr., I. A. Campos, et al., “Anti-inflammatory and anti-arthritic activities of 3, 4-dihydro-2, 2-dimethyl-2 H-naphthol[1,2-b]pyran-5, 6-dione (β-lapachone),” Inflammation Research, vol. 62, pp. 107–113, 2013.
  7. R. Ghorbani-Vaghei and S. M. Malaekehpoor, “N- Bromosuccinimide as an efficient catalyst for the synthesis of indolo [2,3-b ]quinolines,” Tetrahedron Letters, vol. 53, pp. 4751–4753, 2012.
  8. K. Rad-Moghadam and S. C. Azimi, “Mg(BF4)2 doped in [BMIm][BF4]: a homogeneous ionic liquid-catalyst for efficient synthesis of 1, 8-dioxo-octahydroxanthenes, decahydroacridines and 14-aryl-14 H-dibenzo[a, j]xanthenes,” Journal of Molecular Catalysis A, vol. 363-364, pp. 465–469, 2012.
  9. T. S. Jin, J. C. Xiao, S. J. Wang, and T. S. Li, “Ultrasound-assisted synthesis of 2-amino-2-chromenes with cetyltrimethylammonium bromide in aqueous media,” Ultrasonics Sonochemistry, vol. 11, no. 6, pp. 393–397, 2004. View at Publisher · View at Google Scholar · View at Scopus
  10. C. L. Ni, X. H. Song, H. Yan, X. Q. Song, and R. G. Zhong, “Improved synthesis of diethyl 2,6-dimethyl-4-aryl-4H-pyran-3,5-dicarboxylate under ultrasound irradiation,” Ultrasonics Sonochemistry, vol. 17, no. 2, pp. 367–369, 2010. View at Publisher · View at Google Scholar · View at Scopus
  11. G. Chen, H. Jia, L. Zhang, B. Chen, and J. Li, “An efficient synthesis of 2-substituted benzothiazoles in the presence of FeCl3/Montmorillonite K-10 under ultrasound irradiation,” Ultrasonics Sonochemistry, vol. 20, pp. 627–632, 2013.
  12. A. Lak, M. Mazloumi, M. S. Mohajerani et al., “Rapid formation of mono-dispersed hydroxyapatite nanorods with narrow-size distribution via Microwave Irradiation,” Journal of the American Ceramic Society, vol. 91, no. 11, pp. 3580–3584, 2008.
  13. M. S. Mohajerani, M. Mazloumi, A. Lak, A. Kajbafvala, S. Zanganeh, and S. K. Sadrnezhaad, “Self-assembled zinc oxide nanostructures via a rapid microwave-assisted route,” Journal of Crystal Growth, vol. 310, no. 15, pp. 3621–3625, 2008.
  14. R. Narayanan, “Synthesis of green nanocatalysts and industrially important green reactions,” Green Chemistry Letters and Reviews, vol. 5, pp. 707–725, 2012.
  15. R. M. Mohamed, D. L. McKinney, and W. M. Sigmund, “Enhanced nanocatalysts,” Materials Science and Engineering R, vol. 73, pp. 1–13, 2012.
  16. M. Mazloumi, N. Shahcheraghi, A. Kajbafvala et al., “3D bundles of self-assembled lanthanum hydroxide nanorods via a rapid microwave-assisted route,” Journal of Alloys and Compounds, vol. 473, no. 1-2, pp. 283–287, 2009.
  17. A. Kajbafvala, H. Ghorbani, A. Paravar, J. P. Samberg, E. Kajbafvala, and S. K. Sadrnezhaad, “Effects of morphology on photocatalytic performance of zinc oxide nanostructures synthesized by rapid microwave irradiation methods,” Superlattices and Microstructures, vol. 51, pp. 512–522, 2012.
  18. M. R. Bayati, R. Molaei, A. Kajbafvala, S. Zanganeh, H. R. Zargar, and K. Janghorban, “Investigation on hydrophilicity of micro-arc oxidized TiO2 nano/micro-porous layers,” Electrochimica Acta, vol. 55, no. 20, pp. 5786–5792, 2010. View at Publisher · View at Google Scholar · View at Scopus
  19. A. Kajbafvala, J. P. Samberg, H. Ghorbani, E. Kajbafvala, and S. K. Sadrnezhaad, “Effects of initial precursor and microwave irradiation on step-by-step synthesis of zinc oxide nano architectures,” Materials Letters, vol. 67, pp. 342–345, 2012.
