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Journal of Nanomaterials
Volume 2013 (2013), Article ID 680821, 10 pages
http://dx.doi.org/10.1155/2013/680821
Research Article

TiO2-SiO2/Ph-POSS Functional Hybrids: Preparation and Characterisation

Institute of Chemical Technology and Engineering, Faculty of Chemical Technology, Poznan University of Technology, M. Sklodowskiej-Curie 2, 60965 Poznan, Poland

Received 10 July 2013; Revised 20 August 2013; Accepted 20 August 2013

Academic Editor: Mengnan Qu

Copyright © 2013 Magdalena Nowacka et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. J. Godnjavec, B. Znoj, N. Veronovski, and P. Venturini, “Polyhedral oligomeric silsesquioxanes as titanium dioxide surface modifiers for transparent acrylic UV blocking hybrid coating,” Progress in Organic Coatings, vol. 74, no. 4, pp. 654–659, 2011. View at Publisher · View at Google Scholar · View at Scopus
  2. I. Blanco, L. Abate, F. A. Bottino, and P. Bottino, “Thermal degradation of hepta cyclopentyl, mono phenyl-polyhedral oligomeric silsesquioxane (hcp-POSS)/polystyrene (PS) nanocomposites,” Polymer Degradation and Stability, vol. 97, no. 6, pp. 849–855, 2012. View at Publisher · View at Google Scholar · View at Scopus
  3. M. Hoyos, A. Fina, F. Carniato, M. Prato, and O. Monticelli, “Novel hybrid systems based on poly(propylene-g-maleic anhydride) and Ti-POSS by direct reactive blending,” Polymer Degradation and Stability, vol. 96, no. 10, pp. 1793–1798, 2011. View at Publisher · View at Google Scholar · View at Scopus
  4. W. Du, J. Shan, Y. Wu, R. Xu, and D. Yu, “Preparation and characterization of polybenzoxazine/trisilanol polyhedral oligomeric silsesquioxanes composites,” Materials and Design, vol. 31, no. 4, pp. 1720–1725, 2010. View at Publisher · View at Google Scholar · View at Scopus
  5. A. Fina, D. Tabuani, and G. Camino, “Polypropylene-polysilsesquioxane blends,” European Polymer Journal, vol. 46, no. 1, pp. 14–23, 2010. View at Publisher · View at Google Scholar · View at Scopus
  6. X. Z. Zhang, Y. J. Song, and Y. D. Huang, “Properties of silsesquioxane coating modified carbon fibre/polyarylacetylene composites,” Composites Science and Technology, vol. 67, no. 14, pp. 3014–3022, 2007. View at Publisher · View at Google Scholar · View at Scopus
  7. C. Jin, S. List, S. Yamanaka et al., “Deposition and characterization of porous silica xerogel films,” in Proceedings of the MRS Fall Meeting, vol. 443, pp. 99–104, December 1996. View at Scopus
  8. H. Fong, S. H. Dickens, and G. M. Flaim, “Evaluation of dental restorative composites containing polyhedral oligomeric silsesquioxane methacrylate,” Dental Materials, vol. 21, no. 6, pp. 520–529, 2005. View at Publisher · View at Google Scholar · View at Scopus
  9. L. Barral, F. J. Díez, S. García-Garabal et al., “Thermodegradation kinetics of a hybrid inorganic-organic epoxy system,” European Polymer Journal, vol. 41, no. 7, pp. 1662–1666, 2005. View at Publisher · View at Google Scholar · View at Scopus
  10. F. Carniato, C. Bisio, L. Sordelli, E. Gavrilova, and M. Guidotti, “Ti-POSS covalently immobilized onto mesoporous silica: a model for active sites in heterogeneous catalytic epoxidation,” Inorganica Chimica Acta, vol. 380, no. 1, pp. 244–251, 2012. View at Publisher · View at Google Scholar · View at Scopus
  11. X. Chen, D. Wang, X. Li, Y. Liu, and L. Hu, “POSS/TiO2 nanohybrids as sun protection factors for skin changes caused by ultraviolet a radiation,” Materials Science Forum, vol. 610, pp. 1039–1043, 2009. View at Publisher · View at Google Scholar · View at Scopus
  12. P. A. Wheeler, R. Misra, R. D. Cook, and S. E. Morgan, “Polyhedral oligomeric silsesquioxane trisilanols as dispersants for titanium oxide nanopowder,” Journal of Applied Polymer Science, vol. 108, no. 4, pp. 2503–2508, 2008. View at Publisher · View at Google Scholar · View at Scopus
  13. F. Ciesielczyk, M. Nowacka, A. Przybylska, and T. Jesionowski, “Dispersive and electrokinetic evaluations of alkoxysilane-modified MgO·SiO2 oxide composite and pigment hybrids supported on it,” Colloids and Surfaces A, vol. 376, no. 1–3, pp. 21–30, 2011. View at Publisher · View at Google Scholar · View at Scopus
  14. D. Ambrozewicz, B. Marciniec, and T. Jesionowski, “New POSS/magnesium silicate nano-hybrids obtained by chemical or mechanical methods,” Chemical Engineering Journal, vol. 210, no. 1, pp. 229–236, 2012.
