About this Journal Submit a Manuscript Table of Contents
Journal of Nanomaterials
Volume 2013 (2013), Article ID 616501, 11 pages
http://dx.doi.org/10.1155/2013/616501
Review Article

Recent Advances as Materials of Functional Metal-Organic Frameworks

1College of Biology, Chemistry and Material Science, East China Institute of Technology, Fuzhou, Jiangxi 344000, China
2Fundamental Science on Radioactive Geology and Exploration Technology Laboratory, East China Institute of Technology, NanChang, Jiangxi 330013, China

Received 30 January 2013; Accepted 22 March 2013

Academic Editor: Jianmin Ma

Copyright © 2013 Xiao-Lan Tong et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. D. Britt, D. Tranchemontagne, and O. M. Yaghi, “Metal-organic frameworks with high capacity and selectivity for harmful gases,” Proceedings of the National Academy of Sciences of the United States of America, vol. 105, no. 33, pp. 11623–11627, 2008. View at Publisher · View at Google Scholar · View at Scopus
  2. N. L. Rosi, M. Eddaoudi, J. Kim, M. O'Keeffe, and O. M. Yaghi, “Advances in the chemistry of metal-organic frameworks,” CrystEngComm, vol. 4, pp. 401–404, 2002. View at Publisher · View at Google Scholar
  3. M. D. Allendorf, C. A. Bauer, R. K. Bhakta, and R. J. T. Houk, “Luminescent metal-organic frameworks,” Chemical Society Reviews, vol. 38, no. 5, pp. 1330–1352, 2009. View at Publisher · View at Google Scholar · View at Scopus
  4. C. Janiak, “Engineering coordination polymers towards applications,” Dalton Transactions, no. 14, pp. 2781–2804, 2003. View at Scopus
  5. C. L. Cahill, D. T. de Lill, and M. Frisch, “Homo- and heterometallic coordination polymers from the f elements,” CrystEngComm, vol. 9, no. 1, pp. 15–26, 2007. View at Publisher · View at Google Scholar · View at Scopus
  6. D. Maspoch, D. Ruiz-Molina, and J. Veciana, “Old materials with new tricks: multifunctional open-framework materials,” Chemical Society Reviews, vol. 36, no. 5, pp. 770–818, 2007. View at Publisher · View at Google Scholar · View at Scopus
  7. T. Sakamoto, A. Ojida, and I. Hamachi, “Molecular recognition, fluorescence sensing, and biological assay of phosphate anion derivatives using artificial Zn(II)-Dpa complexes,” Chemical Communications, no. 2, pp. 141–152, 2009. View at Publisher · View at Google Scholar · View at Scopus
  8. A. J. Moro, P. J. Cywinski, S. Körsten, and G. J. Mohr, “An ATP fluorescent chemosensor based on a Zn(II)-complexed dipicolylamine receptor coupled with a naphthalimide chromophore,” Chemical Communications, no. 7, pp. 1085–1087, 2010. View at Publisher · View at Google Scholar
  9. H. L. Jiang, Y. Tatsu, Z. H. Lu, and Q. Xu, “Non-, micro-, and mesoporous metal–organic framework isomers: reversible transformation, fluorescence sensing, and large molecule separation,” Journal of the American Chemical Society, vol. 132, no. 16, pp. 5586–5587, 2010. View at Publisher · View at Google Scholar
  10. M. Ji, X. Lan, Z. Ping, C. Hao, and J. Qiu, “Luminescent properties of metal-organic framework mof-5: relativistic time-dependent density functional theory investigations,” Inorganic Chemistry, vol. 51, no. 22, pp. 12389–12394, 2012. View at Publisher · View at Google Scholar