  20. M. Mazloumi, S. Zanganeh, A. Kajbafvala et al., “Ultrasonic induced photoluminescence decay in sonochemically obtained cauliflower-like ZnO nanostructures with surface 1D nanoarrays,” Ultrasonics Sonochemistry, vol. 16, no. 1, pp. 11–14, 2009. View at Publisher · View at Google Scholar · View at Scopus
  21. S. Zanganeh, A. Kajbafvala, N. Zanganeh et al., “Hydrothermal synthesis and characterization of TiO2 nanostructures using LiOH as a solvent,” Advanced Powder Technology, vol. 22, no. 3, pp. 336–339, 2011. View at Publisher · View at Google Scholar · View at Scopus
  22. A. Kajbafvala, S. Zanganeh, E. Kajbafvala, H. R. Zargar, M. R. Bayati, and S. K. Sadrnezhaad, “Microwave-assisted synthesis of narcis-like zinc oxide nanostructures,” Journal of Alloys and Compounds, vol. 497, no. 1-2, pp. 325–329, 2010. View at Publisher · View at Google Scholar · View at Scopus
  23. A. Kajbafvala, M. R. Shayegh, M. Mazloumi et al., “Nanostructure sword-like ZnO wires: rapid synthesis and characterization through a microwave-assisted route,” Journal of Alloys and Compounds, vol. 469, no. 1-2, pp. 293–297, 2009. View at Publisher · View at Google Scholar · View at Scopus
  24. A. Lak, M. Mazloumi, M. Mohajerani et al., “Self-assembly of dandelion-like hydroxyapatite nanostructures via hydrothermal method,” Journal of the American Ceramic Society, vol. 91, no. 10, pp. 3292–3297, 2008. View at Publisher · View at Google Scholar · View at Scopus
  25. S. Zanganeh, A. Kajbafvala, N. Zanganeh et al., “Self-assembly of boehmite nanopetals to form 3D high surface area nanoarchitectures,” Applied Physics A, vol. 99, no. 1, pp. 317–321, 2010. View at Publisher · View at Google Scholar · View at Scopus
  26. M. Mazloumi, M. Attarchi, A. Lak et al., “Boehmite nanopetals self assembled to form rosette-like nanostructures,” Materials Letters, vol. 62, no. 26, pp. 4184–4186, 2008. View at Publisher · View at Google Scholar · View at Scopus
  27. S. Zanganeh, M. Torabi, A. Kajbafvala et al., “CVD fabrication of carbon nanotubes on electrodeposited flower-like Fe nanostructures,” Journal of Alloys and Compounds, vol. 507, no. 2, pp. 494–497, 2010. View at Publisher · View at Google Scholar · View at Scopus
  28. Y. Estevez, M. Quiliano, A. Burguete et al., “Trypanocidal properties, structure-activity relationship and computational studies of quinoxaline 1,4-di-N-oxide derivatives,” Experimental Parasitology, vol. 127, pp. 745–751, 2011.
  29. E. Vicente, P. R. Duchowicz, E. A. Castro, and A. Monge, “QSAR analysis for quinoxaline-2-carboxylate 1,4-di-N-oxides as anti-mycobacterial agents,” Journal of Molecular Graphics and Modelling, vol. 28, no. 1, pp. 28–36, 2009. View at Publisher · View at Google Scholar · View at Scopus
  30. H. Yoo, Y. Lee, M. E. Suh, D. J. Kim, and S. W. Park, “Cytotoxic effects of quinoxaline derivatives on human cancer cell lines,” Archiv Der Pharmazie, vol. 331, pp. 331–333, 1998.
  31. M. J. Climent, A. Corma, J. C. Hernández, A. B. Hungría, S. Iborra, and S. Martínez-Silvestre, “Biomass into chemicals: one-pot two- and three-step synthesis of quinoxalines from biomass-derived glycols and 1,2-dinitrobenzene derivatives using supported gold nanoparticles as catalysts,” Journal of Catalysis, vol. 292, pp. 118–129, 2012.
  32. A. Hasaninejad, M. Shekouhy, and A. Zare, “Silica nanoparticles efficiently catalyzed synthesis of quinolines and quinoxalines,” Catalysis Science & Technology, vol. 2, pp. 201–214, 2012.
  33. B. B. F. Mirjalili, A. Bamoniri, and A. Akbari, “Nano-BF3·SiO2: a reusable and eco-friendly catalyst for synthesis of quinoxalines,” Chemistry of Heterocyclic Compounds, vol. 47, pp. 487–491, 2011.
  34. B. B. F. Mirjalili and A. Akbari, “Nano-TiO2: an eco-friendly alternative for the synthesis of quinoxalines,” Chinese Chemical Letters, vol. 22, no. 6, pp. 753–756, 2011. View at Publisher · View at Google Scholar · View at Scopus
  35. H. Y. Lü, S. H. Yang, J. Deng, and Z. H. Zhang, “Magnetic Fe3O4 nanoparticles as new, efficient, and reusable catalysts for the synthesis of quinoxalines in water,” Australian Journal of Chemistry, vol. 63, no. 8, pp. 1290–1296, 2010. View at Publisher · View at Google Scholar · View at Scopus
  36. A. A. Yelwande, M. E. Navgire, B. R. Arbad, and M. K. Lande, “Polyaniline/SiO2 nanocomposite catalyzed efficient synthesis of quinoxaline derivatives at room temperature,” Journal of the Chinese Chemical Society, vol. 59, pp. 1–6, 2012.