  15. A. N. Murashkevich, A. S. Lavitskaya, O. A. Alisienok, and I. M. Zharskii, “Fabrication and properties of SiO2/TiO2 composites,” Inorganic Materials, vol. 45, no. 10, pp. 1146–1152, 2009. View at Publisher · View at Google Scholar · View at Scopus
  16. M. Bellardita, M. Addamo, A. Di Paola et al., “Photocatalytic activity of TiO2/SiO2 systems,” Journal of Hazardous Materials, vol. 174, no. 1–3, pp. 707–713, 2010. View at Publisher · View at Google Scholar · View at Scopus
  17. A. Nilchi, S. Janitabar-Darzi, A. R. Mahjoub, and S. Rasouli-Garmarodi, “New TiO2/SiO2 nanocomposites-phase transformations and photocatalytic studies,” Colloids and Surfaces A, vol. 361, no. 1–3, pp. 25–30, 2010. View at Publisher · View at Google Scholar · View at Scopus
  18. T. Jesionowski, F. Ciesielczyk, and A. Krysztafkiewicz, “Influence of selected alkoxysilanes on dispersive properties and surface chemistry of spherical silica precipitated in emulsion media,” Materials Chemistry and Physics, vol. 119, no. 1-2, pp. 65–74, 2010. View at Publisher · View at Google Scholar · View at Scopus
  19. M. E. McGovern, K. M. R. Kallury, and M. Thompson, “Role of solvent on the silanization of glass with octadecyltrichlorosilane,” Langmuir, vol. 10, no. 10, pp. 3607–3614, 1994. View at Scopus
  20. C. H. Lee, S. H. Park, W. Chung, J. Y. Kim, and S. H. Kim, “Preparation and characterization of surface modified silica nanoparticles with organo-silane compounds,” Colloids and Surfaces A, vol. 384, no. 1–3, pp. 318–322, 2011. View at Publisher · View at Google Scholar · View at Scopus
  21. K. Siwinska-Stefanska, F. Ciesielczyk, A. Kolodziejczak-Radzimska, D. Paukszta, J. Sójka-Ledakowicz, and T. Jesionowski, “TiO2-SiO2 inorganic barrier composites: from synthesis to application,” Pigment and Resin Technology, vol. 41, no. 3, pp. 139–148, 2012.
  22. T. Jesionowski and A. Krysztafkiewicz, “Comparison of the techniques used to modify amorphous hydrated silicas,” Journal of Non-Crystalline Solids, vol. 277, no. 1, pp. 45–57, 2000. View at Publisher · View at Google Scholar · View at Scopus
  23. E. P. Plueddemann, Silane Coupling Agents, Plenum Press, New York, NY, USA, 1982.
  24. M. Doǧan, Y. Turhan, M. Alkan, H. Namli, P. Turan, and Ö. Demirbaş, “Functionalized sepiolite for heavy metal ions adsorption,” Desalination, vol. 230, no. 1–3, pp. 248–268, 2008. View at Publisher · View at Google Scholar · View at Scopus
  25. D. J. Shaw, Introduction to Colloid and Surface Chemistry, Butterworths, London, UK, 1970.
  26. D. Thiemig and A. Bund, “Characterization of electrodeposited Ni-TiO2 nanocomposite coatings,” Surface and Coatings Technology, vol. 202, no. 13, pp. 2976–2984, 2008. View at Publisher · View at Google Scholar · View at Scopus
  27. K. Siwińska-Stefańska, M. Nowacka, A. Kołodziejczak-Radzimska, and T. Jesionowski, “Preparation of hybrid pigments via adsorption of selected food dyes onto inorganic oxides based on anatase titanium dioxide,” Dyes and Pigments, vol. 94, no. 2, pp. 338–348, 2012. View at Publisher · View at Google Scholar · View at Scopus
  28. M. Kosmulski, “pH-dependent surface charging and points of zero charge. IV. Update and new approach,” Journal of Colloid and Interface Science, vol. 337, no. 2, pp. 439–448, 2009. View at Publisher · View at Google Scholar · View at Scopus
  29. M. Kosmulski, “The pH-dependent surface charging and points of zero charge. V. Update,” Journal of Colloid and Interface Science, vol. 353, no. 1, pp. 1–15, 2011. View at Publisher · View at Google Scholar · View at Scopus
  30. K. Siwinska-Stefanska, F. Ciesielczyk, M. Nowacka, and T. Jesionowski, “Influence of selected alkoxysilanes on dispersive properties and surface chemistry of titanium dioxide and TiO2-SiO2 composite material,” Journal of Nanomaterials, vol. 2012, Article ID 316173, 19 pages, 2012. View at Publisher · View at Google Scholar
  31. I. Jerman, M. Mihelčič, D. Verhovek, J. Kovač, and B. Orel, “Polyhedral oligomeric silsesquioxane trisilanols as pigment surface modifiers for fluoropolymer based Thickness Sensitive Spectrally Selective (TSSS) paint coatings,” Solar Energy Materials and Solar Cells, vol. 95, no. 2, pp. 423–431, 2011. View at Publisher · View at Google Scholar · View at Scopus
  32. T. Ozawa, “Thermal analysis: review and prospect,” Thermochimica Acta, vol. 355, no. 1-2, pp. 35–42, 2000. View at Publisher · View at Google Scholar · View at Scopus