  11. X. Q. Song, W. S. Liu, W. Don, Y. W. Wang, J. R. Zheng, and Z. P. Zang, “Structure variation and luminescence properties of lanthanide complexes incorporating a naphthalene-derived chromophore featuring salicylamide pendant arms,” European Journal of Inorganic Chemistry, vol. 2008, no. 11, pp. 1901–1912, 2008. View at Publisher · View at Google Scholar
  12. N. Sabbatini, M. Guardigli, and J. M. Lehn, “Luminescent lanthanide complexes as photochemical supramolecular devices,” Coordination Chemistry Reviews, vol. 123, no. 1-2, pp. 201–228, 1993. View at Scopus
  13. F. S. Richardson, “Terbium(III) and europium(III) ions as luminescent probes and stains for biomolecular systems,” Chemical Reviews, vol. 82, no. 5, pp. 541–552, 1982. View at Publisher · View at Google Scholar
  14. B. D. Chandler, J. O. Yu, D. T. Cramb, and G. K. H. Shimizu, “Series of lanthanide-alkali metal–organic frameworks exhibiting luminescence and permanent microporosity,” Chemistry of Materials, vol. 19, no. 18, pp. 4467–4473, 2007. View at Publisher · View at Google Scholar
  15. P. Mahata and S. Natarajan, “A new series of three-dimensional metal-organic framework, [M2 (H2O)] [C5N1H3(COO)2]3·2H2O, M = La, Pr, and Nd: synthesis, structure, and properties,” Inorganic Chemistry, vol. 46, no. 4, pp. 1250–1258, 2007. View at Publisher · View at Google Scholar
  16. P. Mahata, K. V. Ramya, and S. Natarajan, “Synthesis, structure and optical properties of rare-earth benzene carboxylates,” Dalton Transactions, no. 36, pp. 4017–4026, 2007. View at Publisher · View at Google Scholar · View at Scopus
  17. X. J. Zhang, Y. H. Xing, Z. Sun et al., “A series of two-dimensional metal-organic frameworks based on the assembly of rigid and flexible carboxylate-containing mixed ligands with lanthanide metal salts,” Crystal Growth & Design, vol. 7, no. 10, pp. 2041–2046, 2007. View at Publisher · View at Google Scholar
  18. J. He, J. Yu, Y. Zhang, Q. Pan, and R. Xu, “Synthesis, structure, and luminescent property of a heterometallic metal-organic framework constructed from rod-shaped secondary building blocks,” Inorganic Chemistry, vol. 44, no. 25, pp. 9279–9282, 2005. View at Publisher · View at Google Scholar
  19. B. Chen, L. Wang, F. Zapata, G. Qian, and E. B. Lobkovsky, “A luminescent microporous metal-organic framework for the recognition and sensing of anions,” Journal of the American Chemical Society, vol. 130, no. 21, pp. 6718–6719, 2008. View at Publisher · View at Google Scholar · View at Scopus
  20. P. Day and A. E. Underhill, Eds., Metal-Organic and Organic Molecular Magnets, vol. 252, Royal Society of Chemistry, Cambridge, UK, 2000.
  21. C. N. R. Rao, A. K. Cheetham, and A. Thirumurugan, “Hybrid inorganic-organic materials: a new family in condensed matter physics,” Journal of Physics: Condensed Matter, vol. 20, no. 8, Article ID 083202, 2008. View at Publisher · View at Google Scholar
  22. M. Kurmoo, “Magnetic metal-organic frameworks,” Chemical Society Reviews, vol. 38, pp. 1353–1379, 2009. View at Publisher · View at Google Scholar
  23. S. J. Blundell and F. L. Pratt, “Organic and molecular magnets,” Journal of Physics: Condensed Matter, vol. 16, no. 24, pp. R771–R828, 2004. View at Publisher · View at Google Scholar · View at Scopus
  24. K. Itoh and M. Kinoshita, Eds., Molecular Magnetism: New Magnetic Materials, Gordon Breach-Kodansha, Tokyo, Japan, 2000.