  37. H. Alinezhad, M. Tajbakhsh, F. Salehian, and P. Biparva, “Synthesis of quinoxaline derivatives using TiO2 nanoparticles as an efficient and recyclable catalyst,” Bulletin of the Korean Chemical Society, vol. 32, pp. 3720–3725, 2011.
  38. A. Kumar, S. kumar, A. Saxena, A. De, and S. Mozumdar, “Ni-nanoparticles: an efficient catalyst for the synthesis of quinoxalines,” Catalysis Communications, vol. 9, no. 5, pp. 778–784, 2008. View at Publisher · View at Google Scholar · View at Scopus
  39. G. R. Bardajee, R. Malakooti, I. Abtin, and H. Atashin, “Palladium Schiff-base complex loaded SBA-15 as a novel nanocatalyst for the synthesis of 2,3-disubstituted quinoxalines and pyridopyrazine derivatives,” Microporous and Mesoporous Materials, vol. 169, pp. 67–74, 2013.
  40. B. L. Finkelstein and C. J. Strock, “Synthesis and insecticidal activity of novel pyrazole methanesulfonates,” Pesticide Science, vol. 50, no. 4, pp. 324–328, 1997. View at Scopus
  41. C. M. R. De Sant'anna, R. B. De Alencastro, C. R. Rodrigues et al., “A semiempirical study of pyrazole acylhydrazones as potential antimalarial agents,” International Journal of Quantum Chemistry, vol. 60, no. 8, pp. 1835–1843, 1996. View at Scopus
  42. A. A. Farghaly, A. A. Bekhit, and J. Y. Park, “Design and synthesis of some oxadiazolyl, thiadiazolyl, thiazolidinyl, and thiazolyl derivatives of 1H-pyrazole as anti-inflammatory antimicrobial agents,” Archiv der Pharmazie, vol. 333, no. 2-3, pp. 53–57, 2000. View at Scopus
  43. F. N. Khan, J. S. Jin, T. Maiyalagan et al., “Iron-oxide nanoparticles mediated cyclization of 3-(4-chlorophenyl)-1-hydrazinylisoquinoline to 1-(4,5-dihydropyrazol-1-yl)isoquinolines,” Research on Chemical Intermediates, vol. 38, pp. 571–582, 2012.
  44. S. Rostamizadeh, N. Shadjou, M. Azad, and N. Jalali, “(α-Fe2O3)-MCM-41 as a magnetically recoverable nanocatalyst for the synthesis of pyrazolo[4,3-c]pyridines at room temperature,” Catalysis Communications, vol. 26, pp. 218–224, 2012.
  45. J. R. Goodell, A. A. Madhok, H. Hiasa, and D. M. Ferguson, “Synthesis and evaluation of acridine- and acridone-based anti-herpes agents with topoisomerase activity,” Bioorganic and Medicinal Chemistry, vol. 14, no. 16, pp. 5467–5480, 2006. View at Publisher · View at Google Scholar · View at Scopus
  46. M. Jones, A. E. Mercer, P. A. Stocks et al., “Antitumour and antimalarial activity of artemisinin-acridine hybrids,” Bioorganic and Medicinal Chemistry Letters, vol. 19, no. 7, pp. 2033–2037, 2009. View at Publisher · View at Google Scholar · View at Scopus
  47. S. M. Roopan, R. Subashini, A. Bharathi, G. Rajakumar, A. A. Rahuman, and P. K. Gullanki, “Synthesis, spectral characterization and larvicidal activity of acridin-1(2H)-one analogues,” Spectrochimica Acta A, vol. 95, pp. 442–445, 2012.
  48. S. M. Roopan and F. R. N. Khan, “SnO2 nanoparticles mediated nontraditional synthesis of biologically active 9-chloro-6, 13-dihydro-7-phenyl-5H-indolo[3, 2-c]-acridine derivatives,” Medicinal Chemistry Research, vol. 20, pp. 732–737, 2011.
  49. M. A. Ghasemzadeh, J. Safaei-Ghomi, and H. Molaei, “Fe3O4 nanoparticles: as an efficient, green and magnetically reusable catalyst for the one-pot synthesis of 1,8-dioxo-decahydroacridine derivatives under solvent-free conditions,” Comptes Rendus Chimie, vol. 15, pp. 969–974, 2012.
  50. S. Rostamizadeh, A. Amirahmadi, N. Shadjou, and A. M. Amani, “MCM-41-SO3H as a nanoreactor for the one-pot, solvent-free synthesis of 1, 8-dioxo-9-aryl decahydroacridines,” Journal of Heterocyclic Chemistry, vol. 49, pp. 111–115, 2012.
  51. A. A. Trabanco, G. Duvey, J. M. Cid et al., “New positive allosteric modulators of the metabotropic glutamate receptor 2 (mGluR2): identification and synthesis of N-propyl-8-chloro-6-substituted isoquinolones,” Bioorganic and Medicinal Chemistry Letters, vol. 21, no. 3, pp. 971–976, 2011. View at Publisher · View at Google Scholar · View at Scopus
  52. Y. Asano, S. Kitamura, T. Ohra et al., “Discovery, synthesis and biological evaluation of isoquinolones as novel and highly selective JNK inhibitors,” Bioorganic and Medicinal Chemistry, vol. 16, no. 8, pp. 4699–4714, 2008. View at Publisher · View at Google Scholar · View at Scopus
  53. V. Krishnakumar, B. K. Mandal, K. M. Kumar, and F. N. Khan, “Flower-shaped ZnO nanoparticles as an efficient, heterogeneous and reusable catalyst in the synthesis of N-arylhomophthalimides and benzannelated isoquinolinones,” Research on Chemical Intermediates, vol. 38, pp. 1881–1892, 2012.
  54. B. Japelj, S. Rečnik, P. Čebašek, B. Stanovnik, and J. Svete, “Synthesis and antimycobacterial activity of alkyl 1-heteroaryl-1H-1,2,3- triazole-4-carboxylates,” Journal of Heterocyclic Chemistry, vol. 42, no. 6, pp. 1167–1173, 2005. View at Scopus
  55. A. K. Jordão, V. F. Ferreira, T. M. L. Souza et al., “Synthesis and anti-HSV-1 activity of new 1,2,3-triazole derivatives,” Bioorganic and Medicinal Chemistry, vol. 19, no. 6, pp. 1860–1865, 2011. View at Publisher · View at Google Scholar · View at Scopus
  56. N. G. Aher, V. S. Pore, N. N. Mishra et al., “Synthesis and antifungal activity of 1,2,3-triazole containing fluconazole analogues,” Bioorganic and Medicinal Chemistry Letters, vol. 19, no. 3, pp. 759–763, 2009. View at Publisher · View at Google Scholar · View at Scopus
  57. F. Alonso, Y. Moglie, G. Radivoy, and M. Yus, “Multicomponent click synthesis of potentially biologically active triazoles catalysed by copper nanoparticles on activated carbon in water,” Heterocycles, vol. 84, pp. 1033–1044, 2012.
  58. J. Albadi, M. Keshavarz, F. Shirini, and M. Vafaie-nezhad, “Copper iodide nanoparticles on poly(4-vinyl pyridine): a new and efficient catalyst for multicomponent click synthesis of 1,4-disubstituted-1,2,3-triazoles in water,” Catalysis Communications, vol. 27, pp. 17–20, 2012.
  59. H. Sharghi, A. Khoshnood, M. M. Doroodmand, and R. Khalifeh, “1,4-Dihydroxyanthraquinone-copper(II) nanoparticles immobilized on silica gel: a highly efficient, copper scavenger and recyclable heterogeneous nanocatalyst for a click approach to the three-component synthesis of 1,2,3-triazole derivatives in water,” Journal of the Iranian Chemical Society, vol. 9, pp. 231–250, 2012.
  60. B. S. P. Anil Kumar, K. H. V. Reddy, B. Madhav, K. Ramesh, and Y. V. D. Nageswar, “Magnetically separable CuFe2O4 nano particles catalyzed multicomponent synthesis of 1,4-disubstituted 1,2,3-triazoles in tap water using ‘click chemistry’,” Tetrahedron Letters, vol. 53, pp. 4595–4599, 2012.
  61. B. Kaboudin, Y. Abedi, and T. Yokomatsu, “One-pot synthesis of 1,2,3-triazoles from boronic acids in water using Cu(II)-β-cyclodextrin complex as a nanocatalyst,” Organic Biomolecular Chemistry, vol. 10, pp. 4543–4548, 2012.
  62. V. Maddi, K. S. Raghu, and M. N. A. Rao, “Synthesis and anti-inflammatory activity of 3-(benzylideneamino)coumarins in rodents,” Journal of Pharmaceutical Sciences, vol. 81, no. 9, pp. 964–965, 1992. View at Publisher · View at Google Scholar · View at Scopus
  63. M. Roussaki, C. A. Kontogiorgis, D. Hadjipavlou-Litina, S. Hamilakis, and A. Detsi, “A novel synthesis of 3-aryl coumarins and evaluation of their antioxidant and lipoxygenase inhibitory activity,” Bioorganic and Medicinal Chemistry Letters, vol. 20, no. 13, pp. 3889–3892, 2010. View at Publisher · View at Google Scholar · View at Scopus
  64. S. Sardari, Y. Mori, K. Horita, R. G. Micetich, S. Nishibe, and M. Daneshtalab, “Synthesis and antifungal activity of coumarins and angular furanocoumarins,” Bioorganic and Medicinal Chemistry, vol. 7, no. 9, pp. 1933–1940, 1999. View at Publisher · View at Google Scholar · View at Scopus
  65. B. V. Kumar, H. S. B. Naik, D. Girija, and B. V. Kumar, “ZnO nanoparticle as catalyst for efficient green one-pot synthesis of coumarins through Knoevenagel condensation,” Journal of Chemical Sciences, vol. 123, pp. 615–621, 2011.