  25. B. Moulton and M. J. Zaworotko, “From molecules to crystal engineering: supramolecular isomerism and polymorphism in network solids,” Chemical Reviews, vol. 101, no. 6, pp. 1629–1658, 2001. View at Publisher · View at Google Scholar · View at Scopus
  26. M. E. Davis, “Ordered porous materials for emerging applications,” Nature, vol. 417, no. 6891, pp. 813–821, 2002. View at Publisher · View at Google Scholar · View at Scopus
  27. C. Janiak, “Engineering coordination polymers towards applications,” Dalton Transactions, no. 14, pp. 2781–2804, 2003. View at Scopus
  28. W. Lin, “Homochiral porous metal-organic frameworks: why and how?” Journal of Solid State Chemistry, vol. 178, no. 8, pp. 2486–2490, 2005. View at Publisher · View at Google Scholar · View at Scopus
  29. C. J. Kepert, “Advanced functional properties in nanoporous coordination framework materials,” Chemical Communications, no. 7, pp. 695–700, 2006. View at Publisher · View at Google Scholar
  30. D. Maspoch, D. Ruiz-Molina, and J. Veciana, “Old materials with new tricks: multifunctional open-framework materials,” Chemical Society Reviews, vol. 36, no. 5, pp. 770–818, 2007. View at Publisher · View at Google Scholar · View at Scopus
  31. S. Chen, J. Zhang, and X. Bu, “Ionothermal synthesis of homochiral framework with acetate-pillared cobalt-camphorate architecture,” Inorganic Chemistry, vol. 47, no. 13, pp. 5567–5569, 2008. View at Publisher · View at Google Scholar
  32. Z. X. Li, J. P. Zhao, E. C. Saňudo et al., “New 3D coordination polymers constructed from pillared metal-formate kagome layers exhibiting spin canting only in the Nickel(II) complex,” Inorganic Chemistry, vol. 48, no. 24, pp. 11601–11607, 2009. View at Publisher · View at Google Scholar
  33. T. S. Venkatakrishnan, S. Sahoo, N. Bréfuel et al., “Enhanced ion anisotropy by nonconventional coordination geometry: single-chain magnet behavior for a [{FeIIL}2{NbIV(CN)8}] helical chain compound designed with heptacoordinate FeII,” Journal of the American Chemical Society, vol. 132, no. 17, pp. 6047–6056, 2010.
  34. X. Y. Wang, Z. M. Wang, and S. Gao, “Constructing magnetic molecular solids by employing three-atom ligands as bridges,” Chemical Communications, no. 3, pp. 281–294, 2008. View at Publisher · View at Google Scholar
  35. N. Guillou, C. Livage, and G. Férey, “Cobalt and nickel oxide architectures in metal carboxylate frameworks: from coordination polymers to 3D inorganic skeletons,” European Journal of Inorganic Chemistry, vol. 2006, no. 24, pp. 4963–4978, 2006.
  36. L. M. C. Beltran and J. R. Long, “Directed assembly of metal-cyanide cluster magnets,” Accounts of Chemical Research, vol. 38, no. 4, pp. 325–334, 2005. View at Publisher · View at Google Scholar
  37. E. Coronado, C. Martí-Gastaldo, J. R. Galán-Mascarós, and M. Cavallini, “Polymetallic oxalate-based 2D magnets: soluble molecular precursors for the nanostructuration of magnetic oxides,” Journal of the American Chemical Society, vol. 132, no. 15, pp. 5456–5468, 2010. View at Publisher · View at Google Scholar
  38. D. Sarma, P. Mahata, S. Natarajan, P. Panissod, G. Rogez, and M. Drillon, “Synthesis, structure, and magnetic properties of a new eight-connected metal-organic framework (MOF) based on Co4 clusters,” Inorganic Chemistry, vol. 51, no. 8, pp. 4495–4501, 2012. View at Publisher · View at Google Scholar
  39. K. Nakabayashi and S. Ohkoshi, “Monometallic lanthanoid assembly showing ferromagnetism with a Curie temperature of 11 K,” Inorganic Chemistry, vol. 48, no. 18, pp. 8647–8649, 2009. View at Publisher · View at Google Scholar
  40. X. Feng, L. Y. Wang, J. S. Zhao et al., “Series of anion-directed lanthanide-rigid-flexible frameworks: syntheses, structures, luminescence and magnetic properties,” CrystEngComm, vol. 12, no. 3, pp. 774–783, 2010. View at Publisher · View at Google Scholar · View at Scopus