  66. I. Manolov, C. Maichle-Moessmer, I. Nicolova, and N. Danchev, “Synthesis and anticoagulant activities of substituted 2,4-diketochromans, biscoumarins, and chromanocoumarins,” Archiv der Pharmazie, vol. 339, no. 6, pp. 319–326, 2006. View at Publisher · View at Google Scholar · View at Scopus
  67. J. M. Khurana and K. Vij, “Nickel nanoparticles: a highly efficient catalyst for one pot synthesis of tetraketones and biscoumarins,” Journal of Chemical Sciences, vol. 124, pp. 907–912, 2012.
  68. Z. Bouaziz, J. Riondal, A. Mey, M. Berlion, J. Villard, and H. Fillion, “Synthesis of some naphthoxazine carbolactone derivatives with in vitro cytotoxic and antifungal activities,” European Journal of Medicinal Chemistry, vol. 26, no. 4, pp. 469–472, 1991. View at Publisher · View at Google Scholar · View at Scopus
  69. A. Kumar, A. Saxena, M. Dewan, A. De, and S. Mozumdar, “Recyclable nanoparticulate copper mediated synthesis of naphthoxazinones in PEG-400: a green approach,” Tetrahedron Letters, vol. 52, pp. 4835–4839, 2011.
  70. G. A. M. Nawwar, “Salicylamides containing amino acid or pyran moieties with molluscicidal activity,” Archiv der Pharmazie, vol. 327, no. 4, pp. 201–205, 1994. View at Scopus
  71. A. Plant, A. Harder, N. Mencke, and H. Bertram, “Synthesis and anthelmintic activity of 7-hydroxy- 5-oxo-5H-thieno[3, 2-b]pyran-6-carboxanilides and -6-thiocarboxanilides,” Pest Management Science, vol. 48, pp. 351–358, 1996.
  72. N. Babakhani and S. Keshipoor, “TiO2 and TiO2 nanoparticles as efficient and recoverable catalysts for the synthesis of pyran annulated heterocyclic systems,” Research on Chemical Intermediates, 2012. View at Publisher · View at Google Scholar
  73. H. Mehrabi and M. Kazemi-Mireki, “CuO nanoparticles: an efficient and recyclable nanocatalyst for the rapid and green synthesis of 3,4-dihydropyrano[c]chromenes,” Chinese Chemical Letters, vol. 22, pp. 1419–1422, 2011.
  74. M. Khoobi, L. Ma’mani, F. Rezazadeh et al., “One-pot synthesis of 4H-benzo[b]pyrans and dihydropyrano[c]chromenes using inorganic-organic hybrid magnetic nanocatalyst in water,” Journal of Molecular Catalysis A, vol. 359, pp. 74–80, 2012.
  75. S. Rostamizadeh, N. Shadjou, and M. Hasanzadeh, “Application of MCM-41-SO3H as an advanced nanocatalyst for the solvent free synthesis of pyrano[3, 2-c]pyridine derivatives,” Journal of the Chinese Chemical Society, vol. 59, pp. 866–871, 2012.
  76. H. Valizadeh and A. A. Azimi, “ZnO/MgO containing ZnO nanoparticles as a highly effective heterogeneous base catalyst for the synthesis of 4H-pyrans and coumarins in [bmim]BF4,” Journal of the Iranian Chemical Society, vol. 8, no. 1, pp. 123–130, 2011. View at Scopus
  77. H. Nagabhushana, S. Sandeep Saundalkar, L. Muralidhar et al., “α-Fe2O3 nanoparticles: an efficient, inexpensive catalyst for the one-pot preparation of 3,4-dihydropyrano[c] chromenes,” Chinese Chemical Letters, vol. 22, no. 2, pp. 143–146, 2011. View at Publisher · View at Google Scholar · View at Scopus
  78. M. Hosseini, R. Miri, M. Amini et al., “Synthesis, QSAR and calcium channel antagonist activity of new 1,4-dihydropyridine derivatives containing 1-methy 1-4,5-dichloroimidazolyl substituents,” Archiv der Pharmazie, vol. 340, no. 10, pp. 549–556, 2007. View at Publisher · View at Google Scholar · View at Scopus
  79. I. Kruk, A. Kladna, K. Lichszteld et al., “Antioxidant activity of 4-flavonil-1,4-dihydropyridine derivatives,” Biopolymers, vol. 62, no. 3, pp. 163–167, 2001. View at Publisher · View at Google Scholar · View at Scopus
  80. R. Murugan, K. Ramamoorthy, S. Sundarrajan, and S. Ramakrishna, “Magnesium oxide nanotubes: synthesis, characterization and application as efficient recyclable catalyst for pyrazolyl 1,4-dihydropyridine derivatives,” Tetrahedron, vol. 68, pp. 7196–7201, 2012.
  81. C. Y. Fiakpui, O. A. Phillips, K. S. K. Murthy, and E. E. Knaus, “Synthesis and anticonvulsant activities of 5-(2-Chlorophenyl)7H-pyrido [4,3-f] [1,2,4]triazolo [4,3-a] [1,4]diazepines,” Journal of Heterocyclic Chemistry, vol. 36, no. 2, pp. 377–380, 1999. View at Scopus
  82. R. Ramajayam, R. Giridhar, M. R. Yadav et al., “Synthesis, antileukemic and antiplatelet activities of 2,3-diaryl-6,7-dihydro-5H-1,4-diazepines,” European Journal of Medicinal Chemistry, vol. 43, no. 9, pp. 2004–2010, 2008. View at Publisher · View at Google Scholar · View at Scopus
  83. A. Maleki, “Fe3O4/SiO2 nanoparticles: an efficient and magnetically recoverable nanocatalyst for the one-pot multicomponent synthesis of diazepines,” Tetrahedron, vol. 68, pp. 7827–7833, 2012.
  84. E. Lukevics, L. Lgnatovich, I. Sleiksha et al., “Synthesis, structure and cytotoxic activity of 2-acetyl-5- trimethylsilylthiophene(furan) and their oximes,” Applied Organometallic Chemistry, vol. 20, no. 7, pp. 454–458, 2006. View at Publisher · View at Google Scholar · View at Scopus
  85. A. Foroumadi, N. Mohammadhosseini, S. Emami et al., “Synthesis and antibacterial activity of new 7-piperazinylquinolones containing a functionalized 2-(furan-3-yl)ethyl moiety,” Archiv der Pharmazie, vol. 340, no. 1, pp. 47–52, 2007. View at Publisher · View at Google Scholar · View at Scopus
  86. J. Safaei-Ghomi, M. A. Ghasemzadeh, and A. Kakavand-Qalenoei, “CuI-nanoparticles-catalyzed one-pot synthesis of benzo[b]furans via three-component coupling of aldehydes, amines and alkyne,” Journal of Saudi Chemical Society, 2012. View at Publisher · View at Google Scholar
  87. N. Mulakayala, P. V. N. S. Murthy, D. Rambabu et al., “Catalysis by molecular iodine: a rapid synthesis of 1,8-dioxo-octahydroxanthenes and their evaluation as potential anticancer agents,” Bioorganic & Medicinal Chemistry Letters, vol. 22, pp. 2186–2191, 2012.
  88. S. Rostamizadeh, A. M. Amani, G. H. Mahdavinia, G. Amiri, and H. Sepehrian, “Ultrasound promoted rapid and green synthesis of 1,8-dioxo-octahydroxanthenes derivatives using nanosized MCM-41-SO3H as a nanoreactor, nanocatalyst in aqueous media,” Ultrasonics Sonochemistry, vol. 17, no. 2, pp. 306–309, 2010. View at Publisher · View at Google Scholar · View at Scopus
  89. I. Banti, S. Nencetti, E. Orlandini, A. Lapucci, M. C. Breschi, and S. Fogli, “Synthesis and in-vitro antitumour activity of new naphthyridine derivatives on human pancreatic cancer cells,” Journal of Pharmacy and Pharmacology, vol. 61, no. 8, pp. 1057–1066, 2009. View at Publisher · View at Google Scholar · View at Scopus
  90. P. M. Sivakumar, G. Iyer, and M. Doble, “QSAR studies on substituted 3- or 4-phenyl-1,8-naphthyridine derivatives as antimicrobial agents,” Medicinal Chemistry Research, vol. 21, pp. 788–795, 2012. View at Publisher · View at Google Scholar · View at Scopus
  91. S. Rostamizadeh, M. Azad, N. Shadjou, and M. Hasanzadeh, “(α-Fe2O3)-MCM-41-SO3H as a novel magnetic nanocatalyst for the synthesis of N-aryl-2-amino-1, 6-naphthyridine derivatives,” Catalysis Communications, vol. 25, pp. 83–91, 2012.
  92. A. Dandia, V. Parewa, and K. S. Rathore, “Synthesis and characterization of CdS and Mn doped CdS nanoparticles and their catalytic application for chemoselective synthesis of benzimidazoles and benzothiazoles in aqueous medium,” Catalysis Communications, vol. 28, pp. 90–94, 2012.