  41. Y. Wang, X. L. Li, T. W. Wang, Y. Song, and X. Z. You, “Slow relaxation processes and single-ion magnetic behaviors in dysprosium-containing complexes,” Inorganic Chemistry, vol. 49, no. 3, pp. 969–976, 2010. View at Publisher · View at Google Scholar
  42. D. P. Li, T. W. Wang, C. H. Li, D. S. Liu, Y. Z. Li, and X. Z. You, “Single-ion magnets based on mononuclear lanthanide complexes with chiral Schiff base ligands [Ln(FTA)3L] (Ln = Sm, Eu, Gd, Tb and Dy),” Chemical Communications, vol. 46, no. 17, pp. 2929–2931, 2010. View at Publisher · View at Google Scholar
  43. W. W. Sun, C. Y. Tian, X. H. Jing, Y. Q. Wang, and E. Q. Gao, “Solvent-modulated metamagnetism in a nickel(II) coordination polymer with mixed azide and carboxylate bridges,” Chemical Communications, no. 31, pp. 4741–4743, 2009. View at Publisher · View at Google Scholar
  44. T. Liu, J. Zhang, Z. M. Wang, and S. Gao, “A 64-nuclear cubic cage incorporating propeller-like FeIII8 apices and HCOO-edges,” Journal of the American Chemical Society, vol. 130, no. 32, pp. 10500–10501, 2008. View at Publisher · View at Google Scholar
  45. R. Q. Zhong, R. Q. Zou, M. Du et al., “Metal-organic frameworks of manganese(ii) 4,4′- biphenyldicarboxylates: crystal structures, hydrogen adsorption, and magnetism properties,” CrystEngComm, vol. 12, no. 3, pp. 677–681, 2010. View at Publisher · View at Google Scholar · View at Scopus
  46. S. S. Kaye, A. Dailly, O. M. Yaghi, and J. R. Long, “Impact of preparation and handling on the hydrogen storage properties of Zn4O(1,4-benzenedicarboxylate)3 (MOF-5),” Journal of the American Chemical Society, vol. 129, no. 46, pp. 14176–14177, 2007. View at Publisher · View at Google Scholar · View at Scopus
  47. D. N. Dybtsev, H. Chun, and K. Kim, “Rigid and flexible: a highly porous metal-organic framework with unusual guest-dependent dynamic behavior,” Angewandte Chemie International Edition, vol. 43, no. 38, pp. 5033–5036, 2004. View at Publisher · View at Google Scholar
  48. B. Panella and M. Hirscher, “Hydrogen physisorption in metal-organic porous crystals,” Advanced Materials, vol. 17, no. 5, pp. 538–541, 2005. View at Publisher · View at Google Scholar · View at Scopus
  49. L. J. Murray, M. Dincă, and J. R. Long, “Hydrogen storage in metal-organic frameworks,” Chemical Society Reviews, vol. 38, no. 5, pp. 1294–1314, 2009. View at Publisher · View at Google Scholar
  50. S. S. Kaye and J. R. Long, “Hydrogen storage in the dehydrated prussian blue analogues M3[Co(CN)6]2 (M = Mn, Fe, Co, Ni, Cu, Zn),” Journal of the American Chemical Society, vol. 127, no. 18, pp. 6506–6507, 2005. View at Publisher · View at Google Scholar
  51. F. Nouar, J. F. Eubank, T. Bousquet, L. Wojtas, M. J. Zaworotko, and M. Eddaoudi, “Supermolecular building blocks (SBBs) for the design and synthesis of highly porous metal-organic frameworks,” Journal of the American Chemical Society, vol. 130, no. 6, pp. 1833–1835, 2008. View at Publisher · View at Google Scholar · View at Scopus
  52. I. Senkovska and S. Kaskel, “Solvent-Induced pore-size adjustment in the metal-organic framework [Mg3(ndc)3(dmf)4] (ndc = naphthalenedicarboxylate),” European Journal of Inorganic Chemistry, vol. 2006, no. 22, pp. 4564–4569, 2006. View at Publisher · View at Google Scholar
  53. M. Dincă and J. R. Long, “High-enthalpy hydrogen adsorption in cation-exchanged variants of the microporous metal-organic framework Mn3[(Mn4Cl)3(BTT)8(CH3OH)10]2,” Journal of the American Chemical Society, vol. 129, no. 36, pp. 11172–11176, 2007. View at Publisher · View at Google Scholar
  54. D. Sun, S. Ma, Y. ke, D. J. Collins, and H. C. Zhou, “An Interweaving MOF with high hydrogen uptake,” Journal of the American Chemical Society, vol. 128, no. 12, pp. 3896–3897, 2006. View at Publisher · View at Google Scholar