  93. P. Gupta, S. Hameed, and R. Jain, “Ring-substituted imidazoles as a new class of anti-tuberculosis agents,” European Journal of Medicinal Chemistry, vol. 39, no. 9, pp. 805–814, 2004. View at Publisher · View at Google Scholar · View at Scopus
  94. A. Khalafi-Nezhad, M. N. Soltani Rad, H. Mohabatkar, Z. Asrari, and B. Hemmateenejad, “Design, synthesis, antibacterial and QSAR studies of benzimidazole and imidazole chloroaryloxyalkyl derivatives,” Bioorganic and Medicinal Chemistry, vol. 13, no. 6, pp. 1931–1938, 2005. View at Publisher · View at Google Scholar · View at Scopus
  95. H. Zang, Q. Su, Y. Mo, B. W. Cheng, and S. Jun, “Ionic liquid [EMIM]OAc under ultrasonic irradiation towards the first synthesis of trisubstituted imidazoles,” Ultrasonics Sonochemistry, vol. 17, no. 5, pp. 749–751, 2010. View at Publisher · View at Google Scholar · View at Scopus
  96. M. V. Chary, N. C. Keerthysri, S. V. N. Vupallapati, N. Lingaiah, and S. Kantevari, “Tetrabutylammonium bromide (TBAB) in isopropanol: an efficient, novel, neutral and recyclable catalytic system for the synthesis of 2,4,5-trisubstituted imidazoles,” Catalysis Communications, vol. 9, no. 10, pp. 2013–2017, 2008. View at Publisher · View at Google Scholar · View at Scopus
  97. S. Kantevari, S. V. N. Vuppalapati, D. O. Biradar, and L. Nagarapu, “Highly efficient, one-pot, solvent-free synthesis of tetrasubstituted imidazoles using HClO4-SiO2 as novel heterogeneous catalyst,” Journal of Molecular Catalysis A, vol. 266, no. 1-2, pp. 109–113, 2007. View at Publisher · View at Google Scholar · View at Scopus
  98. B. F. Mirjalili, A. H. Bamoniri, and L. Zamani, “One-pot synthesis of 1,2,4,5-tetrasubstituted imidazoles promoted by nano-TiCl4.SiO2,” Scientia Iranica, Transactions C, vol. 19, pp. 565–568, 2012.
  99. G. M. Ziarani, A. Badiei, N. Lashgari, and Z. Farahani, “Efficient one-pot synthesis of 2,4,5-trisubstituted and 1,2,4,5-tetrasubstituted imidazoles using SBA-Pr-SO3H as a green nano catalyst,” Journal of Saudi Chemical Society, 2013. View at Publisher · View at Google Scholar
  100. J. Safari, S. Gandomi-Ravandi, and Z. Akbari, “Sonochemical synthesis of 1,2,4,5-tetrasubstituted imidazoles using nanocrystalline MgAl2O4 as an effective catalyst,” Journal of Advanced Research, 2012. View at Publisher · View at Google Scholar
  101. A. Teimouri and A. N. Chermahini, “An efficient and one-pot synthesis of 2,4,5-trisubstituted and 1,2,4,5-tetrasubstituted imidazoles catalyzed via solid acid nano-catalyst,” Journal of Molecular Catalysis A, vol. 346, pp. 39–45, 2011.
  102. M. G. Hossein, A. A. Mohammad, and S. Hamid, “MCM-41-SO3H as a highly efficient sulfonic acid nanoreactor for the rapid and green synthesis of some novel highly substituted imidazoles under solvent-free condition,” Chinese Journal of Chemistry, vol. 30, pp. 703–708, 2012.
  103. B. Karami, K. Eskandari, and A. Ghasemi, “Facile and rapid synthesis of some novel polysubstituted imidazoles by employing magnetic Fe3O4 nanoparticles as a high efficient catalyst,” Turkish Journal of Chemistry, vol. 36, pp. 601–614, 2012.
  104. S. J. Ahmadi, M. Hosseinpour, and S. Sadjadi, “Granulated copper oxide nanocatalyst: a mild and efficient reusable catalyst for the one-pot synthesis of 4-amino-5-pyrimidinecarbonitriles under aqueous conditions,” Monatshefte fur Chemie, vol. 142, pp. 1163–1168, 2011.
  105. R. Hekmatshoar, G. N. Kenary, S. Sadjadi, and Y. S. Beheshtiha, “ZnO Nanoparticles: a mild and efficient reusable catalyst for the one-pot synthesis of 4-amino-5-pyrimidinecarbonitriles under aqueous conditions,” Synthetic Communications, vol. 40, no. 13, pp. 2007–2013, 2010. View at Publisher · View at Google Scholar · View at Scopus
  106. M. M. Heravi, S. Sadjadi, S. Sadjadi, H. A. Oskooie, R. H. Shoar, and F. F. Bamoharram, “Supported preyssler nanoparticles in synthesis of 1,3-diaryl-5- spirohexahydropyrimidines,” Journal of the Chinese Chemical Society, vol. 56, no. 2, pp. 246–250, 2009. View at Scopus
  107. B. W. J. Chen, L. L. Chng, J. Yang, Y. Wei, J. Yang, and J. Y. Ying, “Palladium-based nanocatalyst for one-pot synthesis of polysubstituted quinolines,” ChemCatChem, vol. 5, pp. 277–283, 2013.