  55. R. Zou, A. I. Abdel-Fattah, H. Xu, Y. Zhao, and D. D. Hickmott, “Storage and separation applications of nanoporous metal-organic frameworks,” CrystEngComm, vol. 12, no. 5, pp. 1337–1353, 2010. View at Publisher · View at Google Scholar · View at Scopus
  56. X. S. Wang, S. Ma, D. Yuan et al., “A large-surface-area boracite-network-topology porous MOF constructed from a conjugated ligand exhibiting a high hydrogen uptake capacity,” Inorganic Chemistry, vol. 48, no. 16, pp. 7519–7521, 2009. View at Publisher · View at Google Scholar
  57. J. L. C. Rowsell, J. Eckert, and O. M. Yaghi, “Characterization of H2 binding sites in prototypical metal-organic frameworks by inelastic neutron scattering,” Journal of the American Chemical Society, vol. 127, no. 42, pp. 14904–14910, 2005. View at Publisher · View at Google Scholar · View at Scopus
  58. J. L. C. Rowsell, A. R. Millward, K. S. Park, and O. M. Yaghi, “Hydrogen sorption in functionalized metal-organic frameworks,” Journal of the American Chemical Society, vol. 126, no. 18, pp. 5666–5667, 2004. View at Publisher · View at Google Scholar · View at Scopus
  59. U. Mueller, M. Schubert, F. Teich, H. Puetter, K. Schierle-Arndt, and J. Pastré, “Metal-organic frameworks—prospective industrial applications,” Journal of Materials Chemistry, vol. 16, no. 7, pp. 626–636, 2006. View at Publisher · View at Google Scholar · View at Scopus
  60. D. Britt, D. Tranchemontagne, and O. M. Yaghi, “Metal-organic frameworks with high capacity and selectivity for harmful gases,” Proceedings of the National Academy of Sciences of the United States of America, vol. 105, no. 33, pp. 11623–11627, 2008. View at Publisher · View at Google Scholar
  61. L. H. Xie, J. B. Lin, X. M. Liu et al., “Porous coordination polymer with flexibility imparted by coordinatively changeable lithium ions on the pore surface,” Inorganic Chemistry, vol. 49, no. 3, pp. 1158–1165, 2010. View at Publisher · View at Google Scholar
  62. A. U. Czaja, N. Trukhan, and U. Mueller, “Industrial applications of metal-organic frameworks,” Chemical Society Reviews, vol. 38, no. 5, pp. 1284–1293, 2009. View at Publisher · View at Google Scholar
  63. S. J. Yang, T. Kim, J. H. Im et al., “MOF-derived hierarchically porous carbon with exceptional porosity and hydrogen storage capacity,” Chemistry of Materials, vol. 24, no. 3, pp. 464–470, 2012. View at Publisher · View at Google Scholar
  64. J. An, S. J. Geib, and N. L. Rosi, “High and selective CO2 uptake in a cobalt adeninate metal-organic framework exhibiting pyrimidine- and amino-decorated pores,” Journal of the American Chemical Society, vol. 132, no. 1, pp. 38–39, 2010. View at Publisher · View at Google Scholar
  65. D. Britt, H. Furukawa, B. Wang, T. G. Glover, and O. M. Yaghi, “Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites,” Proceedings of the National Academy of Sciences of the United States of America, vol. 106, no. 49, pp. 20637–20640, 2009. View at Publisher · View at Google Scholar · View at Scopus
  66. J. R. Li, Y. Tao, Q. Yu, X. H. Bu, H. Sakamoto, and S. Kitagawa, “Selective gas adsorption and unique structural topology of a highly stable guest-free zeolite-type MOF material with N-rich chiral open channels,” Chemistry—A European Journal, vol. 14, no. 9, pp. 2771–2776, 2008. View at Publisher · View at Google Scholar
  67. J. Lee, O. K. Farha, J. Roberts, K. A. Scheidt, S. T. Nguyen, and J. T. Hupp, “Metal-organic framework materials as catalysts,” Chemical Society Reviews, vol. 38, no. 5, pp. 1450–1459, 2009. View at Publisher · View at Google Scholar · View at Scopus
  68. L. Ma, C. Abney, and W. Lin, “Enantioselective catalysis with homochiral metal-organic frameworks,” Chemical Society Reviews, vol. 38, no. 5, pp. 1248–1256, 2009. View at Publisher · View at Google Scholar
  69. A. U. Czaja, N. Trukhan, and U. Müller, “Industrial applications of metal-organic frameworks,” Chemical Society Reviews, vol. 38, no. 5, pp. 1284–1293, 2009. View at Publisher · View at Google Scholar