  108. S. J. Ahmadi, M. Hosseinpour, and S. Sadjadi, “Nanocrystalline copper(II) oxide-catalyzed one-pot synthesis of imidazo[1,2-a ]quinoline and quinolino[1,2-a ]quinazoline derivatives via a three-component condensation,” Synthetic Communications, vol. 41, no. 3, pp. 426–435, 2011. View at Publisher · View at Google Scholar · View at Scopus
  109. H. R. Prakash Naik, H. S. Bhojya Naik, T. R. Ravikumar Naik, T. Aravinda, and D. S. Lamani, “TiO2 nanopowder catalyzed microwave-induced one-pot synthesis of novel quinoline/benzo[h]quinoline3-carbonitrile under solvent free conditions,” Phosphorus, Sulfur and Silicon and the Related Elements, vol. 184, no. 8, pp. 2109–2114, 2009. View at Publisher · View at Google Scholar · View at Scopus
  110. J. M. Nezhad, J. Akbari, A. Heydari, and B. Alirezapour, “CuO nanoparticles as an efficient and reusable catalyst for the one-pot Friedlander quinoline synthesis,” Bulletin of the Korean Chemical Society, vol. 32, pp. 3853–3854, 2011.
  111. M. So, Y. Liu, C. Ho, K. Lam, and C. Che, “Silica-supported gold nanoparticles catalyzed one-pot, tandem aerobic oxidative cyclization reaction for nitrogen-containing polyheterocyclic compounds,” ChemCatChem, vol. 3, pp. 386–393, 2011.
  112. M. B. Gawande, A. Velhinho, I. D. Nogueira, C. A. A. Ghumman, O. M. N. D. Teodoro, and P. S. Branco, “A facile synthesis of cysteine-ferrite magnetic nanoparticles for application in multicomponent reactions—a sustainable protocol,” The Royal Society of Chemistry, vol. 2, pp. 6144–6149, 2012.
  113. S. Abdolmohammadi, “TiO2 nanoparticles as an effective catalyst for the synthesis of hexahydro-2-quinolinecarboxylic acids derivatives,” Chinese Chemical Letters, vol. 23, pp. 1003–1006, 2012.
  114. S. Sadjadi, R. Hekmatshoar, S. J. Ahmadi, M. Hosseinpour, and M. Outokesh, “On water: a practical and efficient synthesis of benzoheterocycle derivatives catalyzed by nanocrystalline copper(II) oxide,” Synthetic Communications, vol. 40, no. 4, pp. 607–614, 2010. View at Publisher · View at Google Scholar · View at Scopus
  115. V. Polshettiwar and R. S. Varma, “Nano-organocatalyst: magnetically retrievable ferrite-anchored glutathione for microwave-assisted Paal-Knorr reaction, aza-Michael addition, and pyrazole synthesis,” Tetrahedron, vol. 66, no. 5, pp. 1091–1097, 2010. View at Publisher · View at Google Scholar · View at Scopus
  116. H. Li, Z. Zhu, F. Zhang et al., “Palladium nanoparticles confined in the cages of MIL-101: an efficient catalyst for the one-pot indole synthesis in water,” ACS Catalysis, vol. 1, pp. 1604–1612, 2011.
  117. R. Parella, Naveen, and S. A. Babu, “Magnetic nano Fe3O4 and CuFe2O4 as heterogeneous catalysts: a green method for the stereo- and regioselective reactions of epoxides with indoles/pyrroles,” Catalysis Communications, vol. 29, pp. 118–121, 2012.
  118. S. M. Roopan and F. R. N. Khan, “ZnO nanorods catalyzed N-alkylation of piperidin-4-one, 4(3H)-pyrimidone, and ethyl 6-chloro-1,2-dihydro-2-oxo-4-phenylquinoline-3-carboxylate,” Chemical Papers, vol. 64, no. 5, pp. 678–682, 2010. View at Publisher · View at Google Scholar · View at Scopus
  119. S. M. Roopan, M. Gund, F. N. Khan, R. Kumar, J. S. Jin, and A. S. Kumar, “Regioselective O-alkylation: synthesis of 1-{2-[(2chloroquinolin-3-yl)methoxy]-6-chloro-4phenylquinolin-3-yl}ethanones,” Research on Chemical Intermediates, vol. 38, pp. 1111–1118, 2012.
  120. S. M. Roopan, F. R. N. Khan, and B. K. Mandal, “Fe nano particles mediated C–N bond-forming reaction: regioselective synthesis of 3-[(2-chloroquinolin-3-yl)methyl]pyrimidin-4(3H)ones,” Tetrahedron Letters, vol. 51, no. 17, pp. 2309–2311, 2010. View at Publisher · View at Google Scholar · View at Scopus